• 한국전기전자재료학회논문지
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• 제27권11호
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• pp.736-739
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• 2014

In this paper, we propose a enhanced anti-corrosion property of the ground system by coating the CNT/PVDF composite film on it. Polymer material used for preventing the corrosion of ground system is polyvinylidene fluoride (PVDF), and conducting filler for obtaining conductivity of the composite film is multi-walled carbon nanotubes (MWCNTs). The MWCNTs were dispersed in the organic solvent of methyl ethyl ketone 2-butanone (MEK) with different concentration ratios, and the PVDF was solved in the MEK solvent with constant concentration ratio of 1 wt%. The CNT/PVDF composite solution was perpared by mixing and re-dispersing the CNT solution and the PVDF solution. Finally, the CNT/PVDF composite films were fabricated by the spray coating method using the above composite solution. Electrical conductivity, surface states, and anti-corrosion property of the CNT/PVDF composite films coated on the Cu substrate were evaluated. We found that the CNT/PVDF composite film showed relatively low resistance, hydrophobic surface state, and chemical stability. Consequently, we could improve the anti-corrosion property and maintain the electrical conductivity of the ground system by coating the CNT/PVDF composite film on it.

• Journal of Mechanical Science and Technology
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• 제16권10호
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• pp.1222-1228
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• 2002

This research is the development of a flexible tactile sensor array for service robots using PVDF (polyvinylidene fluoride) film for the detection of a contact state in real time. The prototype of the tactile sensor which has 8${\times}$8 array using PVDF film was fabricated. In the fabrication procedure, the electrode patterns and the common electrode of the thin conductive tape were attached to both sides of the 281$\mu\textrm{m}$ thickness PVDF film using conductive adhesive. The sensor was covered with polyester film for insulation and attached to the rubber base for a stable structure. The proposed fabrication method is simple and easy to make the sensor. The sensor has the advantages in the implementing for practical applications because its structure is flexible and the shape of the each tactile element can be designed arbitrarily. The signals of a contact force to the tactile sensor were sensed and processed in the DSP system in which the signals are digitized and filtered. Finally, the signals were integrated for taking the force profile. The processed signals of the output of the sensor were visualized in a personal computer, and the shape and force distribution of the contact object were obtained. The reasonable performance for the detection of the contact state was verified through the sensing examples.

• Environmental Engineering Research
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• 제20권3호
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• pp.223-229
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• 2015

The application of coagulation for feed water pretreatment prior to microfiltration (MF) process has been widely adopted to alleviate fouling due to particles and organic matters in feed water. However, the efficiency of coagulation pretreatment for MF is sensitive to its operation conditions such as pH and coagulant dose. Moreover, the optimum coagulation condition for MF process is different from that for rapid sand filtration in conventional drinking water treatment. In this study, the use of response surface methodology (RSM) was attempted to determine coagulation conditions optimized for pretreatment of MF. The center-united experimental design was used to quantify the effects of coagulant dose and pH on the control of fouling control as well as the removal organic matters. A MF membrane (SDI Samsung, Korea) made of polyvinylidene fluoride (PVDF) was used for the filtration experiments. Poly aluminum chloride (PAC) was used as the coagulant and a series of jar tests were conducted under various conditions. The flux was $90L/m^2-h$ and the fouling rate were calculated in each condition. As a result of this study, an empirical model was derived to explore the optimized conditions for coagulant dose and pH for minimization of the fouling rate. This model also allowed the prediction of the efficiency of the coagulation efficiency. The experimental results were in good agreement with the predictions, suggesting that RSM has potential as a practical method for modeling the coagulation pretreatment for MF.

• Journal of Microbiology and Biotechnology
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• 제25권11호
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• pp.1908-1919
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• 2015

