• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.416-424
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• 2018

Oil spill and oily wastewater have now become a serious threat to the freshwater and marine environments. Porous materials with super-hydrophobicity and super-oleophilicity are good candidates for the oil adsorption and oil/water separation. Here, flexible hybrid nanofibrous membrane (FHNM) containing $SiO_2$/polyvinylidene fluoride (PVDF) microspheres was prepared by simultaneous electrospinning and electrospraying. The obtained FHNM combined the flexibility of the nanofiber mat and super-hydrophobicity of the microspheres, which could not be achieved by either only electrospinning or only electrospraying. It was found that when the weight ratio between the $SiO_2$ and PVDF reached a critical value, the $SiO_2$ nanoparticles were present on the PVDF microsphere surface, significantly improving the surface roughness and hence the contact angle of the FHNM. Compared with the pure electrospun PVDF nanofiber mat, most of the FHNMs have a higher oil adsorption capacity. The FHNM could separate the oil with water quickly under the gravity and displayed a high efficiency and good reusability for the oil/water separation. More importantly, the FHNM could not only separate the oil with the pure water but also the corrosive solution including the salt, acid and alkali solution.

• Smart Structures and Systems
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• 제5권1호
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• pp.23-42
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• 2009

In order to reduce vibration or to control shape of structures made of metal or composites, piezoelectric materials have been extensively used since their discovery in 1880's. A recent trend is also seen to apply piezoelectric materials to flexible structures made of rubber-like materials. In this paper a non-linear finite element model using updated Lagrangian (UL) approach has been developed for static analysis of rubber-elastic material with surface-bonded piezoelectric patches. A compressible stain energy function has been used for modeling the rubber as hyperelastic material. For formulation of the nonlinear finite element model a twenty-node brick element is used. Four degrees of freedom u, v and w and electrical potential ${\varphi}$ per node are considered as the field variables. PVDF (polyvinylidene fluoride) patches are applied as sensors/actuators or sensors and actuators. The present model has been applied to bimorph PVDF cantilever beam to validate the formulation. It is then applied to study the smart rubber components under different boundary and loading conditions. The results predicted by the present formulation are compared with the analytical solutions as well as the available published results. Some results are given as new ones as no published solutions available in the literatures to the best of the authors' knowledge.

• Membrane and Water Treatment
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• 제12권1호
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• pp.23-35
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• 2021

A POM-membrane was fabricated by immobilizing a keggin type polyoxometalate (POM) H5PV2Mo10O40 onto the surface of microporous flat-sheet polymeric polyvinylidene fluoride (PVFD) membrane using a chemical deposition method. The POM-membrane was characterized by FT-IR, SEM and EDX to confirm existing of the POM onto the membrane surface. The POM-membrane was used to remove an anionic textile dye (Reactive Black 5 named as an RB5) from aqueous phases with a cross-flow membrane filtration and a batch adsorption system. The dye removal efficiency of the POM-membrane using the cross-flow membrane filtration system and the batch adsorption system was about 88% and 98%, respectively. The influence factors such as contact time, adsorbent dosage, pH, and initial dye concentration were investigated to understand the adsorption mechanism of the RB5 dye onto the POM-membrane. To find the best fitting isotherm model, Langmuir, Freundlich, BET and Harkins-Jura isotherm models were used to analyze the experimental data. The isotherm analysis showed that the Langmuir isotherm model was found to the best fit for the adsorption data (R2 = 0.9982, qmax = 24.87 mg/g). Also, adsorption kinetic models showed the pseudo second order kinetic model was found the best model to fit the experimental data (R2 = 0.9989, q = 8.29 mg/g, C0 = 15 ppm). Moreover, after four times regeneration with HNO3 acid, the POM-membrane showed high regenerability without losing dye adsorption capacity.

