• Title/Summary/Keyword: Porcelain materials

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Study on HRB Characteristics of Suspension Porcelain Insulators (자기재 현수 애자의 HRB 경도 특성)

  • Han, S.W.;Cho, H.G.;Park, K.H.
    • Proceedings of the KIEE Conference
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    • 2003.10a
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    • pp.142-144
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    • 2003
  • The suspension insulators are subjected to harsh environment in service for a long time. Long term reliability of the insulators is required for both mechanical and electrical performances. We studied HRB characteristics to find out a deformation of suspension porcelain with alumina contents. These experimental results show that HRB intensity was affected severely by alumina contents, and the propagation properties was affected mainly by a distribution and shape of micro pores on porcelain samples.

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Evaluation of Material Characteristics of Suspension-Type Porcelain Insulators for 154 KV Power Transmission Lines

  • Choi, In-Hyuk;Park, Joon-Young;Kim, Tae-gyun;Yoon, Yong-Beum;Yi, Junsin
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.207-210
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    • 2017
  • The suspension arrangement of insulators provides flexibility and assists in power transmission in transmission lines. The performance of the insulator string is strongly influenced by the environmental conditions to which it is exposed, its shape and the inherent material properties of suspension-type insulators. The suspension-type insulators are mostly made from glass, porcelain and ceramic material due to their high resistivity. Irregularity in charge distribution throughout the porcelain insulator may lead to accelerated aging and electrical breakdown. A very high and steep lightning impulse voltage may also cause breakdown of suspension-type insulators. We investigated various material characteristics such as alumina addition, surface morphology, x-ray diffraction pattern and relative density of suspension porcelain insulators manufactured in 1989 (36,000 lbs.), 1995 (36,000 lbs.) and 2001 (36,000 lbs.) by the KRI Company for use in 154 kV high power transmission lines. We compared the material characteristics of these porcelain insulators with that of the top-of-the-line porcelain insulators (36,000 lbs.) manufactured by the NGK Company in 2000. These suspension-type porcelain insulators were exposed to arc and flashover tests to examine their electrical and mechanical strength. It was noted that alumina addition (17 wt.%) for K-2001 was one of the major contributors to the enhancement of the performance of the porcelain insulators and to their ability to withstand very high current generation during the arc test. The porcelain insulators manufactured during 2001 also showed the highest relative density of 95.8% as compared to the other insulators manufactured in 1989 and 1995 respectively 94.2% and 91.5%. We also discuss reports of various failure modes of suspension-type porcelain insulators.

Fabrication of Porcelains Having Improved Thermal Shock Resistance by a Lithium Solution Infiltration Method (리튬용액침투법에 의한 내열충격성이 향상된 세라믹 제조)

  • Na, Sang-Moon;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.127-133
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    • 2013
  • Porcelain with high thermal shock resistance was successfully fabricated by a lithium solution infiltration method with a lithium hydroxide solution. Lithium hydroxide solutions having various lithium concentrations were infiltrated into pre-sintered porcelain bodies. The porcelain sample infiltrated by the 9 wt% lithium solution and heat treated at $1250^{\circ}C$ for 1 h showed a low thermal expansion coefficient of $1.0{\times}10^{-6}/^{\circ}C$ with excellent thermal shock resistance. The highly thermally resistant porcelain had a well-developed ${\beta}$-spodumene phase with the general phases observed in porcelain. Furthermore, the porcelain showed a denser structure of $2.41g/cm^3$ sintering density and excellent whiteness in comparison with commercial thermally resistible porcelains. The lithium hydroxide in the samples readily reacted with moisture, and liquid phase reactants were formed during the fabrication process. In the case of an excess amount of lithium in the sample body, the lithium reactants were forced to the surface and re-crystallized at the surface, leaving large pores beneath the surface. These phenomena resulted in an irregular structure in the surface area and led to cracking in samples subjected to a thermal shock test.

