• Journal of Korean Society of Water and Wastewater
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• 제38권4호
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• pp.209-221
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• 2024

This study explored effects of a sludge-based biochar addition on nitrogen removal of membrane bioreactor (MBR) for wastewater treatment. The membrane fouling reduction by the biochar addition was also investigated. A dose of 3 g/L of the biochar was applied to an MBR (i.e., BC-MBR) and treatment efficiencies of organic matter and nutrient were analyzed. The MBRs with powdered activated carbon (i.e., AC-MBR) and without any additives were also operated in parallel. The average removals of COD and TN were improved with the biochar addition compared to those with the control MBR. Interestingly, operational duration was also increased with biochar addition. The CLSM analysis revealed that biomass amounts of BC-MBR and AC-MBR were reduced by more than 40%, and thickness of the biofilm attached to the membrane surface also was decreased. The physical properties of biochar surfaces were compared with a commercial powdered activated carbon. The specific surface area with 38 m²/g and pore volume with 0.13 cm³/g of the biochar were much smaller than those of the powdered activated carbon, which were 1100 m²/g and 0.67 cm³/g, respectively. Manufacturing conditions for the biochar production needs to be further investigated for enhancing physical properties for adsorption and biological improvement.

• Applied Chemistry for Engineering
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• 제7권5호
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• pp.925-937
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• 1996

Three types of mordenites treated by steaming($SM_{6.5}$), HF solution for $SM_{6.5}(FM_a)$ and HF solutlon+steaming for $SM_{6.5}(FM_b)$ were prepared and used as cracking catalysts of vacuum gas oil. These samples were analysed by XRF and XPS for average and surface Si/Al atomic ratio, XRD for unit cell constants, nitrogen adsorption/desorption for porosity, pyridine-IR for acidic properties. In comparison with three type samples, $SM_{6.5}$ had a lot of acid amount and showed micropore volume mostly(>85% to total volume). Dealuminated $FM_a$, compared with $SM_{6.5}$, was decreased a little in acid amount and improved for porosity. Also, $FM_b$ was decreased further in acid amount and developed in mesopore dramatically. The catalytic activity and the yield of gasoline, kerosine+diesel and branched aromatic over the modified mordenites which have developed mesopore were improved. This is due to limited access of diffusion of large molecules within pore of the modified mordenites.

• Journal of Korean Society of Environmental Engineers
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• 제27권6호
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• pp.581-589
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• 2005

Recently, membrane processes have been replacing the conventional processes for waste water treatment to produce better quality of effluent and to meet more stringent regulations because of water shortage. However, using membrane processes for water treatment has confronted with fouling and difficulty in treating dissolved organic pollutants. In this study, membrane process equipped with crossflow microfiltration is combined with coagulation process using alum and PAC to improve permeability and treatment efficiency. The effects of coagulant dosage and optimum membrane operating conditions were investigated from measurement of permeate flow, cumulative volume, total resistance, particle size, dissolved organic pollutant, dissolved aluminium and quality of effluent. Characteristic of PAC coagulation was compared with that of alum coagulation. PAC coagulation reduced membrane fouling because of forming larger particle size and increased permeate velocity and cumulative volume. Less dissolved organic pollutants and dissolved aluminum made decreasing-rate of permeate velocity being lowered. At using $0.2\;{\mu}m$ membrane, cake filtration observed. At using $0.45\;{\mu}m$ membrane, there was floc breakage due to shear stress occurred born circulating operation. It made floc size smaller than membrane pore size, which subsequently to decrease permeate velocity and to increase total resistance. The optimum coagulation dosage was $300{\pm}50\;mg/L$ for both alum and PAC. PAC coagulation was more efficiently used with $0.2\;{\mu}m$ membrane, and the highest permeate flux was in using $0.45\;{\mu}m$membrane. The greatest efficiency of treatment was as follows; turbidity 99.8%, SS 99.9%, $BOD_5$ 94.4%, $COD_{Cr}$ 95.4%, T-N 54.3%, T-P 99.8%.

