• Transactions of the Korean hydrogen and new energy society
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• v.21 no.4
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• pp.313-320
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• 2010

Carbon cloth was impregnated into PTFE emulsion. PTFE is a fluoropolymer used as a coating material in various fields due to its hydrophobicity and excellent mechanical properties. In this study, PTFE emulsion was prepared different particle size of 5~500 nm and $3{\sim}5{\mu}m$. FE-SEM and FT-IR spectroscopy were used microscopic observation and investigation of chemical structure change after PTFE coating. Mass variations, gas permeability and water contact angles were analyzed to determine a GDL performance of PTFE coated carbon cloth. PTFE coated carbon cloth show different mass increase according as PTFE concentration and the number of coating times. Water contact angle of PTFE coated carbon cloth was not effected by size of PTFE particle and the number of coating time; meanwhile, gas permeability was rapidly changed at carbon cloth coated by emulsion with size of $3{\sim}5{\mu}m$ PTFE particle.

• Journal of the Korean Electrochemical Society
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• v.24 no.2
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• pp.28-33
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• 2021

Many researchers have increased the loading level of electrodes to improve the energy density of secondary batteries. In this study, high-loading NCM523 (LiNi_0.5Co_0.2Mn_0.3O₂) positive electrode is manufactured using a polytetrafluoroethylene (PTFE) binder, not the conventional polyvinylidene fluoride (PVdF) binder, which has been commonly used in lithium-ion batteries. Through the kneading process using PTFE suspension, not the conventional slurry process using PVdF solution in N-methyl-2-pyrrolidinone (NMP), thick electrodes with high loading are easily manufactured. When the PTFE and PVdF-based electrodes are prepared at a loading level of 5.0 mAh/cm², respectively, the PTFE-based electrode shows better cycle performance and rate capability than those of PVdF-based electrodes. The electrode manufactured by the kneading process using a PTFE binder has high electrode porosity due to insufficient roll-press, but the porosity can be lowered by high temperature roll-press over 120℃. However, there is no significant difference in cycle performance according to the roll press temperature. In addition, the cycle performance of the high loading electrode is slightly improved by increasing the content of the conductive material. Overall, the PTFE binder can improve the performance of the high loading electrode, but additional solutions will be needed.

• New & Renewable Energy
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• v.3 no.1 s.9
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• pp.75-82
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• 2007

Aluminum was used as metallic bipolar plate material to reduce a stack weight. The functional materials such as conductive material, Au and nonconductive material, PTFE [polytetrafluoroethylene] were coated on the bipolar plate to enhance electrical contact and corrosion prevention in PEMFC. The active area of bipolar plate is divided into the top layer part that electric current mainly passes, and the bottom layer part that gas and water pass. The bottom layer part in the flow channel needs not to have electrical conductivity because it doesn't pass electric current directly. In this reason, Au on the top layer and PTFE on the bottom layer were coated to apply high electrical conductivity and/or good corrosion resistance. Although the single cell performance using Au-PTFE/Al bipolar plate was shown 78% in comparison with that of graphite, specific power of Au-PTFE/Al bipolar plate(0.4 W/g) was twice as much as graphite bipolar plate.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.87-87
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• 2012

아라미드 레노직물은 컨베이어벨트, 건조벨트, 스크림직물, 전자산업용 이송체 등 여러 산업분야에 사용되고 있다. 레노는 2D 구조의 메쉬 형태 직물이고 치수안정성이 낮다. 그렇기 때문에 치수안정성을 부여할 수 있는 후가공이 필요하며, 현재는 치수안정성을 부여하고 여러 물성보완과 내수성을 향상시키기 위해 PTFE(Polytetrafluoroethylene) 코팅을 하고 있다. 우리는 이러한 PTFE코팅의 영향을 분석하기 위해 강도, 탄성률, 열팽창계수, 내산성 등을 분석하였고, 그 결과 강도와 탄성률, 열팽창계수, 내산성 등이 PTFE 코팅에 의해 향상된 것을 알 수 있었다. 이는 PTFE 코팅에 의해 형태안정성이 향상되었고, 동시에 열적 안정성이 향상되었기 때문인 것으로 판단된다.

• Tribology and Lubricants
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• v.10 no.4
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• pp.1-12
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• 1994

PTFE(Polytetrafluoroethylene)은 매우 낮은 마찰계수를 나타내고, -260부터 +260$\circ$C의 온도에서 계속적으로 사용할 수 있는 유용한 기계적 성질들을 유지한다. 결정 용융점은 327$\circ$C로서, 대부분의 다른 준결정(semicrystalline) 복합 재료들 보다 훨씬 높다. 더욱이, PTFE는 응력 상태에서 냉간 유동성을 보이며, 준결정 고분자들 중에서 가장 높은 마모율을 보인다. 하지만, 이러한 단점들은 PTFE내에 충전재(filler)를 첨가함으로써 매우 향상될 수 있다. PTFE의 독특한 특성의 하나는 충전재가 함유될 때의 내마모성의 증가가 다른 준결정 고분자보다 대단히 큰 것이다. 위에서 언급된 특성으로 인하여, PTFE는 마찰에 응용되는 고분자계 복합 재료들 중에서 매우 중요한 메트릭스 고분자이다. PTFE의 독특한 트라이볼로지적 성질들은 고유의 분자적 그리고 형태적 구조에 기인한다.