This work investigated the potential of curcumin (CCM) and (-)-epigallocatechin gallate (EGCG) to inhibit N-acyl homoserine lactone (AHL)-mediated biofilm formation in gram-negative bacteria from membrane bioreactor (MBR) activated sludge. The minimum inhibitory concentrations (MICs) of CCM alone against all the tested bacteria were 200-350 μg/ml, whereas those for EGCG were 300-600 μg/ml. Biofilm formation at one-half MICs indicated that CCM and EGCG alone respectively inhibited 52-68% and 59-78% of biofilm formation among all the tested bacteria. However, their combination resulted in 95-99% of biofilm reduction. Quorum sensing inhibition (QSI) assay with known biosensor strains demonstrated that CCM inhibited the expression of C4 and C6 homoserine lactones (HSLs)-mediated phenotypes, whereas EGCG inhibited C4, C6, and C10 HSLs-based phenotypes. The Center for Disease Control biofilm reactor containing a multispecies culture of nine bacteria with one-half MIC of CCM (150 μg/ml) and EGCG (275 μg/ml) showed 17 and 14 μg/cm² of extracellular polymeric substances (EPS) on polyvinylidene fluoride membrane surface, whereas their combination (100 μg/ml of each) exhibited much lower EPS content (3 μg/cm²). Confocal laser scanning microscopy observations also illustrated that the combination of compounds tremendously reduced the biofilm thickness. The combined effect of CCM with EGCG clearly reveals for the first time the enhanced inhibition of AHL-mediated biofilm formation in bacteria from activated sludge. Thus, such combined natural QSI approach could be used for the inhibition of membrane biofouling in MBRs treating wastewaters.

• Journal of Biosystems Engineering
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• 제33권1호
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• pp.30-37
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• 2008

Dynamic excitation and response analysis is an acceptable method to determine some of physical properties of agricultural product for quality evaluation. There is a difference in the internal viscoelasticity between sound and defective fruits due to the difference of geometric structures, thereby showing different vibration characteristics. This study was carried out to develop a portable piezoelectric film-based glove sensor system that can separate internally damaged watermelons from sound ones using an acoustic impulse response technique. Two piezoelectric sensors based on polyvinylidene fluoride (PVDF) films to measure an impact force and vibration response were separately mounted on each glove. Various signal parameters including number of peaks, energy ratio, standard deviation of peak to peak distance, zero-crossing rate, and integral value of peaks were examined to develop a regression-estimated model. When using SMLR (Stepwise Multiple Linear Regression) analysis in SAS, three parameters, i.e., zeros value, number of peaks, and standard deviation of peaks were selected as usable factors with a coefficient of determination ($r^2$) of 0.92 and a standard error of calibration (SEC) of 0.15. In the validation tests using twenty watermelon samples (sound 9, defective 11), the developed model provided good capability showing a classification accuracy of 95%.

• 한국항공우주학회지
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• 제31권2호
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• pp.51-56
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• 2003

압전필름센서는 우수한 동적 감지 특성을 갖고 있어 복합재 구조의 저속충격을 모니터링하는데 유용하게 사용될 수 있다. 복합재 샌드위치 보에 대한 충격응답함수를 유도하였으며, 이를 충격시험와 비교하였따. 충격시험은 손상이 발생하지 않는 저에너지 조건에서 계측장치가 부착된 낙하식 충격시험기를 이용하여 수행하였다. 충격하중에 으한 샌드위치보의 거동을 예측하는 정방향 문제와 압전필름센서 신호로부터 충격력을 복원하는 역방향 문제에서 시험과 해석의 결과는 잘 일치하였다. 본 연구를 통하여 압전필름센서를 이용한 복합재 샌드위치 구조의 저속충격 모니터링 가능성을 확인하였다.

• 한국수소및신에너지학회논문집
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• 제18권3호
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• pp.223-229
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• 2007

여과막 생물반응기를 이용하여 $60^{\circ}C$에서 혐기 세균 복합체가 포도당으로부터 수소를 생산할 수 있는 최적조건을 연구하였다. 여과막 생물반응기는 연속교반 탱크반응기와 외부에 장착된 PVDF (polyvinylidene fluoride) 중공사막 여과장치로 구성되었다. 접종슬러지는 하수처리장 소화 슬러지조에서 얻었고, 포자형성 수소생산 미생물을 얻기 위해 $90^{\circ}C$에서 20분 간 열처리하였다. 16S rRNA PCR-DGGE(polymer chain reaction-denaturing gradient gel electrophoresis) 분석을 통해 열처리 전후의 미생물상 변화를 조사하였다. 열처리 후 DGGE 밴드의 수는 감소하였고, 주요 밴드는 Clostridium perfringens와 유사한 염기서열을 나타내었다. 운전 기간 동안 바이오가스 내 수소함량은 60%(v/v)를 유지하였고, 메탄은 검출되지 않았다. 연속교반 탱크반응기를 여과막 없이 수력학적 체류 4시간에서 운전하였을 때 공급된 포도당의 95.0%가 제거되었고, 이때 균체농도 및 수소생산속도는 각각 1.35 g cell/L 및 7.4 L $H_2$/L/day이었다. 동일한 체류시간에서 PVDF중공사막 여과장치를 장착하여 연속교반 탱크반응기를 운전하였을 때, 균체농도는 1.62 g cel/L로 증가하였고 높은 포도당 제거율(99.5%) 및 수소생산속도(8.8 L $H_2$/L/day)가 관찰되었다. 40 nm 및 100 nm의 공극크기를 가진 여과막은 균체농도 및 수소생산 측면에서 유사한 성능을 나타내었다. 여과막 생물반응기는 여과막의 반복적인 세척을 통해 30일 이상 안정적으로 운전될 수 있었다.

