• Title/Summary/Keyword: Polymer-alkaline electrolyte

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터 의 개발)

  • 오길훈;김한주;최원경;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Economic Evaluation of Domestic Low-Temperature Water Electrolysis Hydrogen Production (국내 저온수전해 수소생산의 경제성 평가)

  • Gim, Bong-Jin;Kim, Jong-Wook;Ko, Hyun-Min
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.4
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    • pp.559-567
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    • 2011
  • This paper deals with an economic evaluation of domestic low-temperature water electrolysis hydrogen production. We evaluate the economic feasibility of on-site hydrogen fueling stations with the hydrogen production capacity of 30 $Nm^3/hr$ by the alkaline and the polymer electrolyte membrane water electrolysis. The hydrogen production prices of the alkaline water electrolysis, the polymer electrolyte membrane water electrolysis, and the steam methane reforming hydrogen fueling stations with the hydrogen production capacity of 30 $Nm^3/hr$ were estimated as 18,403 $won/kgH_2$, 22,945 $won/kgH_2$, 21,412 $won/kgH_2$, respectively. Domestic alkaline water electrolysis hydrogen production is evaluated as economical for small on-site hydrogen fueling stations, and we need to further study the economic evaluation of low-temperature water electrolysis hydrogen production for medium and large scale on-site hydrogen fueling stations.

Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances (고체 알칼리 연료전지용 음이온 교환 세공충진막의 제조 및 특성)

  • Choi, Young-Woo;Park, Gu-Gon;Yim, Sung-Dae;Lee, Mi-Soon;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.150-153
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    • 2009
  • Anion exchange polymer electrolyte pore-filling membranes consisting of the whole hydrocarbon materials were prepared by photo polymerization with various quaternary ammonium cationic monomers and characterized on the properties for applying to solid alkali fuel cell (SAFC). Hydrocarbon porous substrates such as polyethylene were used for the preparation of the pore-filling membranes. The hydroxyl ion conductivity of the polymer electrolyte membranes prepared in this research was dependent on the composition ratio of an electrolyte monomer and crosslinking agents used for polymerization. Furthermore, these pore-filling membranes have commonly excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lower fuel crossover through the membranes, and easier preparation process than those of traditional cast membranes.

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Research and Development Trend of Electrolyte Membrane Applicable to Water Electrolysis System (수전해 시스템에 적용 가능한 전해질막 연구 개발 동향)

  • Im, Kwang Seop;Son, Tae Yang;Kim, Kihyun;Kim, Jeong F.;Nam, Sang Yong
    • Applied Chemistry for Engineering
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    • v.30 no.4
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    • pp.389-398
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    • 2019
  • Hydrogen energy is not only a solution to climate change problems caused by the use of fossil fuels, but also as an alternative source for the industrial power generation and automotive fuel. Among hydrogen production methods, electrolysis of water is considered to be one of the most efficient and practical methods. Compared to that of the fossil fuel production method, the method of producing hydrogen directly from water has no emission of methane and carbon dioxide, which are regarded as global environmental pollutants. In this paper, the alkaline water electrolysis (AWE) and polymer electrolyte membrane water electrolysis (PEMWE), which are one of the hydrogen production methods, were discussed. Recent research trends of hydrocarbon electrolyte membranes and the crossover phenomenon of electrolyte membranes were also described.

Current Patents and Papers Research Trend of Fuel Cell Membrane (특허 및 논문 게재 분석을 통한 연료전지용 전해질막의 연구동향)

  • Woo, Chang Hwa
    • Membrane Journal
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    • v.26 no.6
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    • pp.407-420
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    • 2016
  • The fuel cell technology as a green energy source has been actively studied to solve energy shortages and pollution problems. The generating efficiency of fuel cell is high because the electricity is directly produced by using hydrogen and oxygen and the additional power generator is not needed. The key technology is the manufacturing process of polymer electrolyte membranes for polymer electrolyte membrane fuel cell (PEMFC) system. The Nafion, perfluoro-based polymeric membrane is mainly used as a polymer electrolyte membrane. However, the Nafion is expensive and rapidly decreases the performance of Nafion at high temperature. So, many researchers are lively studying new alternative electrolyte membranes. In this review, through the technology competitiveness evaluation of patents and papers, the frequencies of presentation are filed by country, institution and company. In addition, polymer electrolyte membrane fuel cell, direct methanol fuel cell and alkaline fuel cell are also filed.