An Experimental Study on Wear of Porcelain Surface to Natural Teeth and Crown Metal Alloys (자연치아 및 치과용 합금에 대한 도재표면 마모에 관한 실험적 연구)

  • Lee, Nung-Soo
    • The Journal of Korean Academy of Prosthodontics
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    • v.19 no.1
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    • pp.47-54
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    • 1981
  • Dental porcelains are widely used for restorative material because of its excellent esthetic property. But according to contact with natural teeth or metal in oral cavity, the porcelain may be worn and may effect on masticatory physiology and prosthetic function. The purpose of this experiment was to study on wear of porcelain surface which treated in different method. Using the abrasion device which was designed and constructed by myself, the different porcelain surface were abraded by gold alloy, nickel-chrome alloy and natural teeth in order to compare roughness. Results were as follows. 1. The group of porcelain abraded by gold alloy showed less surface roughness change (t=2.92, p<0.05), and the group of porcelain abraded by natural teeth had high surface roughness. change (t=6.84, p<0.05). 2. According to the method of surface treatment, the surface roughness were very significant (F=9.12, p<0.05). 3. After abrading, the porcelain surface roughness change was very significant (F=54.49, p<0.05). 4. There was no significant between surface treatment method and the kind of abrading materials. (F=1.01, p>0..05). 5. The group of natural glazing had the most smooth surface ($2.1{\pm}1.13{\mu}m$).

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A Simulation on the Displacement Stress of Cement in Porcelain Insulators for Transmission Line (송전용 자기재 애자의 시멘트 변위 응력에 관한 시뮬레이션)

  • Han, S.W.;Cho, H.G.;Woo, B.C.;Jung, G.C.;Lee, D.I.;Choi, I.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.476-479
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    • 2002
  • The ageing cause in many porcelain suspension insulators which occur on transmission and distribution line with dead-end stings is mechanical stress in interface between porcelain and cement materials. It is known that the principal mechanical stress which give electrical failure is the results of the displacement is due to cement growth. We studied the effect of cement displacement resulting environmental ageing parameters on porcelain insulator mechanical properties for transmission line by simulation (ANSYS/NASTRAN program) and test methods. These simulation analysis and experimental results show that cement volume growth affects severely to be mechanical failure ageing.

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The effect of thermocycling on the bonding of different restorative materials to access opening through porcelain fused to metal restorations

  • Al-Moaleem, Mohammed M.;Shah, Farhan Khalid;Khan, Nausheen Saied;Porwal, Amit
    • The Journal of Advanced Prosthodontics
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    • v.3 no.4
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    • pp.186-189
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    • 2011
  • PURPOSE. Porcelain fused to metal (PFM) crowns provide the best treatment option for teeth that have a large or defective restoration. More than 20% of teeth with PFM crowns or bridges require non-surgical root canal treatment (NSRCT). This may be due to the effect of restorative procedures and the possible leakage of bacteria and or their by-products, which leads to the demise of the tooth pulp. Thus, this study was planned to compare the ability of the restorative materials to seal perforated PFM specimens. MATERIALS AND METHODS. The study evaluates the ability of amalgam, composite or compomer restorative materials to close perforated PFM specimen's in-vitro. Ninety PFM specimens were constructed using Ni-Cr alloys and feldspathic porcelain, and then they were divided into 3 groups: amalgam (A), composite + Exite adhesive bond (B) and compomer + Syntac adhesive bond (C). All the PFM samples were embedded in an acrylic block to provide complete sealing of the hole from the bottom side. After the aging period, each group was further divided into 3 equal subgroups according to the thermocycling period (one week for 70 cycles, one month for 300 cycles and three months for 900 cycles). Each subgroup was put into containers containing dye (Pelikan INK), one maintained at $5^{\circ}C$ and the other at $55^{\circ}C$, each cycle for 30 sec time. The data obtained was analyzed by SPSS, 2006 using one way ANOVA test and student t-test and significant difference level at (P<.01). RESULTS. The depth of dye penetration was measured at the interfaces of PFM and filling materials using Co-ordinate Vernier Microscope. The lowest levels of the dye penetration for the three groups, as well as subgroups were during the first week. The values of dye leakage had significantly increased by time intervals in subgroups A and C. CONCLUSION. It was seen that amalgam showed higher leakage than composite while compomer showed the lowest level of leakage.