• 한국전기전자재료학회논문지
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• 제21권10호
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• pp.881-884
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• 2008

In this study, polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) in the composition from 51/49, was deposited on platinum for a metal-ferroelectric-metal structure. From XRD patterns, the 70 nm- and 140 nm-thick PVDF-TrFE films showed the intensity peak of near $20^{\circ}$ connected to a ferroelectric phase. Moreover, the thicker film indicated the higher intensity than thinner one. The difference of the remanent polarization (2Pr) at 0 V is decreased gradually from 10.19 to $5.7{\mu}C/cm^2$ as the thickness decrease from 140 to 70 nm. However, when the thickness decreased to 50 nm, the 2Pr rapidly drop to $1.6{\mu}C/cm^2$ so the minimum critical thickness might be at least 70 nm for device. Both different thickness films, 70 and 140 nm, indicated that the characteristic of current density-voltage was measured for $10^{-6}{\sim}10^{-7}A/cm^2$ below 15 V and the thicker film maintained relatively lower current density than thinner one. From these results, we can expect that the electrical properties for the devices particularly ferroelectric thin film transistor using PVDF-TrFE copolymer were able to be on the trade-off relationship between the remanent polarization with the bias voltage and the leakage current.

• 한국환경보건학회지
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• 제29권2호
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• pp.69-76
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• 2003

Hexavalent chromium may reduce on polyvinyl chloride (PVC) filter during sampling and storage of sample. Recently, new or modified filters for preventing Cr(VI) from the reduction has been introduced. Thus, this study was performed to compare the reduction behaviors of Cr(VI) on several sampling filters and to find the most appropriate filter for airborne Cr(VI) sampling in plating operation. The results were as follows. 1. There were statistically significant differences among PVC, polytetrafluoroethylene (PTFE). glass fiber (GF) and polyvinylidene fluoride (PVDF) filters in recovery rates of spiked Cr(VI) samples by storage time(p<0.05). There was no significant difference between PVC and PTFE filters(p>0.05). The PVC and PTFE filters showed higher recoveries than GF and PVDF filters(p<0.05). 2. The quartz fiber(QF) filter treated with an alkali solution(2% NaOH/3% Na$_2$CO$_3$, 1% NaOH) showed a significantly higher recovery of Cr(VI) by storage time than other filters(GF and QF filter)(p<0.05). There was no difference in recovery of Cr(VI) between alkali-treated and untreated GF it filters(p>0.05). But the QF filters treated with two alkali solution showed a significantly higher recovery than the untreated QF filter(p<0.05). There was no significant difference in recovery of Cr(VI) between QF filters treated with 1% NaOH and 2% NaOH/3% Na$_2$CO$_3$(p>0.05). In conclusion, treatment of QF fillers with alkali solution was most effective in protecting from the reduction of Cr(VI).

• 한국인터넷방송통신학회논문지
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• 제12권5호
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• pp.91-97
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• 2012

근래의 전기 전자 제품은 기능은 향상되는 반면 크기는 소형화되는 추세에 있다. 기존 입체 형태의 음향 신호 재생 장치로서의 엑츄에이터 대신 압전 소자를 이용한 스피커가 개발되기 시작하였다. 압전 소자는 압전 특성을 갖는 물질로서 물체의 외부에서 전압을 가할 때 기계적인 변형을 일으키는 특징(즉 피에조 특징)을 이용한다. 초기의 필름 스피커는 화학적 성질의 한계로 인하여 전도성 고분자 막을 형성하기 힘들다는 한계가 있었고, 도포한 두께를 균일하게 유지하기 힘들었으며, 음향 신호의 출력과 동작 주파수의 한계가 있다는 등의 종래 기술의 문제점을 해결하기 위해, 전도 물질과 피에조 물질(필름)의 결합력을 증가시킴으로써 전도체의 저항을 줄이고 주파수 영역을 확장하고자 한다. 피에조 필름의 표면 접착력을 향상시키고, 고분자 전도체 막의 흡착력을 증가시킴으로써 음향시스템의 출력 향상을 위해 코로나 표면처리방식에 의한 표면 특징을 변화시킴으로써 출력개선을 하였다.