• Title/Summary/Keyword: Polystyrene

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Preparation and Structure of the Synthetic Polymeric Membranes based on Polystyrene and Poly(sodium 4-styrene sulfonate) (Polystyrene과 Poly(sodium 4-styrene sulfonate)를 이용한 합성 고분자 분리막의 제막 및 구조)

  • 변홍식;탁태문
    • Membrane Journal
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    • v.6 no.4
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    • pp.273-283
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    • 1996
  • A cation-exchange membranes were prepared by polystyrene and poly(sodium 4-styrene sulfonate). The degree of crosslinking of polystyrene membranes was controlled by DVB. At the same time, the structure of PS membranes was changed from RO to MF by varying the concentration of PSS in the casting solution. Water flux increased with PS-PSS membranes due to the sulfonate groups, and final membrane cast from the solution containing 5% of DVB and 3% of PSS showed MF structure.

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Controlling the Size and Surface Morphology of Carboxylated Polystyrene Latex Particles by Ammonium Hydroxide in Emulsifier-free Polymerization

  • Dong, Hyun-Bae;Lee, Sang-Yup;Yi, Gi-Ra
    • Macromolecular Research
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    • v.17 no.6
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    • pp.397-402
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    • 2009
  • In emulsifier-free, emulsion polymerization with ionizable comonomer, the ionization of the comonomer is critical in determining the size of the final polymerie particles at sub-micrometer scale. In this study, polystyrene latex beads with carboxylates on the surface were synthesized using acrylic acid as a comonomer. Specifically, ammonium hydroxide was added to the emulsifier-free polymerization system to promote the ionization of acrylic acid by increasing pH. Smaller polystyrene latex particles were produced by increasing the ammonium hydroxide concentration in the reaction system, due to the enhanced stability promoted by the ionization of acrylic acid during the nucleation step. In addition, the surface morphology of the polystyrene latex particles was controlled by the concentration of acrylic acid, the dissociation of which was influenced by the ammonium hydroxide concentration.

Synthesis of Magnetic Polystyrene-Polyimide Core-Shell Microsphere (자성 폴리스티렌-폴리이미드 Core-Shell 마이크로스피어의 합성)

  • Ahn, Byung-Hyun
    • Elastomers and Composites
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    • v.47 no.2
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    • pp.168-173
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    • 2012
  • Polystyrene-polyimide core-shell microsphere was prepared by dispersion polymerization using poly(amic acid) as the stabilizer. Iron oxide was formed at the microsphere by thermal decomposition of iron pentacarbonyl impregnated in the microsphere. The magnetic polystyrene-polyimide microsphere was monodisperse and the size was about 500 nm. The magnetic polystyrene-polyimide microsphere had 40% of iron oxide, which was identified as $Fe_3O_4$ by X-ray diffraction.

Charge Distribution Characteristics of Polystyrene/Polyaniline Conducting Blends (폴리스타이렌/폴리아닐린 전도성 블렌드의 전하분포 특성)

  • Kim, Won-Jung;Ko, Jung-Woo;Park, Chang-Mo;Suh, Kwang-S.
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1457-1459
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    • 2003
  • Space charge distributions and behaviors of polystyrene/polyaniline conducting blends were investigated using a pulsed electroacoustic(PEA) method. It was found that positive charges were accumulated near the cathode with increasing polyaniline content in polystyrene/polyaniline when electric field was applied. Breakdown phenomena was investigated by breakdown test and it was observed that dielectric strength was diminished as polyaniline content was increased. By Scanning Electron Microscopy, corss-sectional views of polystyrene/polyaniline conducting blends were observed that the particles of polyaniline were well distributed in polystyrene.

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Effect of nano-carbon addition on color performance of polystyrene superstructure film

  • ZHOU, Ye-min;Wang, Li-li;LI, Xiao-peng;Wang, Xiu-feng;Jiang, Hong-tao
    • Journal of Ceramic Processing Research
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    • v.19 no.6
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    • pp.479-482
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    • 2018
  • Polystyrene superstructure films show faint rainbow color, and this low color saturation limits its wide application. In this paper, polystyrene superstructure films with single bright blue color were prepared by vertical deposition self-assembly method using polystyrene microspheres with average diameter of $310{\pm}10nm$ as raw material. Polystyrene superstructure films were modified by adding nano-carbon powder, and effect of the amount of nano-carbon powde on color performance was studied. The results showed that without addition of nano-carbon powder, the superstructure films showed a faint rainbow color, while with addition of nano-carbon power, the superstructure films exhibited a single bright blue under the same natural light source. Changing the amount of nano-carbon powder addition could adjust color saturation of the film. With increasing the amount of nano-carbon powder addition from 0.008 wt% to 0.01 wt%, color saturation of the superstructure film increased gradually. Further increasing the amount of nano-carbon powder addition to 0.011wt%, color saturation of the superstructure film didn't increase anymore and tended to get dark.

