• Title/Summary/Keyword: Polyvinyl

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A comprehensive review of microplastics: Sources, pathways, and implications (미세 플라스틱의 종합적 고찰: 근원, 경로 및 시사점)

  • Yano, K.A.V.;Reyes, N.J.D.G.;Geronimo, F.K.F.;Jeon, M.S.;Kim, Y.;Kim, L.H.
    • Journal of Wetlands Research
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    • v.22 no.2
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    • pp.153-160
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    • 2020
  • Most studies defined microplastic (MP) as plastic particles less than 5 mm. The ubiquity of MP is raising awareness due to its potential risk to humans and the environment. MP can cause harmful effects to humans and living organisms. This paper review aimed to provide a better understanding of the sources, pathways, and impacts of MP in the environment. MP can be classified as primary and secondary in nature. Moreover, microplastic can also be classified as based on its physical and chemical characteristics. Stormwater and wastewater are important pathways of introducing MP in large water bodies. As compared to stormwater, the concentrations of MP in wastewater were relatively lower since wastewater treatment processes can contribute to the removal of MP. In terms of polymer distribution, wastewater contains a wider array of polymer varieties than stormwater runoff. The most common types of polymer found in wastewater and stormwater runoff were polypropylene (PP), polyvinyl chloride (PVC), polystyrene (PS), polyethylene (PE) and polyethylene terephthalate (PET). The continuous discharge and the increasing number of MP in the environment can pose greater hazards and harmful effects on humans and other living organisms. Despite the growing number of publications in relation to MP, further studies are needed to define concrete regulations and management strategies for mitigating the detrimental effects of MP in the environment.

Preparation of Silver Nanoparticles Using AgNO3 Precursor as Carrier for Olefin/Paraffin Separation and the Effect Analysis of NO3- (올레핀/파라핀 분리용 운반체로서 AgNO3 전구체를 활용한 은 나노입자 제조 및 NO3-의 효과 분석)

  • kim, Minsu;Kang, Sang Wook
    • Membrane Journal
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    • v.28 no.4
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    • pp.265-270
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    • 2018
  • In previous studies, a poly(ethylene oxide)(PEO)/Ag nanoparicles (AgNPs)(precursor $AgBF_4$)/p-benzoquinone (p-BQ) composite membrane was prepared for olefin/paraffin separation and the performance of this composite membrane was maintained at a selectivity of 10 and a permeability of 15 GPU. However, since the price of $AgBF_4$ precursor is high, this study used $AgNO_3$ as a precursor of Ag nanoparticles which is competitive in terms of price. As a result, it was observed that the separation performance was not obtained because the existing $NO_3{^-}$ could surround AgNPs. In this study, we fabricated PEO, poly(vinyl alcohol)(PVA), and polyether block amide-1657 (PEBAX-1657) polymer composite membrane using electron acceptor 7,7,8,8-tetracyanoquinodimethane (TCNQ) for separation performance even when $AgNO_3$ was used as a precursor of Ag nanoparticles. As a result, it was analyzed that the performance was not observed regardless of the influence of the polymer and the electron acceptor, indicating that the anion of the precursor plays a crucial role in the separation performance.

Effects of Polymer Coating on Seed Vigour in Rice (벼 종자의 Polymer 피복처리가 종자세에 미치는 영향)

  • 이성춘;정춘화;김진희;송동석
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.3
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    • pp.274-285
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    • 1996
  • These experiments were conducted to evaluate the effects of seed coating with ten environmentally acceptable polymers, on germination percentage, water uptake, respiration, emergence and seedling growth characteristics. The water absorption of polymer-coated seeds in saturation condition was highest in klucel and lowest in polyvinyl pyrrolidone(PVP), and that in water was highest in klucel and lowest in maltrin. Respiration rates of polymer-coated seeds in Hwayoungbyeo and Ilpumbyeo were lower than those of none-coated seeds, and those in Daecheongbyeo and Jinmibyeo were higher than that of none-coated seeds, and those of sepiret coated seeds were higher than PVP coated seeds. The germination polimer-coated seed was reduced by one percentage by coating with seed coating machine. Germination percentage was not affected by any of polymer coating in high quality seed, but there were significant effects in low quality seed coating with waterlock, surelease 46 and sepiret significantly reduced germination some cultivars. Germination percentage after accelated ageing treatment were slightly higher most of polymer-coated seeds than in none-coated seeds, but those of sepiret-and klucel-coated seeds were lower significantly. Germination percentage of seeds coated with daran 8600, rnaltrin, sacrust and opadry were enhanced slightly under cold test other polimers reduced germination. The seedling height of polymer-coated seeds were longer than those of none-coated seeds, but those of waterlock, PVP and maltrin coating seeds were shorter, seedling hight was shortened by polimer coating under cold test. Polymer-coated seeds showed higher emergence percentage, shorter emergence time in field condition. The highest emergence percentage and the shortest emergence time was shown at 90% soil moisture content.