• Journal of Chest Surgery
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• v.29 no.8
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• pp.883-888
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• 1996

Expanded polytertrafluoroethylene (expanded PTFE) graft fistulas are widely used as secondary vascu- lar access for patients receiving long-term hemodialysis treatment. We implanted 48 grafts in )5 patients during the period from August 1990 to August 1995. Forty-three grafts in 32 patients were followed for 1 to 46 months. We performed forearm straight grafts in 36 grafts and upperarm straight grafts in 7 grafts. We experienced 3 operative failures, 22 early and late complications(15 graft thrombosis). Cumulative patency for all grafts at 12 months was 63%, at 24 months 32%, at 36 months 32% Forearm graft survival at 12 months was 55%, at 24 months 30%, at )6 months 30%. Upperarm graft survival at 12 months was 8)oyo and 24 months 41%. After reviewing our experience, we think that expanded-PTFE grart as secondary vascular access still have many complications and low survival than autogenous a teriovenous fistula. And so utilization of the expanded PTFE fistula requires better techniques, close observation and maintenance to keep it functional.

• Journal of Power System Engineering
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• v.14 no.4
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• pp.50-55
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• 2010

In order to investigate tribological effects of nano copper particles impregnated(CuN) on surface polytetrafluoroethylene(PTFE) on sealing wear and an experimental study was carried out to determine the wear behavior of copper nano-particles impregnation two kind thickness in super critical $CO_2$ liquid. Experimental results showed that the friction coefficients of CuN PTFE at the low sliding speed(0.44m/s) and the oil temperature ($60^{\circ}C$) were higher than that of virgin PTFE. And a thin nano copper particles impreganated thickness was formed on the surface in the PTFE and the specimen with this treatment has much better friction properties than the original one. Fortunately, at the high load(80 N) and the oil temperature, the friction coefficient of CuN PTFE was lower than that of virgin PTFE. This evidenced the load carrying capacity of CuN PTFE was much better than that of virgin PTFE under the high load condition(80 N) specially. Therefore, it can be concluded that the friction coefficient variation of CuN PTFE is very small but its wear rate decreases greatly with increase in sliding speed.

• Journal of Chest Surgery
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• v.28 no.11
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• pp.983-988
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• 1995

From January 1983 to December 1994, 48 cyanotic patients were underwent a subclavian artery-pulmonary artery shunt using polytetrafluoroethylene[PTFE for the purpose of improvement of reduced pulmonary blood flow. The diameters of the PTFE used were 4mm[4 cases , 5mm[36 cases , and 6mm[8 cases sizes. The effectiveness of modified Blalock-Taussig shunts was evaluated clinically and angiographically. There were 5 early deaths and 2 late deaths. There were 3 early shunt failures and 5 late shunt failures. The overall graft patency rate was 83.3%. Postoperative hemoglobin was reduced significantly[p = 0.0011 in comparison of the preoperative and postoperative hemoglobin, SaO2, PaO2, and cardiothoracic ratio.

• Tribology and Lubricants
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• v.20 no.5
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• pp.237-244
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• 2004

Micro/nano tribological characteristics of PTFE coating films were experimentally studied. PTFE (polytetrafluoroethylene) modified polyethylene and low molecular weight PTFE were used as a coating materials. These films were deposited on Si-wafer (100) by IBAD (ion beam assisted deposition) method. The Ar ion beam sputtering was performed to change the surface topography of films using a hollow cathode ion gun under different Ar ion dose conditions in a vacuum chamber. Micro/nano tribological characteristics, water wetting angles and roughness were measured with a micro tribotester, SPM (scanning probe microscope), contact anglemeter and profilometer, respectively. The durability of the films were measured with macro tribotester. Results showed that the PTFE coating surfaces were converted to hydrophobic. The water contact angle of coated surfaces and surface roughness increased with the coating thickness. Adhesion and friction in micro and nano scale were governed by magnitude of normal load in soft material such as PTFE films. As the increase of sputtering time on low molecular weight PTFE films, the surface roughness was increased and nano adhesion and friction were decreased. The nano tribological characteristics of surfaces are mainly improved by chemical modification such as PTFE coating and given a synergy effect by the physical modification such as topographic modification.

• Transactions of the Korean hydrogen and new energy society
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• v.20 no.5
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• pp.424-431
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• 2009

Treatment for water repellency on the carbon supports of GDL which composed a part of MEA has been suggested as a solution to prevent flooding. PTFE is a fluoropolymer that has hydrophobic property and a PTFE emulsion was selected as waterproof agent in this investigation. Carbon paper was coated by PTFE emulsion with different particle size of 5~500 nm and 3~$5\;{\mu}m$ as various concentration. PTFE coated carbon paper has difference in weight variation changed proportionally at PTFE concentration and coating times. Then gas permeability of the coated carbon paper with emulsion of 3~$5\;{\mu}m$ PTFE was changed vastly. Characteristics of carbon paper coated with different PTFE emulsion were analyzed by FE-SEM, FT-IR spcetroscopy and were evaluated by weight variations, gas permeability and water contact angle.