• Title/Summary/Keyword: Polymeric binders

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Recent Progress on Polymeric Binders for Silicon Anodes in Lithium-Ion Batteries

  • Choi, Nam-Soon;Ha, Se-Young;Lee, Yongwon;Jang, Jun Yeong;Jeong, Myung-Hwan;Shin, Woo Cheol;Ue, Makoto
    • Journal of Electrochemical Science and Technology
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    • v.6 no.2
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    • pp.35-49
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    • 2015
  • Advanced polymeric binders with unique functions such as improvements in the electronic conduction network, mechanical adhesion, and mechanical durability during cycling have recently gained an increasing amount of attention as a promising means of creating high-performance silicon (Si) anodes in lithium-ion batteries with high energy density levels. In this review, we describe the key challenges of Si anodes, particularly highlighting the recent progress in the area of polymeric binders for Si anodes in cells.

Addition of Polymeric Materials to Binders for Solidification of Heavy Metal Contaminated Mine Tailings (폴리머 물질 첨가를 통한 중금속 오염 광미의 고형화 처리)

  • Kim, Tae-Poong;Min, Kyoung-Won;Lee, Hyun-Cheol;Seo, Eui-Young;Lee, Won-Sup
    • Journal of Industrial Technology
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    • v.30 no.A
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    • pp.37-43
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    • 2010
  • Polymeric materials in addition to Portland cement and hydrated limes were used to solidify heavy metal contaminated tailings from five abandoned metal mines in Korea. Mine tailings were mixed separately with Portland cement and hydrated lime at a concentration of 20-30 wt% and 6-9 wt%, respectively and Ethylene Vinyl Acetate(EVA) powder was added to each specimen at a ratio of 2.5 and 5.0 wt% to binders. Polymer-added and polymer-free solidified forms were evaluated for their appropriateness in accordance with the suggested test methods. Regardless of addition of polymeric materials, all solidified forms satisfy the uniaxial compressive strength(UCS) requirements(0.35MPa) for land reclamation and show remarkably reduced leaching concentrations of heavy metals such as As, Cd, Cu, Pb and Zn less than the toxicity criteria of Korean standard leaching test(KSLT). The addition of polymeric materials increased the UCS of solidified forms to improve a long-term stability of solidified mine tailings.

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Development of Advanced Polymeric Binders for High Voltage LiNi0.5Mn1.5O4 cathodes in Lithium-ion batteries (고전압 LiNi0.5Mn1.5O4 양극 고성능 바인더 개발 연구)

  • Dae Hui Yun;Sunghun Choi
    • Journal of Industrial Technology
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    • v.43 no.1
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    • pp.43-48
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    • 2023
  • Spinel LiNi0.5Mn1.5O4 (LNMO) has been considered as one of most promising cathode material, because of its low-cost and competitive energy density. However, 4.7V vs. Li/Li+ of high operating potential facilitates electrolyte degradation on cathode-electrolyte interface during charge-discharge process. In particular, commercial polyvinylidene fluoride (PVDF) is not sutaible for LNMO cathode binder because its weak van der waals force induces thick and non-uniform coverage on the cathode surface. In this review, we study high performance binders for LNMO cathode, which forms uniform coating layer to prevent direct contact between electrolyte and LNMO particle as well as modifying high quality cathode electrolyte interphase, improved cell performace.

Effect of Polymeric Binders on Green body Properties of WC-Co Cemented Carbides (초경합금 성형체 특성 변화에 미치는 유기물 결합제의 영향)

  • Lim, Young-Soo;Ahn, Sun-Yong;Lim, Jae-Suk;Paek, Yeong-Kyeun;Chung, Tai-Joo
    • Journal of Powder Materials
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    • v.29 no.4
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    • pp.291-296
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    • 2022
  • The green body of WC-Co cemented carbides containing polymeric binders such as paraffin, polyethylene glycol (PEG), and polyvinyl acetate (PVA) are prepared. The green density of the WC-Co cemented carbides increases with the addition of binders, with the exception of PVA, which is known to be a polar polymeric substance. The green strength of the WC-Co cemented carbides improves with the addition of paraffin and a mixture of PEG400 and PEG4000. In contrast, the green strength of the WC-Co does not increase when PEG400 and PEG4000 is added individually. The compressive strength of the green body increases to 14 MPa, and the machinability of the green body improves when more than 4-6 wt% paraffin and a mixture of PEG400 and PEG4000 is used. Simultaneously, the sintered density of WC-Co is as high as 99% relative density, similar to a low binder addition of 1-2 wt%.