Resistance of Polystyrene-Impregnated Glued Laminated Lumbers after Exposure to Subterranean Termites in a Field

  • Dede HERMAWAN;Mahdi MUBAROK;Imam Busyra ABDILLAH;Yusuf Sudo HADI;Cossey YOSI;Aujchariya CHOTIKHUN;Rohmah PARI;Gustan PARI
    • Journal of the Korean Wood Science and Technology
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    • v.52 no.1
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    • pp.70-86
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    • 2024
  • Termites are a serious threat to wood-based products in Indonesia. This study investigated the termite resistant property of glulam made from polystyrene-modified wood. Three tropical fast-growing wood species, namely mangium (Acacia mangium), manii (Maesopsis eminii), and rubberwood (Hevea brasiliensis), were prepared for flat-sawn laminae. After getting air-dried condition, the laminae were impregnated with polystyrene using potassium peroxydisulphate as a catalyst followed by polymerization at 80℃. Polystyrene-impregnated and control glued-laminated lumbers (glulams) were manufactured, and solid wood was provided. Three wood species and three wood products with six replicates were exposed in a field in Bogor, Indonesia, for four months, and before the tests, their density and moisture content were measured. At the end of the field tests, the weight loss and protection levels of each test sample were determined. A completely randomized factorial design was used for data analysis. The weight percentage gains for mangium, manii, and rubberwood were 22.30%, 18.22%, and 10.44%, respectively. The results showed that manii belonged to low-density wood, whereas the other two woods were medium-density wood, and the moisture content was the ambient moisture content, typical of the Bogor area. Regarding weight loss and protection level, mangium was the most durable against subterranean termite attacks, followed by rubberwood and manii. Among the wood products, the polystyrene-impregnated glulam presented the highest durability, followed by the control glulam and solid wood. Therefore, mangium and rubberwood polystyrene-impregnated glulams are recommended for future product development.

Preparation of Polystyrene-Polyetherimide Core-Shell Particles by Dispersion Polymerization (분산중합에 의한 폴리스티렌-폴리에테르이미드 코어-셀 입자의 합성)

  • Ahn, Byung Hyun
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.526-530
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    • 2014
  • Polystyrene-poly(etheramic acid) core-shell particles were prepared by dispersion polymerization of styrene using poly(etheramic acid) obtained by the reaction of 2,2'-bis[4-(3,4-dicarboxyphenoxy) phenyl]propane dianhydride and 3,5-diamniobenzoic acid as a stabilizer. 4-Vinylbenzyltrimethylammonium chloride was used as a comonomer to increase the binding efficiency of poly(etheramic acid). When the ethanol-water mixture (7 : 3) was used as a reaction medium, particles were stabilized well and the size distribution of particles was fairly narrow. The particle size increased with the amount of styrene. The particles polymerized in the dimethylformamide-water mixture had a broad size range. Polystyrene-poly(etheramic acid) core-shell particles were transformed to polystyrene-polyetherimide core-shell particles by the chemical imidization of shells.

Systemic Administration of the Potassium Channel Activator in the Polystyrene Latex Bead-Induced Cerebral Vasospasm (Polystyrene Latex Bead에 의한 뇌혈관연축 모델에서 K+ 통로활성제의 전신투여)

  • Jang, Sung Jo;Kang, Sung Don;Yun, Ki Jung
    • Journal of Korean Neurosurgical Society
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    • v.29 no.6
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    • pp.719-724
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    • 2000
  • Objectives : It has been reported that the presence of a pharmacologically inactive foreign substance, polystyrene latex bead, in subarachnoid space activates a non-specific immunological response and elicits arterial narrowing. Recently the activation of potassium($K^+$) channels may be of benefit in relieving cerebral vasospasm. The present study examined the effects of systemic administration of a ATP-sensitive $K^+$ channel activator, cromakalim, on the polystyrene latex bead-induced cerebral vasospasm. Methods : The spasm models similar to that caused by subarachnoid blood injection were created by injection of bead into rabbit cisterna magna. Intravenous injections of cromakalim were administered twice daily(bid) 30 minutes after induction of vasospasm. Animals were killed by perfusion-fixation 2 days after vasospasm. Basilar arteries were removed and sectioned, and the luminal cross-sectional areas were measured. Results : Injection of bead elicited an arterial constriction, reducing arterial diameter to 33.3% of resting tone. Cromakalim inhibited bead-induced constriction at a dose of 0.3mg/kg(Mann-Whitney test, p<0.01). Conclusion : These results support the concept that the cellular events triggered by inactivation of ATP-sensitive $K^+$ channels are responsible for the pathogenesis of vasospasm. The findings also indicate that cromakalim represents a potential therapeutic agents for the treatment of cerebral vasospasm.

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