• BMB Reports
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• v.44 no.2
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• pp.87-95
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• 2011

Enzymatic catalysis has been pursued extensively in a wide range of important chemical processes for their unparalleled selectivity and mild reaction conditions. However, enzymes are usually costly and easy to inactivate in their free forms. Immobilization is the key to optimizing the in-service performance of an enzyme in industrial processes, particularly in the field of non-aqueous phase catalysis. Since the immobilization process for enzymes will inevitably result in some loss of activity, improving the activity retention of the immobilized enzyme is critical. To some extent, the performance of an immobilized enzyme is mainly governed by the supports used for immobilization, thus it is important to fully understand the properties of supporting materials and immobilization processes. In recent years, there has been growing concern in using polymeric materials as supports for their good mechanical and easily adjustable properties. Furthermore, a great many work has been done in order to improve the activity retention and stabilities of immobilized enzymes. Some introduce a spacer arm onto the support surface to improve the enzyme mobility. The support surface is also modified towards biocompatibility to reduce non-biospecific interactions between the enzyme and support. Besides, natural materials can be used directly as supporting materials owning to their inert and biocompatible properties. This review is focused on recent advances in using polymeric materials as hosts for lipase immobilization by two different methods, surface attachment and encapsulation. Polymeric materials of different forms, such as particles, membranes and nanofibers, are discussed in detail. The prospective applications of immobilized enzymes, especially the enzyme-immobilized membrane bioreactors (EMBR) are also discussed.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 1998.04a
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• pp.349-356
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• 1998

A method of calculating the natural frequency corresponding to the first mode of vibration of beams and tower structures, with irregular cross sections and with arbitrary boundary conditions was developed and reported by Kim, D. H. in 1974. In this paper, the result of application of this method to the three span continuous reinforced concrete bridge with elastic intermediate supports in presented. Such bridge represents either concrete or sandwich type three span bridge on polymeric supports for passive control or on actuators for active control. Any method may be used to obtain the deflection influence surfaces needed for this vibration analysis. Finite difference method is used for this purpose, In this paper. The influence of the modulus of the foundation and $D_{22}$, $D_{l2}$, $D_{66}$ stiffnesses on the natural frequency is thoroughly studied.d.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.220-223
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• 2000

A method of calculating the natural frequency corresponding to the modes of vibration of beams and tower structures, with irregular cross sections and with arbitrary boundary conditions was developed and reported by Kim, D. H. in 1974. In this paper, the result of application of this method to the three span continuous reinforced concrete bridge with elastic intermediate supports is presented. Such bridge represents either concrete or sandwich type three span bridge on polymeric supports for passive control or on actuators for active control The concrete slab is considered as a special orthotropic plate. The influence of the modulus of the foundation and $D_{22}$, $D_{12}$, $D_{66}$ stiffnesses on the natural frequency is thoroughly studied.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.382-390
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• 2015

Poly(methyl methacrylate) (PMMA) supports and amine additives were investigated to adsorb $CO_2$. PMMA supports were fabricated by using different ratio of pore forming agents (porogen) to control the BET specific surface area, pore volume and distribution. Toluene and xylene are used for porogens. Supported amine sorbents were prepared by wet impregnation of tetraethylenepentamine (TEPA) on PMMA supports. So we could identify the effect of the pore structure of supports and the quantity of impregnated TEPA on the adsorption capacity. The increased amount of toluene as pore foaming agent resulted in the decreased average pore diameter and the increased BET surface area. Polymer supports with huge different pore distribution could be fabricated by controlling the ratio of porogen. After impregnation, the support with micropore structure is supposed the pore blocking and filling effect so that it has low $CO_2$ capacity and kinetics due to the difficulty of diffusing. Macropore structure indicates fast adsorption capacity and low influence of amine loading. In case of support with mesopore, it has high performance of adsorption capacity and kinetics. So high surface area and meso-/macro- pore structure is suitable for $CO_2$ capture.