• Membrane and Water Treatment
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• 제13권4호
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• pp.173-181
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• 2022

Polyvinylidene fluoride (PVDF) flat sheet hydrophobic membranes were prepared using 16 wt% PVDF in Dimethyl acetamide (DMAc) by phase inversion technique for desalination application using Membrane Distillation (MD). In this work, the effect of coagulation mediums such as ethanol and water as well their synergistic behavior on the fabricated PVDF membrane morphology was studied using SEM. Moreover, other characteristics required for the membrane distillation applications namely porosity, hydrophobicity and tensile strength were measured using the gravimetric method, sessile drop method and universal testing machine respectively. It was observed that the membrane morphology paradigm shifted from the finger-like structure to the sponge-like structure on increasing the ethanol concentration in coagulant. The porosity of the fabricated membrane was under the required MD range and found to be 57.3% at 16 weight % of PVDF in DMAc solvent under a pure ethanol coagulant bath. Moreover, the top surface contact angle ranges from 85° to 115° on increasing the bath concentration from CBC 0 to CBC 100 at 16 weight % of PVDF in DMAc solvent.

• 산업기술연구
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• 제42권1호
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• pp.7-12
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• 2022

High nickel layered oxide cathodes are gaining increasing attention for lithium-ion batteries due to their higher energy density and lower cost compared to LiCoO₂. However, they suffer from the formation of residual lithium on the surface in the form of LiOH and Li₂CO₃ on exposure to ambient air. The residual lithium causes notorious issues, such as slurry gelation during electrode preparation and gas evolution during cell cycling. In this review, we investigate the residual lithium issues through its impact on cathode slurry instability based on deformed polyvinylidene fluoride (PVdF) as well as its formation and reduction mechanism in terms of inherently off-stoichiometric synthesis of high nickel cathodes. Additionally, new analysis method with anhydrous methanol was introduced to exclude Li⁺/H⁺ exchange effect during sample preparation with distilled water. We hope that this review would contribute to encouraging the academic efforts to consider practical aspects and mitigation in global high-energy-density lithium-ion battery manufacturers.

• 비파괴검사학회지
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• 제22권1호
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• pp.1-8
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• 2002

PVDF 및 P(VDF-TrFE) 고분자 압전박막을 이용하여 고주파수 수침용 초음파 탐촉자를 제작한 다음 그 특성을 비교 평가하였다. 탐촉자와 탐상기 사이의 신호전송용 동축케이블의 길이가 고주파수 초음파 검출장에 영향을 미치는 것으로 나타났다. 초음파 빔의 초점이 형성되는 반사체가 편평할수록 고주파수 초음파 검출장은 감소하는 것으로 나타났으며 3mm 직경의 PVDF 탐촉자의 경우 0.5mm 강구에서 약 100MHz의 광대역 고주파수 초음파 검출장을 형성하였다. PVDF와 P(VDF-TrFE) 탐촉자를 비교한 결과 반사신호의 피크 값과 빔 폭은 P(VDF-TrFE)가 PVDF 보다 크게 나타났으나 고주파수 초음파 검출장은 PVDF가 P(VDF-TrFE)보다 광대역 특성을 나타내었다. 개발된 3mm 직경의 PVDF 탐촉자를 이용하여 표면의 깊이균열 크기가 $30{\sim}100{\mu}m$인 수소유기균열(HIC) 강재 시편을 C-scan한 결과 고감도의 분해능으로 미세 균열의 검출이 가능하였다.

• Korean Chemical Engineering Research
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• 제54권1호
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• pp.57-63
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• 2016

Polyvinylidene fluoride (PVDF) 평막 제조를 위하여 PVDF의 용매와 희석제로서 n-methyl-2-pyrrolidone (NMP)와 dibutyl-phthlate (DBP)를 각각 사용하여 열유도 상분리(thermally induced phase separation, TIPS)와 비용매유도 상분리(nonsolvent induced phase separation, NIPS)를 동시에 유도하였다. NMP와 DBP를 PVDF와 용융 혼합할 경우 TIPS 공정에서의 결정화 온도가 낮아졌고 NIPS 공정에서의 불안정 영역이 확대되었다. 용매와 희석제의 비율에 따라 상분리 메카니즘이 변화하였고 이에 따라 다양한 구조의 막이 형성됨을 확인하였다. 또한 dope 용액과 비용매의 접촉여부에 따라 지배적인 상분리 거동이 결정되었다. 열전달이 물질전달에 비하여 빠르게 이루어지므로 막의 표면은 NIPS에 의하여 지배를 받고 막의 내부는 TIPS에 의한 구조가 형성되었다. 또한 dope 용액의 급냉온도에 따라 상분리 메카니즘 및 상분리 속도가 변화하여 다양한 구조를 형성하였다.

