• BMB Reports
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• 제44권2호
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• pp.87-95
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• 2011

Enzymatic catalysis has been pursued extensively in a wide range of important chemical processes for their unparalleled selectivity and mild reaction conditions. However, enzymes are usually costly and easy to inactivate in their free forms. Immobilization is the key to optimizing the in-service performance of an enzyme in industrial processes, particularly in the field of non-aqueous phase catalysis. Since the immobilization process for enzymes will inevitably result in some loss of activity, improving the activity retention of the immobilized enzyme is critical. To some extent, the performance of an immobilized enzyme is mainly governed by the supports used for immobilization, thus it is important to fully understand the properties of supporting materials and immobilization processes. In recent years, there has been growing concern in using polymeric materials as supports for their good mechanical and easily adjustable properties. Furthermore, a great many work has been done in order to improve the activity retention and stabilities of immobilized enzymes. Some introduce a spacer arm onto the support surface to improve the enzyme mobility. The support surface is also modified towards biocompatibility to reduce non-biospecific interactions between the enzyme and support. Besides, natural materials can be used directly as supporting materials owning to their inert and biocompatible properties. This review is focused on recent advances in using polymeric materials as hosts for lipase immobilization by two different methods, surface attachment and encapsulation. Polymeric materials of different forms, such as particles, membranes and nanofibers, are discussed in detail. The prospective applications of immobilized enzymes, especially the enzyme-immobilized membrane bioreactors (EMBR) are also discussed.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 1998년도 봄 학술발표회 논문집
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• pp.349-356
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• 1998

A method of calculating the natural frequency corresponding to the first mode of vibration of beams and tower structures, with irregular cross sections and with arbitrary boundary conditions was developed and reported by Kim, D. H. in 1974. In this paper, the result of application of this method to the three span continuous reinforced concrete bridge with elastic intermediate supports in presented. Such bridge represents either concrete or sandwich type three span bridge on polymeric supports for passive control or on actuators for active control. Any method may be used to obtain the deflection influence surfaces needed for this vibration analysis. Finite difference method is used for this purpose, In this paper. The influence of the modulus of the foundation and $D_{22}$, $D_{l2}$, $D_{66}$ stiffnesses on the natural frequency is thoroughly studied.d.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 추계학술발표대회 논문집
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• pp.220-223
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• 2000

A method of calculating the natural frequency corresponding to the modes of vibration of beams and tower structures, with irregular cross sections and with arbitrary boundary conditions was developed and reported by Kim, D. H. in 1974. In this paper, the result of application of this method to the three span continuous reinforced concrete bridge with elastic intermediate supports is presented. Such bridge represents either concrete or sandwich type three span bridge on polymeric supports for passive control or on actuators for active control The concrete slab is considered as a special orthotropic plate. The influence of the modulus of the foundation and $D_{22}$, $D_{12}$, $D_{66}$ stiffnesses on the natural frequency is thoroughly studied.

• Korean Chemical Engineering Research
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• 제53권3호
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• pp.382-390
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• 2015

Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

• 한국강구조학회 논문집
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• 제17권3호통권76호
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• pp.317-324
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• 2005

본 연구에서는 3경간연속 탄성지지된 복합슬래브교량을 특별직교이방성 판이론을 응용하여 해석하였다. 불균등단면이나 임의의 경계조건을 가진 보나 타워구조물의 고유진동수를 계산하는 방법을 탄성지지된 3경간 연속 복합슬래브교량에 적용하여 연구하였다. 슬래브 상판은 특별직교이방성 판으로 취급하였다. 진동해석에 필요한 변위의 영향계수는 여러 가지 방법으로 구할 수 있으나 본 논문에서는 유한차분법을 사용하였다. 또한 휨강성에 대한 영향과 기초의 탄성계수에 대한 영향에 대하여 연구하였다.

• Composites Research
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• 제17권3호
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• pp.23-28
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• 2004

불균등 단면이나 임의의 경계조건을 가진 보나 탑 구조물의 고유진동수를 계산하는 방법은 김덕현에 의해 1960년 후반기에 개발 응용되고 1974년의 한 국제회의에서 발표되었다. 이 논문에는 이 방법을 탄성지지된 3경간연속 철근콘크리트 교량에 적용한 결과가 실려있다. 콘크리트 상판은 특별직교 이방성 판으로 취급되었다. 이 진동해석에 필요한 변위의 영향계수는 여러 방법으로 구할 수 있으나 이 논문에서는 유한차분법이 사용되었다. 기초의 탄성계수와, $D_{22}$, $D_{12}$, $D_{66}$ 강성의 고유진동수에 대한 영향이 철저하게 연구되었다.

• Macromolecular Research
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• 제14권2호
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• pp.121-128
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• 2006

Microfluidic systems have attracted much research attention recently in the areas of genomics, proteomics, pharmaceutics, clinical diagnostics, and analytical biochemistry, as they provide miniaturized platforms for conventional analysis techniques. The microfluidic systems allow faster and cheaper analysis using much smaller amounts of sample and reagent than conventional methods. Polymers have recently found useful applications in microfluidic systems due to the wide range of available polymeric materials and the relative ease of chemical modification. This paper discusses the fundamentals of microfluidic systems and the roles, essential properties and various forms of polymers used as solid supports in microfluidic systems, based on the recent advances in the use of polymers for microfluidic chips.

• 전자공학회논문지D
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• 제34D권4호
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• pp.73-78
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• 1997

A polymeric waveguide TE-pass polarier operating at wavelengths around 1.55.mu.m is realized by utilizing the birefringence induced by photoleaching at room temperature. To implement the polarizer, the photobleached waveguide supporting only TE mode is integrated in the middle of the etched rib waveguide that supports TE and TM modes. It has a simple structure and requires no high temperature process like poling. The measured polarization extinction ratio is about 21dB and the estimted excess loss is about 0.4dB.

• Bulletin of the Korean Chemical Society
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• 제31권9호
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• pp.2459-2466
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• 2010

Unfunctionalized biaryl compounds were parallelly and combinatorially prepared by the traceless hydrogenolysis of biarylsulfonates supported on pentaerythritol. The hydrogenolysis using 2-propylmagnesium chloride in the presence of $dppfNiCl_2$ efficiently generated corresponding biaryl derivatives without any memory of the support. The strategy using pentaerythritol as a small soluble support was disclosed to have a potential to combine the benefits of both SPOS and solution-phase reaction with fast reaction rate, facile isolation of intermediates, easy analysis of intermediates and atom economical manner. The novel tetrapodal support is expected to be an efficient substitute for polymeric supports in many circumstances.

• 멤브레인
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• 제4권2호
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• pp.96-105
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• 1994

이 논문은 거대전하고분자의 막전달 현상을 위한 이론적 모델을 연구하는데 있다. 전기적 힘에 의한 전하고분자 물질의 형상은 빠르게 곧게 뻗으면서 진행되며, 곧게 뻗는 시간과 길이는 막 전달의 동적현상을 이해하는데 도움을 주고 있다. 빠르게 곧게 뻗을 때, 전하고분자의 두 끝이 전기힘 방향으로 동시에 끌리는 현상이 일어난다. 이같은 형식의 이해는 거대전하고분자의 막분리를 이해하는데 도움을 주고 있다.