• Journal of Korean Society of Steel Construction
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• v.17 no.3 s.76
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• pp.317-324
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• 2005

The specially orthotropic plate theory is used to analyse three-span continuous composite slab bridges with elastic intermediate supports. A method of calculating the natural frequency corresponding to the first mode of vibration of beams and tower structures, with irregular cross sections and with arbitrary boundary conditions, was developed and the result of application of this method to the three-span continuous composite slab bridges with elastic intermediate supports is presented. This type of bridge represents either concrete or sandwich type three-span bridge on polymeric supports for passive control or on actuators for active control. Any method may be used to obtain the deflection influence surfaces needed for this vibration analysis. The finite difference method is used for this purpose in this paper. The influence of flexural stiffnesses and the modulus of the foundation are studied.

• Composites Research
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• v.17 no.3
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• pp.23-28
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• 2004

A method of calculating the natural frequency corresponding to the first mode of vibration of beams and tower structures, with irregular cross sections and with arbitrary boundary conditions was developed and reported by Kim, D. H. in 1974. In this paper, the result of application of this method to the three span continuous reinforced concrete bridge with elastic intermediate supports is presented. Such bridge represents either concrete or sandwich type three span bridge on polymeric supports for passive control or on actuators for active control. The concrete slab is considered as a special orthotropic plate. Any method may be used to obtain the deflection influence surfaces needed for this vibration analysis. Finite difference method is used for this purpose, in this paper, The influence of the modulus of the foundation and $D_{22}$, $D_{12}$, $D_{66}$ stiffnesses on the natural frequency is thoroughly studied.

• Macromolecular Research
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• v.14 no.2
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• pp.121-128
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• 2006

Microfluidic systems have attracted much research attention recently in the areas of genomics, proteomics, pharmaceutics, clinical diagnostics, and analytical biochemistry, as they provide miniaturized platforms for conventional analysis techniques. The microfluidic systems allow faster and cheaper analysis using much smaller amounts of sample and reagent than conventional methods. Polymers have recently found useful applications in microfluidic systems due to the wide range of available polymeric materials and the relative ease of chemical modification. This paper discusses the fundamentals of microfluidic systems and the roles, essential properties and various forms of polymers used as solid supports in microfluidic systems, based on the recent advances in the use of polymers for microfluidic chips.

• Journal of the Korean Institute of Telematics and Electronics D
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• v.34D no.4
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• pp.73-78
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• 1997

A polymeric waveguide TE-pass polarier operating at wavelengths around 1.55.mu.m is realized by utilizing the birefringence induced by photoleaching at room temperature. To implement the polarizer, the photobleached waveguide supporting only TE mode is integrated in the middle of the etched rib waveguide that supports TE and TM modes. It has a simple structure and requires no high temperature process like poling. The measured polarization extinction ratio is about 21dB and the estimted excess loss is about 0.4dB.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2459-2466
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• 2010

Unfunctionalized biaryl compounds were parallelly and combinatorially prepared by the traceless hydrogenolysis of biarylsulfonates supported on pentaerythritol. The hydrogenolysis using 2-propylmagnesium chloride in the presence of $dppfNiCl_2$ efficiently generated corresponding biaryl derivatives without any memory of the support. The strategy using pentaerythritol as a small soluble support was disclosed to have a potential to combine the benefits of both SPOS and solution-phase reaction with fast reaction rate, facile isolation of intermediates, easy analysis of intermediates and atom economical manner. The novel tetrapodal support is expected to be an efficient substitute for polymeric supports in many circumstances.

• Membrane Journal
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• v.4 no.2
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• pp.96-105
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• 1994

Theoretical model for membrane transport of large polye!ectroiyte is presented. When the electric field is applied, the molecular conformation quickly orients in the field direction showing overshooting orientation. the predicted dependence of overshoot time and orientation upon field intensity and molecular size aids to understand the dynamic motion of molecules in membrane transport. The dynamics of the overshoot is associated with self-trapping conformations of molecule. The understanding of these effects supports evidences for the electrophoretic filtration of polydectrolyte in the polymeric membrane. This paper shows one example for molecular study in the theoretical review paper of membrane transport.