• Title/Summary/Keyword: Pore Control

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Effect of ultrasonic irradiation on membrane fouling and membrane wetting in direct contact membrane distillation process (초음파 조사가 직접 접촉식 막증발 공정의 막오염과 막젖음에 미치는 영향)

  • Jang, Yongsun;Choi, Yongjun;Lee, Sangho
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.3
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    • pp.343-350
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    • 2016
  • Membrane distillation (MD) is a novel separation process that have drawn attention as an affordable alternative to conventional desalination processes. However, membrane fouling and pore wetting are issues to be addressed prior to widespread application of MD. In this study, the influence of ultrasonic irradiation on fouling and wetting of MD membranes was investigated for better understanding of the MD process. Experiments were carried out using a direct contact membrane distillation apparatus Colloidal silica was used as a model foulants in a synthetic seawater (35,000 mg/L NaCl solution). A vibrator was directed attached to membrane module to generate ultrasonic waves from 25 kHz (the highest energy) to 75 kHz (the lowest energy). Flux and TDS for the distillate water were continuously monitored. Results suggested that ultrasonic irradiation is effective to retard flux decline due to fouling only in the early stage of the MD operation. Moreover, wetting occurred by a long-term application of ultrasonic rradiation at 75 kHz. These results suggest that the conditions for ultrasonic irradiation should be carefully optimized to maximize fouling control and minimize pore wetting.

Quality Characteristics of Sulgidduk with added Soybean Curd Residue Powder (비지분말 첨가에 의한 설기떡의 품질특성)

  • Lim, Sung-Mee;Lee, Goon-Ja
    • Korean journal of food and cookery science
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    • v.22 no.5 s.95
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    • pp.583-590
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    • 2006
  • This study was carried out to investigate the acceptable ratio of Sulgidduk with added soybean curd residue powder. The moisture content of Sulgidduk with added soybean curd residue powder (0${\sim}$ 10%) ranged from 40.54 ${\sim}$41.38%, and there were no significant differences between the addition of soybean curd residue powder and control. There were also no significant differences in swelling power and pore ratio from control to the addition of 4% soybean curd residue powder. However, these decreased with increasing addition of soybean curd residue powder of more than 6%. The L (lightness) value decreased with increasing addition of soybean curd residue powder, but the a (redness) and b (yellowness) values increased significantly. As the amount of soybean curd residue powder increased, the hardness, cohesiveness, springiness and gumminess decreased, and, the decrease was especially significant with addition of more than 6%. With increases in the storage period, the hardness, springiness and gumminess increased, while cohesiveness decreased for all additions of soybean curd residue powder. In sensory evaluations, Sulgidduk with the addition of 4% soybean curd residue powder was the most preferred with regard to overall quality. These results indicated that the Sulgidduk with 2% and 4% added soybean curd residue powder exhibited the best quality.

Evaluation of Injection capabilities of a biopolymer-based grout material

  • Lee, Minhyeong;Im, Jooyoung;Chang, Ilhan;Cho, Gye-Chun
    • Geomechanics and Engineering
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    • v.25 no.1
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    • pp.31-40
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    • 2021
  • Injection grouting is one of the most common ground improvement practice to increase the strength and reduce the hydraulic conductivity of soils. Owing to the environmental concerns of conventional grout materials, such as cement-based or silicate-based materials, bio-inspired biogeotechnical approaches are considered to be new sustainable and environmentally friendly ground improvement methods. Biopolymers, which are excretory products from living organisms, have been shown to significantly reduce the hydraulic conductivity via pore-clogging and increase the strength of soils. To study the practical application of biopolymers for seepage and ground water control, in this study, we explored the injection capabilities of biopolymer-based grout materials in both linear aperture and particulate media (i.e., sand and glassbeads) considering different injection pressures, biopolymer concentrations, and flow channel geometries. The hydraulic conductivity control of a biopolymer-based grout material was evaluated after injection into sandy soil under confined boundary conditions. The results showed that the performance of xanthan gum injection was mainly affected by the injection pressure and pore geometry (e.g., porosity) inside the soil. Additionally, with an increase in the xanthan gum concentration, the injection efficiency diminished while the hydraulic conductivity reduction efficiency enhanced significantly. The results of this study provide the potential capabilities of injection grouting to be performed with biopolymer-based materials for field application.