• 상하수도학회지
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• 제18권5호
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• pp.588-597
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• 2004

In this research, we investigated the variation of transmembrane pressure and permeate water quality with pre coagulation and sedimentation with iron based coagulant and chlorination of feed water for PVDF (polyvinylidene fluoride) based MF membrane filtration. NaCIO was fed to the membrane module with dosage of 0.5mg/L and maintained during filtration. To observe the effect of raw water, three types of raw and processed waters, including river surface water, coagulated water and coagulated-settled water, were applied. In case of river surface water, the transmembrane pressure increased drastically in 500 hours of operation. On the contrary, no significant increase in transmembrane pressure was observed for 1,200 hours of operation for coagulated water and coagulated-settled waters. The turbidity of permeate was lower than a detection limit of equipment for all raw waters. The removal efficiency of humic substances of coagulated water and coagulated-settled water was approximate ten times of that of surface river water. And, the removal efficiency of TOC and DOC was approximate two times of that of surface river water. From the results of plant operation, stable operation was maintained at $0.9m^3/m^2{\cdot}day$ filtration flux through the combination of pre-coagulation and pre-chlorination. However, the water quality of permeate was the best when pre-coagulation-sedimentation process was combined with pre-chlorination.

• Composites Research
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• 제15권2호
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• pp.11-17
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• 2002

우수한 동적 감지특서을 갖는 압전필름센서는 구조 건전성 모니터링이나 평가와 같은 구조물과 재료의 변화를 분석하는데 사용될 수 있다. 압전필름센서의 이러한 특성을 이용하여 Gr/Ep 복합재 평판의 충격 손상개시를 모니터링하였다. 압전필름센서와 스트레인게이지를 Gr/Ep 복합재 평판에 부착하여 다양한 조건의 에너지에 대한 충격시험을 낙하식 충격 시험기를 사용하여 수행하였다. 충격시험을 수행하는 동안 영구압입, 기지균열, 층간분리와 같은 충격 손상개시를 예측하기 위하여 센서신호를 분석하였다. 충격에너지를 초기 손상이 발생할 수 있는 크기 이상으로 증가시키면 손상의 개시와 진전에 대한 정보를 포함하는 특정 센서 신호를 관찰할 수 있었다. 특히, 압전필름세서는 스트레인게이지 보다 충격 손상개시 및 진전에 대한 좋은 감지 특성을 보여주었다.

• Composites Research
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• 제18권6호
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• pp.26-33
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• 2005

손상이 발생할 경우 복합재료의 기계적 물성치는 급격한 저하를 유발한다 특히, 조류충돌, 우박, 지상 이착륙 상황에서의 타이어 조각이나 돌조각 등과 같은 작은 질량에 의한 고속충격은 구조물과 서브시스템에 심각한 손상을 유발한다. 이런 복합재 적층판에서의 손상은 기존의 전통적인 방법으로 감지하기가 어려우며, 단일 감지 기술만을 이용하여 믿을 만한 손상평가 결과를 얻을 수 없다. 본 논문에서는 고분자 압전필름 센서를 이용하여 복합 적층판에서의 충격에 의한 손상의 개시 시점 및 확장을 탐지하였다. 획득한 센서신호는 시간-주파수 분석법인 웨이블릿 변환과 단시간 푸리에 변환을 적용하였으며, 초음파 C-scan과 전자현미경을 이용하여 시편에서의 손상 확장을 검사하였다 이 연구에서는 다양한 감지기술, 특히 고분자 압전 필름센서를 이용하여 복합재 적층판에서의 고속충격 손상 특성을 확인하였다.