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Study on the Top-Gate Pentacene Thin Film ransistors Using Solution Processing Polymeric Gate Insulator (용액 공정 고분자 게이트 절연체를 이용한 Top-Gate 펜타센 박막 트랜지스터에 관한 연구)

  • Hyung, Gun-Woo;Kim, Jun-Ho;Seo, Ji-Hoon;Koo, Ja-Ryong;Seo, Ji-Hyun;Park, Jae-Hoon;Jung, Young-Ou;Kim, You-Hyun;Kim, Woo-Young;Kim, Young-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.388-394
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    • 2008
  • 본 논문에서는 용액 공정을 이용한 고분자 절연층을 갖는 top-gate 구조의 펜타센 박막 트랜지스터(Thin Film Transistor, TFT)의 특성을 연구하였다. Top-gate 구조의 펜타센 TFT 제작에 앞서 유기 반도체인 펜타센의 결정성 성장을 돕기 위해서 가교된 PVP (cross-linked poly(4-vinylphenol))를 유리 기판 상에 스핀 코팅을 이용하여 형성한 후, 노광 공정을 통해 니켈/은 구조를 갖는 채널 길이 $10{\mu}m$의 소오스, 드레인 전극을 형성하였다. 그리고 열 증착을 이용하여 60 nm 두께의 펜타센 층을 성막하였고, 고분자 절연체로서 PVA(polyvinyl alchol) 또는 가교된 PVA를 용액공정인 스핀 코팅을 이용하여 형성한 후 열 증착으로 알루미늄 게이트 전극을 성막하였다. 이로써 제작된 소자들의 전기적 특성을 확인한 결과 가교된 PVA를 사용한 펜타센 TFT 보다 PVA를 게이트 절연체로 사용한 소자가 전기적 특성이 우수한 것으로 관찰되었다. 이는 PVA의 가교 공정에 의한 펜타센 박막의 성능 퇴화에 기인한 것으로 사료된다. 실험 결과 $0.9{\mu}m$ 두께의 PVA 게이트 절연막을 사용한 top-gate 구조의 펜타센 TFT의 전계 효과 이동도와 문턱전압, 그리고 전류 점멸비는 각각, 약 $3.9{\times}10^{-3}\;cm^2/Vs$, -11.5 V, $3{\times}10^5$으로써 본 연구에서 제안된 소자가 용액 공정형 top-gate 유기 TFT 소자로서 우수한 성능을 나타냄을 알 수 있었다.

Flexural Performance of Cement Treated Clay-Sand Mixtures Reinforced with Synthetic Fibers (합성섬유로 보강된 시멘트-점토-모래 혼합토의 휨성능 평가에 관한 연구)

  • Jung, Du-Hwoe;Cho, Baik-Soon;Lee, Yong-Yun
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.1
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    • pp.19-29
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    • 2017
  • The effects of synthetic fibers, cement content, and sand content on the flexural performance of cement-clay-sand mixtures has been evaluated through a flexural performance test with a third-point loading. Beam specimens for the flexural performance test were fabricated with a various amount of cement, sand, and synthetic fibers. Two types of fibers, PVA (Polyvinyl alcohol) and PP (Polypropylene) fibers, were employed in the test. The test results have exhibited that the factors considered in the test have significant effects on the flexural performance of the mixtures in several aspects. The flexural performance of the mixtures has been improved if the mixtures were reinforced with synthetic fibers. The flexural strength and the flexural toughness of the mixtures has been increased as the fiber content was increased. A multiple linear regression analysis has been performed to evaluate the effect of fiber content, cement dosage, and sand content on the flexural performance of the mixtures in terms of flexural strength and flexural toughness. Cement content and sand content were estimated as important factors to have an influence on the first-crack strength and the peak strength whereas the fiber content has the most significant influence on the post-crack behavior. The first-crack strength and the ultimate strength were increased as the cement content and the sand content were increased. As the fiber content was increased, the flexural toughness was increased.