Control of Particle Characteristics in the Preparation of TiO2 Nano Particles Assisted by Microwave

  • Lee, Han-Bin;Choi, Min-Sik;Kye, Youn-Hee;An, Myoung-Young;Lee, Ik-Mo
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1699-1702
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    • 2012
  • $TiO_2$ nanostructures with various morphologies like cubes, spheres, hexahedral pillars and spherical tubes were synthesized by microwave-assisted hydrothermal process. Each structure was obtained by changing the relative concentrations of titanium tetraisoproxide (TTIP), tetrabutylammonium hydroxide (TBAH) and ethanol. Scanning electron microscopy (SEM), transmission electoron microscopy (TEM), X-ray diffraction and Brunauer-Emmett-Teller (BET) surface area analysis were used to characterize the synthesized $TiO_2$ nanostructures. From these results, it has been proved that $TiO_2$ structure could be controlled to have specific morphology, size, surface area, pore volume and pore size distribution.

Synthesis and Characteristics of Porous Silica Ceramics with Organic Additives(I) (유기물 첨가에 따른 다공성 실리카 세라믹스의 제조 및 특성(I))

  • 신진용;이범재;노재성
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.958-968
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    • 1998
  • Porous silica ceramics were prepared using DCCA(Drying Control Chemical Additives) Such as uncharged polymer(Polyethylene glycol) and protein (Lipase) under H2O/Low-grade TEOS=10 C2H5OH/Low-grade TEOS=1 HC1/Low=grade TEOS=0.01 After Plain which doesn't added DCCA and samples of 11 sorts which varied molecular weight of PEG(Mw=600, 1000, 2000) quantity of Lipase and concentration of wat-er were synthesized gellation time and thermal analysis were investigated. After heat-treated at 600, cry-stal structures analyses of SiO2 polymer and characteristics of pores were investigated. Gellation time was retarded about 2-6 times as compared with plain resulting in addition of DCCA and crystal structures ex-hibited amorphous state. Moreover as increase of water a short gellation time was obtained. The samples added PEG showed increase of specific surface areas up to 20-40% and had micropores while those of Lipase were decreased about 90% and showed broad pore size distribution.

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Inflence of carbonization temperature on electrochemical performance of multi-walled carbon nanotube/poly(vinylidene fluoride) composite-derived carbons (탄소나노튜브/폴리비닐리덴 플루오라이드 복합체로부터 제조된 탄소의 탄화온도에 따른 전기화학적 특성)

  • Kim, Ji-Il;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.214.2-214.2
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    • 2011
  • In this work, porous carbon based electrodes are prepared by carbonization using poly(vinylidene fluoride) (PVDF)/carbon nanotube (CNT) composites to further increase the specific capacitance for supercapacitors. Electrode materials investigate the aspects of specific capacitance, pore size distribution and surface area: influence of carbonization temperatures of PVDF/CNT composites. The electrochemical properties are investigated by cyclic voltammetry, impedance spectra, and galvanostatic charge-discharge performance with in $TEABF_4$ (tetraethylammonium tetrafluoroborate)/acetonitrile as non-aqueous electrolyte. From the results, the highest value of specific capacitance of ~101 $F{\cdot}g^{-1}$ is obtained for the samples carbonized at $600^{\circ}C$. Furthermore, pore size of samples control be low 7 nm through carbonization process. It is suggested that micropores significantly contribute to the specific capacitance, resulting from improved charge transfer.