Effect of Mullite Generation on the Strength Improvement of Porcelain (Mullite 생성이 도자기 강도개선에 미치는 영향)

  • Choi, Hyo-Sung;Pee, Jae-Hwan;Kim, Yoo-Jin;Cho, Woo-Seok;Kim, Kyeong-Ja
    • Journal of the Korean Ceramic Society
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    • v.48 no.2
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    • pp.168-172
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    • 2011
  • Alumina powder was added in a general porcelain (Backja) with clay, feldspar and quartz contents to promote the mullite ($3Al_2O_3{\cdot}2SiO_2$) generation in the porcelain. Low melting materials ($B_2O_3(450^{\circ}C)$, $MnO_3(940^{\circ}C)$, CuO($1080^{\circ}C$)) were doped at ~3 wt% to modify the sinterability of porcelain with a high alumina contents and promote the mullite generation. Green body was made by slip casting method with blended slurry and then, they were fired at $1280^{\circ}C$ for 1hr by a $2^{\circ}C/min$. Densifications of samples with high alumina contents (20~30 wt%) were impeded. As the doping contents of low melting materilas increased, the sinterability of samples was improved. The shrinkage rate and bulk density of samples were improved by doping with low melting materials. Mullite phase increased with increasing the low melting contents in the phase analyses. This means lots of alumina and quartz were transformed into mullite phase by low melting contents doping. In the results, high bending strength of samples with high alumina contents was accomplished by improving the densification and mullite generation in the porcelain.

Changes of Physical and Chemical Properties for Making Raw Materials and Reproductions According to Manufacturing Stages in Traditional Korean White Porcelain

  • Kim, Du Hyeon;Jeong, Ji Youn;Oh, Eun Jeong;Han, Min Su
    • Journal of Conservation Science
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    • v.38 no.4
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    • pp.301-313
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    • 2022
  • We made a Korean white porcelain or Joseon Baekja jar and based on the raw materials used and reproductions of each stage, we aimed to compare and analyze the physicochemical changes of the raw materials such as clay at each manufacturing stage, as well as identify the characteristics and correlations. Although the basic main components of clay and glaze material are similar, their texture becomes denser in the process of bisque firing pottery (Chobeol-pyeon) and glaze firing pottery (Jaebeol-pyeon), and we confirmed that in addition to the tendency of increasing vitrification, low-temperature minerals such as mica and illite gradually disappeared, while high-temperature minerals such as cristobalite were newly created. This phenomenon has also been verified by the rapid decrease in absorption rate while the change in specific gravity was small. In addition, the color was greatly affected by the firing atmosphere, and the yellow-red chromaticity of the raw materials was higher during bisque firing but showed a rapidly decreasing characteristic during glaze firing. The value of magnetic susceptibility, which is related to iron (Fe) component, showed a tendency to decrease in glaze firing pottery. CT images were confirmed as a method that can indirectly estimate the change in the material properties of the object step-by-step for the entire object. In conclusion, the study of manufacturing stages of reproduction can provide basic data for scientific research on the estimation of porcelain and pottery making technology and changes in raw materials.

Properties of Kaolinite as a Raw Material for Porcelain

  • Kim, Jong-Young;Hwang, Kwang-Taek
    • Journal of the Korean Ceramic Society
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    • v.56 no.6
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    • pp.566-576
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    • 2019
  • In this work, we investigated kaolinite raw materials from China, Vietnam, and Seongju (Korea) used for the manufacture of porcelain products in Korea. According to chemical analysis results, for the kaolinites from Seongju, more feldspar components containing CaO, K2O, and Na2O are found than in those from China or Vietnam, of which the composition is close to that of pure kaolinite. Through X-ray Rietveld quantitative analysis, kaolinite and muscovite are found to be the main phases for all the raw materials. Halloysite, quartz, gibbsite, and andesine are found at more than 5% for KM-85 (China), LKC-60 (Vietnam), KC-009 (China), and WA (Seongju). Absorption rate is on order of LKC-60 < KC-009 < KM-85 < PA < WA, and the sample, sintered in reductive atmosphere, exhibits the lowest absorption rate. Comparing the color of the sintered samples, kaolinites of KM-85, LKC-60, and KC-009 (L*: 94 - 97%) show higher whiteness value than those of WA and PA (L*: 82 - 91%).