• Bulletin of the Korean Chemical Society
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• v.29 no.4
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• pp.799-804
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• 2008

An amphiphilic diacetylene compound was deposited on the surface of nano sized magnetite particles ($Fe_3O_4$) using a self-assembly method. The diacetylene molecular assembly formed on the surface of nanoparticle was subjected to photopolymerization. This resulted in the formation of a polymeric assembly on the surface of the nanoparticles in which the adjacent diacetylene molecules were connected through conjugated covalent networks. The presence of immobilized polymer species on the surface of nanoparticles is expected to protect them from agglomeration and ripening, thereby stabilizing their physical properties. In this work, $Fe_3O_4$ nanoparticles were prepared by chemical coprecipitation method and the diacetylene molecule 10,12- pentacosadiynoic acid (PCDA) was anchored to the surface of $Fe_3O_4$ nanoparticles through its carboxylate head group. Irradiation of UV light on the nanoparticles containing immobilized diacetylenes resulted in the formation of a polymeric assembly. Presence of diacetylene molecules on the surface of nanoparticles was confirmed by X-ray photoelectron spectroscopy and FT-IR measurements. Photopolymerization of the diacetylene assembly was detected by UV-Visible spectroscopy. Magnetic properties of the nanoparticles coated with polymeric assembly were investigated with SQUID and magnetic hysteresis showed superparamagnetic behaviors. The results put forward a simple and effective method for achieving polymer coating on the surface of magnetic nanoparticle.

• Journal of the Korean Magnetic Resonance Society
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• v.1 no.2
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• pp.126-140
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• 1997

Mesoporous MCM-41 gallosilicate material was synthesized through shifting through shifting gallosilicate polymer equilibrium towards a MCM-41 phase by addition of acid. The location of Cu(II) exchanged into MCM-41 and its interaction with various adsorbate molecules were investigated by electron spin responance and electron spin echo modulation spectroscopies. It was found that in the fresh hydrated material, Cu(II) is octahedrally coordinated to six water molecules. This species is located in a cylindrical channel and rotates rapidly at room temperature. Evacuation at room temperature removes three of these water molecules, leaving the Cu (II) coordinated to three water molecules and anchored to oxygens in the channel wall. Dehydration at 45$0^{\circ}C$ produces one Cu (II) species located in the inner surface of a channel as evidenced by broadening of its ESR lines by oxygen. Adsorption of polar molecules such as water, methanol and ammonia on dehydrated CuNa-MCM-41 gallosilicate material causes changes in the ESR spectrum of Cu (II), indicating the complex formation with these adsorbates. Cu (II) forms a complex with six molecules of methanol as evidenced by an isotropic room temperature ESR signal and ESEM data like upon water adsorption. Cu(II) also forms a complex containing four molecules of ammonia based on resolved nitrogen superhyperfine interaction.

• Structural Engineering and Mechanics
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• v.64 no.1
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• pp.135-143
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• 2017

To upgrade shear performance of reinforced concrete (RC) beams, and particularly of the segments under negative moment within continuous T-section beams, a series of original schemes has been proposed using carbon fibre-reinforced polymer (CFRP) U-shaped strips for shear-strengthening. The current work focuses on one of them, in which CFRP U-strips are wound around steel bars against the top of the flange of a T-beam and then spliced on its bottom face in addition to being bonded onto its sides. The test results showed that the proposed scheme successfully provided reliable anchorage for U-strips and prevented premature onset of shear failure due to FRP debonding. The governing shear mode of failure changed from peeling of CFRP to its fracture or crushing of concrete. The strengthened specimens displayed an average increase of about 60% in shear capacity over the unstrengthened control one. The specimen with a relatively high ratio and uniform distribution of CFRP reinforcement had a maximum increase of nearly 75% in strength as well as significantly improved ductility. The formulas by various codes or guidelines exhibited different accuracy in estimating FRP contribution to shear resistance of the segments that are subjected to negative moment and strengthened with well-anchored FRP U-strips within continuous T-beams. Further investigation is necessary to find a suitable approach to predicting load-carrying capacity of continuous beams shear strengthened in this way.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.6
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• pp.2797-2803
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• 2012

This paper presents the pull-out behaviors of headed glass fiber reinforced polymer (GFRP) rebar embedded in mortar under tension loading. Five specimens with headed GFRP rebars that were anchored in the center of mortar bases were constructed and the pull-out test was conducted. To verify the test results, the finite element analysis was conducted and the results were compared with the FE analysis using ANSYS software package. Based on the test results it was indicated that the CCD(concrete capacity design) failure theory should be adopted and not to use the 45o cone failure theory as the breakout capacity in the headed GFRP rebar embedded in mortar.

• Structural Engineering and Mechanics
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• v.37 no.1
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• pp.111-129
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• 2011

This paper presents a nonlinear analysis of reinforced concrete column with lap splice confined by FRP wrapping in the critical hinging zone. The steel stress-slip model derived from the tri-uniform bond stress model presented in the companion paper is included in the nonlinear frame analysis to simulate the response of reinforced concrete columns subjected to cyclic displacement reversals. The nonlinear modeling is based on a fiber discretization of an RC column section. Each fiber is modeled as either nonlinear concrete or steel spring, whose load-deformation characteristics are calculated from the section of fiber and material properties. The steel spring that models the reinforcing bars consists of three sub-springs, i.e., steel bar sub-spring, lap splice spring, and anchorage bond-slip spring connected in series from top to bottom. By combining the steel stress versus slip of the lap splice, the stress-deformation of steel bar and the steel stress-slip of bars anchored into the footing, the nonlinear steel spring model is derived. The analytical responses are found to be close to experimental ones. The analysis without lap splice springs included may result in an erroneous overestimation in the strength and ductility of columns.

• Polymer(Korea)
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• v.36 no.4
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• pp.486-493
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• 2012

Photocurable sulfonated polyimide (SPI) polyelectrolyte containing chalcone group was prepared and fabricated on an alumina electrode pretreated with chalcone-containing silane-coupling agent. SPI films with bis(tetramethyl)ammonium 2,2'-benzidinedisulfonate ($Me_4N$-BDS)/4,4'-diaminochalcone (DAC)/pyromellitic dianhydride (PA)= 90/10/100 possessed very linear response(Y = -0.04528X+7.69446, $R^2=0.99675$) and showed resistance changing from 4.48 to $2.1k{\Omega}$ between 20 and 95 %RH. The response time for absorption and desorption measurements between 33 and 94 %RH% was about 79 s, which affirmed the high efficiency of crosslinked SPI film for rapid detection of humidity. A negative temperature coefficient showing $-0.49%RH/^{\circ}C$ was found and proper temperature compensation should be considered in future applications. Moreover, pretreatment of the substrates with chalcone-containing silane-coupling agent was performed to improve the water durability and the stability of the humidity sensors at a high humidity and a high temperature and long-term stability for 480 h. The crosslinked SPI films anchored to electrode substrate could be a promising material for the fabrication of efficient humidity sensors with superior characteristics compared to the commercially available sensors.