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Processing Methods for the Preparation of Porous Ceramics

  • Ahmad, Rizwan;Ha, Jang-Hoon;Song, In-Hyuck
    • Journal of Powder Materials
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    • v.21 no.5
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    • pp.389-398
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    • 2014
  • Macroporous ceramics with tailored pore size and shape could be used for well-established and emerging applications, such as molten metal filtration, biomaterial, catalysis, thermal insulation, hot gas filtration and diesel particulate filters. In these applications, unique properties of porous materials were required which could be achieved through the incorporation of macro-pores into ceramics. In this article, we reviewed the main processing techniques which can be used for the fabrication of macroporous ceramics with tailored microstructure. Partial sintering, replica templates, sacrificial fugutives, and direct foaming techniques was described here and compared in terms of microstructures and mechanical properties that could be achieved. The main focus was given to the direct foaming technique which was simple and versatile approach that allowed the fabrication of macro-porous ceramics with tailored features and properties.

Three-dimensional Nanoporous Graphene-based Materials and Their Applications (3차원 나노 다공성 그래핀의 제조와 응용)

  • Jung, Hyun;Kang, Yein
    • Ceramist
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    • v.22 no.3
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    • pp.243-255
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    • 2019
  • Graphene, a two-dimensional material with a single atomic layer, has recently become a major research focus in various applications such as electronic devices, sensors, energy storage, catalysts, and adsorbents, because of its large theoretical surface area, excellent electrical conductivity, outstanding chemical stability, and good mechanical properties. Recently, 3D nanoporous graphene structures have received tremendous attention to expand the application of 2D graphene. Here, we overview the synthesis of 3D nanoporous graphene network structure with two-dimensional graphite oxide sheets, the control of porous parameters such as specific surface area, pore volume and pore size etc, and the modification of electronic structure by heteroatom doping along with its various applications. The 3D nanoporous graphene shows superior performance in diverse applications as a promising key material. Consequently, 3D nanoporous graphene can lead the future for advanced nanotechnology.

Preparation of Alumina Ceramics by Pressureless Powder Packing Forming Method (II) Characterization of Sintered Body Fabricated by Pressureless Powder Packing Forming Method (무가압 분말 충전 성형법을 이용한 알루미나 세라믹스의 제조 (II) 무가압 분말 충전 성형법에 의해 제조된 소결체 특성 관찰)

  • 박정형;성재석
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.113-119
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    • 1995
  • The green body was fabricated by a new forming method, pressureless powder packaing forming method, and the characteristics of sintered specimen were investigated. It was found that alumina ceramics prepared by the present method showed porous structure with narrow pore size distribution, and in case of abrasive powder sintered body, compared with dry-pressed specimen, had the nearly same density. Especially, the specimen prepared with spray-dried granules showed the characteristic that granules were not either deformed or fractured during forming and sintering process. Therefore, it was found that this new forming method was effective method in fabrication of porous ceramics on account of easy control of porosity and pore size and its high thermal stability.

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Optical Characterization of DBR Porous Silicon by Changing of Applied Current Density (전류세기의 변화에 따른 DBR 다공성 실리콘의 광학적 특성)

  • Choi, Tae-Eun;Park, Jaehyun
    • Journal of Integrative Natural Science
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    • v.2 no.2
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    • pp.82-85
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    • 2009
  • Distributed Bragg reflector (DBR) porous silicon (PSi) was generated by an electrochemical etching a bragg structure into a silicon wafer through electrode current in aqueous ethanolic HF solution. DBR PSi exhibiting unique reflectivity was successfully obtained by an electrochemical etching of silicon wafer using square current waveform. The multilayered photonic crystals of DBR PSi exhibited the reflection of a specific wavelength with high reflectivity in the optical reflectivity spectrum. In this work, we have developed a method to create refractive index in Si substrate through intensity of an electric current. The electrochemical process allows for precise control of the structural properties of DBR PSi such as thickness of the porous layer, porosity, and average pore diameter. The number of reflection peak of DBR PSi and its pore size increased as the intensity of electric current increased. This might be a demonstration for the fabrication of specific reflectors or filters.

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