• Journal of the Korean Geotechnical Society
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• 제30권6호
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• pp.5-21
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• 2014

It has been pointed out that the collapses of unsaturated road embankments caused by earthquake are attributed to high water content caused by the seepage of the underground water and/or the rainfall infiltration. Hence, it is important to study influences of water content on the dynamic stability and deformation mode of unsaturated road embankments for development of a proper design scheme including an effective reinforcement to prevent severe damage. This study demonstrates dynamic centrifugal model tests with different water contents to investigate the effect of water content on deformation and failure behaviors of unsaturated road embankments. Based on the measurement of displacement, the pore water pressure and the acceleration during dynamic loading, dynamic behavior of the unsaturated road embankments with about optimum water content and the higher water content than the optimum one have been examined. In addition, an image analysis has revealed the displacement field and the distributions of strains in the road embankment, by which deformation mode of the road embankment with higher water content has been clarified. It has been confirmed that in the case of higher water content the settlement of the crown is large mainly owing to the volume compression underneath the crown, while the small confining pressure at the toe and near the slope surface induces large shear deformation with volume expansion.

• Journal of the Korea Institute of Building Construction
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• 제16권1호
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• pp.35-43
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• 2016

Concrete is a representative heterogeneous material and mechanical properties of concrete are influenced by various factors. Due to the fact that pores in concrete affect determining compressive strength of concrete, studies which deal with distribution and magnitudes of pores are very important. That way, studies using picture imaging have been emerged. Studies on mechanical performance evaluation of structural lightweight foamed concrete and FEM analysis based on picture image are inadequate because lightweight foamed concrete has been researched for only non-structural. Therefore, in this study, cement paste with foaming agent to evaluate mechanical performance is made, FEM analysis with picture image is conducted and young's modulus of experiment and analysis are compared. In this study, dosage of foaming agent is determined 7 level to check pore distribution and water-binder ratio is determined 20% to progress research about structural light weight foamed concrete. Weight of unit volume is minimum at 0.8% of foaming agent dosage. However, weight of unit volume is increased over 0.8% of foaming agent dosage because of interconnection with independent pores. For FEM analysis, cement paste is photographed to use image analyzer(HF-MA C01). Consequently, the fact that Young's Modulus of experiment and FEM analysis are same is drawn by using OOF(Object Oriented Finite elements).

• Applied Chemistry for Engineering
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• 제28권6호
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• pp.638-644
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• 2017

Pitch based activated carbon fibers for electric double layer capacitor (EDLC) electrodes were treated by oxyfluorination via varying the ratio of fluorine and oxygen gases to improve high power property. As the partial pressure of fluorine increased, the oxyfluorinated activated carbon fibers showed an increase of linear fluorine functional groups. While the oxygen functional groups increased, no changes was observed with respect to the partial gas pressure. The specific surface area and pore volume decreased due to the etching reaction on the activated carbon fiber surface through oxyfluorination, but the mesopore volume increased about 4.5 times. In the case of activated carbon fibers treated with 50% of the fluorine gas partial pressure, the specific capacitance increased to about 29% and 61% at scan rates of 5 and 50 mV/s, respectively. The improvement of the specific capacitance was believed to be due to the introduction of oxygen and fluorine functional groups on the activated carbon fiber surface and the increase of mesopores through oxyfluorination.

• Korean Journal of Soil Science and Fertilizer
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• 제33권3호
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• pp.175-181
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• 2000

This study was carried out to investigate the change of soil physical properties in long-term fertilized paddy soils with a Fine silty family of Typic Halpaqueps (Pyeongtaeg series). Treatments fertilized consisted of no fertilizer, compost, NPK, NPK+compost for thirty one years and of NPK+silicate for seventeen years. Water stable aggregate and degree of aggregate stability, which were higher in surface-soil than sub-soil, were high in order of NPK + compost > NPK + silicate > compost > NPK > no fertilizer plot. The ratio of aggregate larger than 0.5mm was high at compost and silicate plots but that smaller than 0.5mm was high at no fertilizer and NPK plots. And this aggregate stability showed negative correlation with soil hardness and bulk density ; positive correlation with sedimentation volume of soils in water. Sedimentation volume of soils in water was a little higher in surface-soil than sub-soil and in wet soil than dry soil, respectively. Pore space ratio and water retention capacity of soils were the most increased by the application of compost and not affected by silicate as in cases of liquid limit and plastic limit. Ignition loss of soils was high in order of NPK + compost > compost > NPK + silicate > NPK > no fertilizer plot. And field shattering ratio of soil mass smaller than 25.4mm was relatively high in NPK + compost, compost, and silicate plots.