Thermally Crosslinked Polyimide Binders for Si-alloy Anodes in Li-ion Batteries

  • Chang, Hyeong-Seok;Ji, Sang-Gu;Rho, Miso;Lee, Byoung-Min;Kim, Sung-Soo;Choi, Jae-Hak
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.339-346
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    • 2022
  • Silicon (Si) has attracted considerable attention due to its high theoretical capacity compared to conventional graphite anode materials. However, Si-based anode materials suffer from rapid capacity loss due to mechanical failure caused by large volume change during cycling. To alleviate this phenomenon, crosslinked polymeric binders with strong interactions are highly desirable to ensure the electrode integrity. In this study, thermally crosslinked polyimide binders were used for Si-alloy anodes in Li-ion batteries. The crosslinked polyimide binder was found to have high adhesion strength, resulting in enhanced electrode integrity during cycling. Therefore, the Si-alloy anodes with crosslinked polyimide binder provide enhanced electrochemical performance, such as Coulombic efficiency, capacity retention, and cycle stability.

Preparation of Colour Filter Photo Resists for Improving Colour Purity in Liquid Crystal Displays by Synthesis of Polymeric Binder and Treatment of Pigments

  • Yoon, Chun;Choi, Jae-Hong
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1821-1826
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    • 2009
  • Liquid crystal display (LCD) devices contain a colour filter which can visualise colour images by transmitting or absorbing light. Colour properties of LCD mainly depend on colour materials such as pigments and polymeric binders. In this paper, colour properties were studied to improve colour quality of LCD. Generally, the colour properties can be classified into three categories which are colour purity, brightness and contrast ratio. For this study, photo resists were prepared by treatment of pigments and synthesis of polymeric binder. The treated pigments were dispersed and formulated with additives for preparing a photo resist that could be used for manufacturing colour filters. As a result of what we studied, type, mixture ratio and concentration of pigments were very important to improve colour purity of LCD device.

Development of Binder Materials for Si-based Anode in Lithium-ion Batteries (리튬이온전지 실리콘계 음극 바인더 소재 개발)

  • Jihee, Yoon;Jung-Keun, Yoo
    • Composites Research
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    • v.35 no.6
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    • pp.365-370
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    • 2022
  • According to the rapid growth of electric vehicle (EVs) and E-mobility market, Li-ion batteries are one of the most progressive technologies. The demand of LIBs with high energy capacity, rate performance and fast charging is continuously increasing, hence high-performance LIBs should be developed. Si is considered as the most promising anode material to improve energy density because of its high theoretical capacity. However, Si suffers large volume chances during the charging and discharge process, leading to the fast degradation of cycle performance. Therefore, polymeric binders play a key role in electrochemical performance of Si anode by efficiently enduring the Si expansion and maintaining the binding networks in electrode. In this review, we explain the role of polymeric binders in electrode and introduce the anode binders with enhanced mechanical and chemical properties which can improve electrochemical performances of Si-based anode.

An Experimental Study on Friction and Wear Characteristics of Air Curable $MoS_2$ Bonded Films with Polymeric Binder Materials (결합제 변화에 따른 상온 경화성 접착형 $MoS_2$ 고체윤활 피막의 마찰.마모 특성)

  • 한흥구;공호성;윤의성;권오관
    • Tribology and Lubricants
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    • v.14 no.4
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    • pp.72-78
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    • 1998
  • In this work, the effects of binder materials on the tribological behavior were experimentally evaluated for air curable MoS$_2$bonded film lubricants. The binders tested were basically alkyd and acryl based resins, and also were modified by nitro-cellulose in various weight percentages. Effects on the binder ratio to solid lubricants and the molecular weight of binders were also investigated in all aspects of the tribological behavior. For the tests, LFW-1 and Falex tester were used to measure mainly the endurance life and load carrying capacity of bonded lubricants. Results showed that lubricants of methacrylic resin has the better performance than those of other resins, and also the properties of lubricants both of alkyd and acrylic resins could be improved by modification with nitro-cellulose. It was also shown that the optimum ratio of nitro-cellulose related closely to the binder material and the testing machine.