• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05e
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• pp.6-10
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• 2003

In our country, the housing materials of polymeric outdoor insulators have mainly been used EPDM or silicone rubber. EPDM housing materials had been widely used in the field for the first time. The reason why silicone has the high cost of production. But recently, most of the manufacturers that newly developed polymeric insulators make its choice of silicone housing. EPDM showed a good resistance to tracking. We compared the various characteristics for EPDM and silicone insulators that have similar type and design. Silicone insulators have more performance in flashover voltage test and leakage current measurement because of a good water repellent than EPDM ones. Also, the property of EPDM compared with silicone insulators greatly decreased after aging test in combined acceleration ageing facilities for 1000 hours.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.51 no.10
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• pp.473-478
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• 2002

Accelerated thermal aging conditions of polymeric materials were studied by Kissinger equation with TGA analysis. The activation energy was obtained from the slope of straight line of each specimen at the different TGA heating rate. Estimating activation energy from Kissinger equation was acquired, and the resulting calculation showed that 3.59, 3.0, 3.86, 3.73 for the PEEK, polyimide, polysulfone and Viton, respectively. The studied polymeric specimens are used for electrical penetration assembly in nuclear power plant. Accelerated aging time and temperature were also determined corresponding to actual service temperature and 41 years.

• Clean Technology
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• v.4 no.2
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• pp.32-40
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• 1998

The polymeric porous materials which consist of polypropylene(PP) and polyethylene(PE) powder were prepared to apply to the air purification systems by extrusion sintering method. SEM analysis showed that a composite polymeric porous structure made up of PP and PE was obtained, where PE was melted and adhered to PP because the melting temperature of PE was lower than that of PP. The filtration characteristics and mechanical properties of polymeric porous materials were investigated by varying the head die temperature of the extruder, extrusion velocity, and the melt index and quantity of PE. The filtration efficiency was proportional to the quantity of PE but inversely proportional to the melt index of PE. The polymeric porous materials composed of PP and PE, which was made by extrusion sintering method, was found to be suitable for the filter element of the air purification system.

• Journal of Microbiology and Biotechnology
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• v.21 no.1
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• pp.28-36
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• 2011

Diblock copolymers composed of poly(${\varepsilon}$-caprolactone) (PCL) and poly(N,N-dimethylamino-2-ethyl methacrylate) (PDMAEMA), or methoxy polyethylene glycol(PEG), were synthesized via a combination of ring-opening polymerization and atom-transfer radical polymerization in order to prepare polymeric nanoparticles as an antifungal drug carrier. Amphotericin B (AmB), a natural antibiotic, was incorporated into the polymeric nanoparticles. The physical properties of AmB-incorporated polymeric nanoparticles with PCL-b-PDMAEMA and PCL-b-PEG were studied in relation to morphology and particle size. In the aggregation state study, AmB-incorporated PCL-b- PDMAEMA nanoparticles exhibited a monomeric state pattern of free AmB, whereas AmB-incorporated PCL-b- PEG nanoparticles displayed an aggregated pattern. In in vitro hemolysis tests with human red blood cells, AmBincorporated PCL-b-PDMAEMA nanoparticles were seen to be 10 times less cytotoxic than free AmB (5 ${\mu}g$/ml). In addition, an improved antifungal activity of AmBincorporated polymeric nanoparticles was observed through antifungal activity tests using Candida albicans, whereas polymeric nanoparticles themselves were seen not to affect activity. Finally, in vitro AmB release studies were conducted, proving the potential of AmB-incorporated PCL-b-PDMAEMA nanoparticles as a new formulation candidate for AmB.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2241-2247
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• 2007

A new series of chiral bent-shaped liquid crystals with an asymmetric central core based on 1,6- dihydroxynaphthalene and chiral terminal chain prepared from (S)-(?)-2-methyl-1-butanol, 1,6-naphthalene bis[4-(4-alkoxyphenyliminomethyl)]benzoates [N(1,6)-n-O-PIMB(n-2)*-(n-4)O (n = 8-11)] were synthesized. Their mesomorphic properties and phase structures were investigated by means of electro-optical, polarization reversal current, and second harmonic generation measurements in order to confirm the relationship between the molecular structure and phase structure. All odd n (n = 9 and 11) compounds, N(1,6)-9-O-PIMB7*-5O and N(1,6)-11-O-PIMB9*-7O exhibit antiferroelectric phase, whereas even n (n = 8 and 10) compounds was flexible, N(1,6)-10-O-PIMB8*-6O exhibits the ferroelectric phase but N(1,6)-8-O-PIMB6*-4O exhibits the antiferroelectric phase. These results come from the decrease of the closed packing efficiency within a layer and the lack of uniform interlayer interaction between adjacent layers, which were caused by the asymmetrical naphthalene central core. Thus, we concluded that the structure of central core as well as the terminal chain plays an important role for the emergence of particular polar ordering in phase structures.