• Korean Journal of Soil Science and Fertilizer
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• 제40권5호
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• pp.392-399
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• 2007

This study was carried out to assess optimum conditions of peatmoss-based substrates for red pepper plug seedlings. Peatmoss-based substrates prepared by mixing of peatmoss with vermiculite, perlite, rice hull and zeolite at various mixing ratios were used for growing pepper plug seedlings. The physical and chemical properties of the peatmoss substrate were analyzed by the CEN(European committee for standardization) method. Fresh and dry weights (shoot, root), leaf area, root length and T/R ratio (dry shoot weight/dry root weight) were determined at 55 days after sowing. The results showed that the growing media PVSZ 6 (peatmoss:silver vermiculite: zeolite=6:3.9:0.1) and PVGZ 6 (peatmoss:gold vermiculite: zeolite=6:3.9:0.1) can successfully be used for red pepper plug seedlings judging from dry weight and T/R ratio of the plug seedlings. The optimal ranges of total pore space, water volume, air volume, easily available water content and water buffering capacity of the peatmoss based growing media for pepper plug seedlings were 87~93%, 52~71%, 20~41%, 10~37% and 0.6~10%, respectively.

• Korean Journal of Soil Science and Fertilizer
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• 제40권5호
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• pp.369-376
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• 2007

This experiment was carried out to investigate optimum conditions of coir-based substrates for the red pepper plug seedlings. Eleven different coir based substrates prepared by mixing of coir, vermiculite, rice hull, perlite, zeolite, mixed at different ratios were tested. The physical and chemical properties of the substrates were analyzed by the CEN (European committee for standardization) method. Fresh and dry weights of shoot and root, leaf area, root length, and T/R ratio (dry shoot weight/dry root weight) were determined at 55 days after sowing. The results showed that the growing media CRZ 8(coir:rice hull: vermiculite=8:1.9:0.1) and CVSZ 6(coir:silver vermiculite: zeolite=6:3.9:0.1) can successfully be used for pepper plug seedlings judging from dry weight and T/R ratio of the plug seedlings. The optimal range of total pore space, water volume, air volume, easily available water content and water buffering capacity of the coir-based growing substrates for pepper plug seedlings were in the range of 92~94%, 52~60%, 32~43%, 18~21%, and 0.9~8%, respectively.

• Clean Technology
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• 제27권3호
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• pp.223-231
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• 2021

In order to address many issues associated with large volume changes of silicon, which has very low electrical conductivity but offers about 10 times higher theoretical capacity than graphite (Gr), a silicon nanoparticles/hollow carbon (SiNP/HC) composite having bimodal-mesopores was prepared using silica nanoparticles as a template. A control SiNP/C composite without a hollow structure was also prepared for comparison. The physico-chemical and electrochemical properties of SiNP/HC were analyzed by X-ray diffractometry, X-ray photoelectron spectroscopy, nitrogen adsorption/desorption measurements for surface area and pore size distribution, scanning electron microscopy, transmission electron microscopy, galvanostatic cycling, and cyclic voltammetry tests to compare them with those of the SiNP/C composite. The SiNP/HC composite showed significantly better cycle life and efficiency than the SiNP/C, with minimal increase in electrode thickness after long cycles. A hybrid composite, SiNP/HC@Gr, prepared by physical mixing of the SiNP/HC and Gr at a 50:50 weight ratio, exhibited even better cycle life and efficiency than the SiNP/HC at low capacity. Thus, silicon/carbon composites designed to have hollow spaces capable of accommodating volume expansion were found to be highly effective for long cycle life of silicon-based composites. However, further study is required to improve the low initial coulombic efficiency of SiNP/HC and SiNP/HC@Gr, which is possibly because of their high surface area causing excessive electrolyte decomposition for the formation of solid-electrolyte-interface layers.