Pore-filling anion conducting membranes and their cell performance for a solid alkaline fuel cell (세공충진 음이온 전도성막의 제조 및 이를 이용한 고체알칼리 연료전지 성능 평가)

  • Choi, Youngwoo;Lee, Misoon;Park, Gugon;Yim, Sungdae;Yang, Taehyun;Kim, Changsoo
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.129.2-129.2
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    • 2010
  • AEM which were used for solid alkaline fuel cell(SAFC) were prepared by photo polymerization in method pore-filling with various quaternary ammonium cationic monomers and crosslinkers without an amination process. Their specific thermal and chemical properties were characterized through various analyses and the physico-chemical properties of the prepared electrolyte membranes such as swelling behavior, ion exchange capacity and ionic conductivity were also investigated in correlation with the electrolyte composition. The polymer electrolyte membranes prepared in this study have a very wide hydroxyl ion conductivity range of 0.01 - 0.45S/cm depending on the composition ratio of the electrolyte monomer and crosslinking agent used for polymerization. However, the hydroxyl ion conductivity of the membranes was relatively higher at the whole cases than those of commercial products such as A201 membrane of Tokuyama. These pore-filling membranes have also excellent properties such as smaller dimensional affects when swollen in solvents, higher mechanical strength, lowest electrolyte crossover through the membranes, and easier preparation process compared of traditional cast membranes. The prepared membranes were then applied to solid alkaline fuel cell and it was found comparable fuel cell performance to A201 membrane of Tokuyama.

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터의 개발)

  • Oh, Kil-Hun;Kim, Han-Joo;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Impedance analysis of electrochemical systems using an ion-conducting polymer electrolyte membrane (전도성 고분자 전해질막을 이용하는 전기화학적 시스템의 임피던스 해석)

  • Park, Jin-Soo;Moon, Seung-Hyeon;Kim, Chang-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.1-8
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    • 2004
  • Ion-conducting polymer electrolyte membranes (PEMs) have recently used in developing fuel cell or solar cell for portable, mobile and residential applications [1]. Polymer electrolyte membrane fuel cell (PEMFC), direct methanol fuel cell (DMFC), alkaline electrolyte fuel cell (AFC) and dye-sensitized solar cell have been employing the ion-conducting PEMs to complete their electrical circuits to produce electricity.(omitted)

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Electrochemical Properties of Activated Carbon Supecapacitor Adopting Poly(acrylonitrile) Separator Coated by Polymer-Alkaline Electrolytes (고분자-알칼리 전해질이 코팅된 Poly(acrylonitrile) 분리막을 적용한 활성탄 수퍼커패시터 특성)

  • Kim, Kwang Man;Lee, Young-Gi;Ko, Jang Myoun
    • Korean Chemical Engineering Research
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    • v.55 no.4
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    • pp.467-472
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    • 2017
  • Alkaline electrolytes consisting of 6 M KOH and polymer (PEO, PVA, and PAAK) are coated on PAN nonwoven fabrics as a separator, and the electrochemical properties of the activated carbon supercapacitor adopting them are investigated in terms of redox behavior, specific capacitance, and interfacial impedance. Although the interaction between polymer and KOH are comparatively inactive in PEO and PVA, PAAK (3 wt.%)-KOH forms a hydrogel phase by active interactions between $COO^-K^+$ in side-chain of PAAK and $K^+OH^-$ from alkaline electrolyte solution, improving ionic conduction of electrolytes and the electrochemical properties of the supercapacitor. As a result, the activated supercapacitor adopting the PAAK-KOH shows the superior specific capacitance of $46.8Fg^{-1}$ at $100mVs^{-1}$.