Viability of eggs, filariform larvae and adults of Stronglyloides venezuelensis (Nematoda: Strongyloidea) maintained in vitro (베네수엘라분선충 (Strongvloides venezuelensis)의 충란, 감염자충 및 성충의 실험관 내 배양)

  • ;M.
    • Parasites, Hosts and Diseases
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    • v.36 no.2
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    • pp.99-108
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    • 1998
  • The present study was performed to check the viability of eggs, filariform larvae and adults of Strongvloines venezueLensis exposed to various conditions for an in vitro maintenance. The eggs in the feces remained viable for about 25 days at $4^{\circ}C$ and 15 days at room temperature. However, the isolated eggs in sterile saline lost their viability within 24 hr at $4^{\circ}C$. The eggs in morula stage were very sensitive to air drying and rapidly lost their viability (=12 hrs. Filariform larvae survived for a maximum period of 45 days in fecal suspension and 28 days in 0.12% nutrient broth in polyvinyl culture bags maintained at $20^{\circ}C$. On the other hand, those isolated from nutrient broth cultures survived for a maximum period of 32 days in tap water and 22 days in sterile saline at $20^{\circ}C$. The mature adult worms obtained from experimentally infected rats survived maximally for 9 days in serum supplemented (10% rat-serum) 0.12% nutrient broth and 4 days in serum free nutrient broth at $37^{\circ}C$ while the culture media were changed at an alternate day. The adult female worms deposited fertile eggs in serum supplemented and serum free nutrient broth cultures, however, the hatched larvae (Ll) were not able to develop to the filariform stage in the culture media and found to die within 24 hr of maintenance. The present findings on an in vitro maintenance of different stages of 5. uenezueLetis may provide useful information for biological and biochemical studies with Strongyloines species. Key words: Strongvloides venezuelensis. viability in vitro maintenance, free-living filariform larvae (L3), embryonation of eggs

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In Vitro Production of Bovine Embryos by Modification of Simple Defined Culture Medium (단순한정배양액의 성분조정에 의한 소 수정란의 체외생산)

  • 노상호;윤종택;한기영;이병천;황우석
    • Journal of Embryo Transfer
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    • v.13 no.3
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    • pp.235-243
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    • 1998
  • In this study, we investigated the effects of three kinds of culture medium (Charles and Rosenkrans; CRlaa, Tyrode's; TALP, synthetic oviduct fluid: SOF), insulin transferrin + selenium complex (ITS), macromolecules(polyvinyl alcohol: PVA, fetalb-ovine serum: FBS) and NaCl on the development of early bovine embryos. In experiment 1, there were no differences in embryo development among three kinds of embryo culture medium (CR $l_{aa}$ , TALP, SOF). In experiment 2, BSA, FBS and PVA were added each in TALP as macromolecule sources. The developmental rates of embryos in BSA or FBS added TALP were significantly higher than in PVA added one (p〈0.01), but there was no difference between BSA and FBS added groups. In experiment 3, bovine embryos were cultured in TALP with the following supplements: BSA alone(1, 3 or 8 mg/ml, each) or BSA(1, 3 or 8 mg/ml, each)+ITS (10$\mu\textrm{g}$/m1 insulin, 5 $\mu\textrm{g}$/ml transferrin, 5 ng/ml selenium). In higher concentration of BSA and ITS supplemented groups, the developmental rates over compacted morula were higher than others, but there was a significant effect of ITS only in 1 mg/ml of BSA added group (p〈0.05). In experiment 4, the effect of reduced concentration of NaCl was evaluated. The developmental rate over compacted morula in the medium containing 90 mM of NaCl was higher than in 114 mM group (p〈0.05). In conclusion, BSA could be used as a macromolecule source in bovine embryo culture, and ITS, as a serum substitute, could be used for improving of embryonic development. Also, reduction of NaCl concentration from 114 mM to 90 mM may improve the development of bovine embryos.bryos.