• Korean Journal of Materials Research
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• v.9 no.4
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• pp.409-413
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• 1999

Recently, the polymeric insulators have been accepted in several countries for the outdoor high voltage applications. In comparison with the conventional porcelain, polymeric insulators offer various advantages such as light weight, superior vandal resistance and better contamination performance. The outdoor polymeric insulating materials such as silicone rubber, ethylene propylene diene monomer(EPDM), ethylene vinyl acetate(EVA) and epoxy are aged such as silicone rubber, ethylene propylene diene monomer(EPDM), ethylene vinyl acetate(EVA) and epoxy are aged under the various natural environment with the long-term performance in outdoor. In this paper, the effects of UV-under the various natural environment with the long-term performance in outdoor. In this paper, the effects of UV-ray on the surface of silicone rubber were investigated by using the weather-Ometer. The accelerated aging stresses were simulated by UV radiation, high temperature and humidity as well as water spray. These aging characteristics were examined through contact angle measurements, tracking resistance test, FT-IR and SEM/EDS analysis. The experimental results showed that tracking resistance decreases with increase in the UV-ray irradiation period. But the surface of silicone rubber kept hydrophobicity. It is found that the inorganic filler such as)$ Al(OH_3$ improves tracking resistance and the $Tio_2$is very effective in preventing degradation of silicone rubber surface from UV-ray.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.53-53
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• 2011

자동차용 천연가죽 시트의 제조 공정에서 크롬과 비크롬 Metalic 탄닝제, 식물성 탄닝제, 신탄(Syntan) 및 가지제(Fatliuor) 등의 종류와 함량에 따른 인장강도, 신장율, 정하중 신율, 잔류줄음율 등을 측정하여 특정하중에 따른 콜라겐 섬유 조직의 영구변형율과의 상관관계를 비교 분석해본 결과, 크롬 및 비크롬계 탄닝제에 비해 식물성 탄닝제를 적용하였을 때 조직의 변형율이 적었으며, 리틴닝 공정에서 아크릴계, 레진계 및 단백질계 신탄을 혼합 적용하였을 때 가죽의 배(Belly)부위의 물성 균일화 효과가 우수하였으며, 음이온성 가지제 9%를 사용하여 가죽에 유연성을 부여함으로써 조직이 치밀하고 변형율이 감소되어 내구성이 우수한 결과를 나타내었다.

• Current Applied Physics
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• v.18 no.11
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• pp.1235-1239
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• 2018

We present a novel process to fabricate three-dimensional (3D) metallic patterns from 3D printed polymeric structures utilizing different hygroscopic swelling behavior of two different polymeric materials. 3D patterns are printed with two different polymers as cube shape. The surface of the 3D printed polymeric structures is plated with nickel by an electroless plating method. The nickel patterns on the surface of the 3D printed cube shape structure are formed by removing sacrificial layers using the difference in the rate of hygroscopic swelling between two printing polymer materials. The hygroscopic behavior on the interfaced structure was modeled with COMSOL Multiphysics. The surface and electrical properties of the fabricated three-dimensional patterns were analyzed and characterized.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.34 no.12
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• pp.457-463
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• 1985

This paper studies on the tracking phenamena by the IEC recommended method with various polymeric insulating materials which are used in industrial fields. Under the same experimental condition, according to the materials it is observed that there are the type of tracking breakdown and the type of tracking erosion. In the tracking breakdown type materials, the tracking breakdown is occurred at a small number of drops increasing of test voltage and solution density. In the tracking erosion type materials, the erosion depth is saturated or proportioned as increasing of test voltage and solution density.

• Korean Journal of Materials Research
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• v.13 no.3
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• pp.180-184
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• 2003

Ce-doped $Y_2$SiO$_{5}$ phosphor particles of spherical morphology, fine size, high crystallinity and high photoluminescence (PL) intensity were prepared by spray pyrolysis. When nitrate precursor solution is adopted, hollow particles were formed by uneven drying rate between surface and inside of droplet. Citric acid and ethylene glycol were introduced as polymeric precursor to control the morphology of particles. When polymeric solution is adopted, polymeric chain is formed by the esterification reaction between carboxyl and hydroxy groups of citric acid and ethylene glycol, and considered as controlling the drying characteristics of droplet. $Y_2$$SiO_{5}$ :Ce phosphor particles prepared from polymeric precursor solution were spherical, filled, fine size and not agglomerate before and after post heat treatment. The optimum doping concentration of cerium was 0.5 mol% of overall solution concentration. The optimum amount of TBOS of high PL intensity and pure crystallinity of X2-type $Y_2$$SiO _{5}$ was 105% of stoichiometric amount. The PL intensity of $Y_2$X$/_{5}$ :Ce phosphor particles prepared using the polymeric precursor solution was 164% of that of the nitrate precursor solution due to homogeneous composition and good morphology.y.