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Study on the Tracking Characteristics Depending on Accelerated Degradation of PVC Insulation Material (PVC 절연재료의 가속열화에 따른 트래킹 특성에 관한 연구)

  • Choi, Su-Gil;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.31 no.6
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    • pp.91-98
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    • 2017
  • The present paper is a study on the tracking characteristics depending on accelerated degradation of PVC insulation material. In order to insulation degradation of PVC insulation material, the Arrhenius equation, a type of accelerated degradation test formula, was used to conduct accelerated degradation experiments with experiment samples prepared at the following age equivalents: 0, 10, 20, 30 and 40 years. Afterwards, a tracking experiment was conducted on the accelerated experiment samples as part of the KS C IEC 60112 criteria. When measuring the PVC tracking features according to the accelerated aging, the results showed that when 0.1% of ammonium chloride was added to the PVC insulating material, but no tracking occurred. However, depending on the age equivalent, The results of analyzing the current waveform and voltage waveform of the tracking propagation process showed the age equivalent from 0 years to 40 years displayed a break down in insulation resistance and even the BDB(before dielectric breakdown) sections did not maintain the same functionality of the original material. Based on a criterion of an age equivalent of 0 years, material with an age equivalent of 10 years posed a 1.4 times greater risk, material with an age equivalent of 20 years posed a 2 times greater risk, material with an age equivalent of 30 years posed a 4.6 times greater risk, and material with an age equivalent of 40 years posed a 7 times greater risk.

Processing of Low Salt Mackerel Fillet and Quality Changes during Storage (저염 고등어 Fillet의 제조 및 저장중 품질변화)

  • Lee, Kang-Ho;Hong, Byeong-Il;Jung, Byung-Chun
    • Korean Journal of Food Science and Technology
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    • v.30 no.5
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    • pp.1070-1076
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    • 1998
  • The processing conditions of low salt mackerel (Scomber japonicus) fillet was investigated, in which fresh mackerel was filleted, salted in brine until the expected salt concentration reached, dried with cool air (3 m/sec, $10{\sim}20^{\circ}C$), and finally packed individually in polyvinyl chloride film. Salting time and salt concentration of brine decided the final salt level penetrated into the fillet. As the final salt level was fixed to $0.8{\sim}1.0%, salting for $15{\sim}20 hours with 5% or 10% brine at $5^{\circ}C$ was enough to get that level of salt. Formation of histamine during salting was negligible. Changes in VBN, salt soluble proteins, and histamine formation of salted mackerel fillet during the storage occurred more rapidly in cases of storage at $5^{\circ}C than af $-2^{\circ}C and $-20^{\circ}C. Oxidation of lipid during the storage progressed, however it was delayed longer then 100 days in case of storage at $-20^{\circ}C. Addition of sodium erythrobate or ginger extracts could provide some extent of browning retardation. The shelf-life of the salted mackerel fillet based on panel scores of brown color and rancidity appealed to be 14 days when stored at $5^{\circ}C, and more than 28 days in case of storage at $-2^{\circ}C and about 3 months stored at $-20^{\circ}C.

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Acetylcholinesterase-based Biosensor for Detection of Residual Organophosphates and Carbamates Insecticides (유기인계 및 카바메이트계 농약을 측정할 수 있는 바이오 센서의 개발)

  • Kim, Young-Mee;Kim, Jin-Young;Cho, Moon-Jae;Chang Kong-Man;Hyun, Hae-Nam;Cho, Somi K.
    • Applied Biological Chemistry
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    • v.49 no.4
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    • pp.315-321
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    • 2006
  • Inhibitors of acetylcholinesterase(AchE), such as organophosphates and carbamates, interfere the action of AchE in nerve and may lead to a severe impairment of nerve functions or even death. Therefore, insect AchE is the biological target of predominant insecticides used in agriculture. Biosensors are sensitive and can be used as dispoisable sensors for environmental control. In recent years, the use of AchEs in biosensor technology has gained enormous attention, in particular with respect to insecticide detection. The principle of biosensors using AchE as a biological recognition element is based on the inhibition the catalytic activity by the agents to be detected. We here present a strip-type biosensor based on AchE inhibition. In this study, acetylcholinesterase and PVA-SbQ(polyvinyl alcohol functionalized with methyl pyridinium methyl sulfate) were co-immobilized on immobilone-P membranes. Immobilization of the enzymes showed a stability in 6 months without activity loss in $4^{\circ}C$ storage. Enzymes immobilized on surfaces of membrane responded to organophosphates and carbamate more sensitivitive than enzyme in solution. Organophosphates and carbamates concentrations could be detected by entrapped and surface immobilized enzymes, in 5 min. For chlorpyrifos, carbofuran, cabaryl, and methidathion, the detection limits of AChE-strip were similar to that of HPLC/GC method.