• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 봄 학술발표회 논문집
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• pp.87-92
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• 2002

At present, the polymer-modified mortars are used as high-performance as well as multi-functional materials in the construction industry. The purpose of this study is to synthesize polymer to modify in cement mortars and make test samples to understand pore size distribution. This paper deals with the effect of monomer ratio on the typical properties of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate(MMA/BA) latexes synthesized through emulsion polymerization. From the results, we knew that the pore volume of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate latexes at bound MMA contents of 70 and 60 percent is 7.5-75cm$^3$/g and the fine pore volume is increased with an increase in the polymer-cement ratio. The total pore volume of polymer-modified mortars using MMA/BA latexes is linearly reduced with an increase in the bound MMA content and increased in the polymer-cement ratio.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.235-239
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• 1994

Polymer mortars are mainly used as protective coatings in concrete, reinforced concrete, and more rarely, steel, while polymer concretes represent a new type of structural material capable of withstanding highly corrosive environments. The mechanical properties, chemical stability, and some other useful properties are the reasons research, design, and production organizations. However polymer mortars and polymer concretes have been introduced only recently, and many of their properties are still imperfectly known. And, the main technique in producing polymer concrete is to minimize void volume in the aggregate mass so as to reduce the quantity of the relatively impressive polymer necessary for binding the aggregate. In this study, compressive strength and flexural strength of unsaturated polyester resin concrete are related to quantity of resin and solid volume of aggregate. It was founded that the more solid volume of aggregate increase, the less using quantity of resin decrease with out reducing mechnical properties. When solid volume ratio of aggregate is 70.6%, using quantity of resin is minimized to 10wt.%.

• 콘크리트학회논문집
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• 제15권2호
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• pp.273-279
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• 2003

본 연구에서는 MMA/BA 합성 라텍스를 이용하여 폴리머 시멘트 모르타르의 성질에 영향을 미치는 모노머비의 효과를 검토하고, 시멘트 혼화용 폴리머로서의 개발적용을 위해 필요한 기초적 실험 데이터를 얻기 위한 것이다. 실험결과, MMA/BA모노 머비에 따른 폴리머 시멘트 모르타르의 세공경 분포는 MMA/BA의 비가 60 : 40, 70 : 30에서 미세공극량이 크게 증가했으며, 전세공용적은 감소하였다. 또한 모노머비에 관계없이 폴리머 시멘트 비가 증가할수록 그 효과는 더욱 커지는 것으로 나타났다. 일반적으로 MMA/BA 혼입 폴리머 시멘트 모르타르의 압축강도는 MMA 결합재량 70% 및 폴리머-시멘트비 15%에서 가장 우수하게 나타났으며, 흡수율과 염화물 이온 침투저항성은 MMA 결합재량보다는 폴리머-시멘트비에 의해 크게 지배되는 것으로 나타났다. 모노머비를 변화한 MMA/BA 합성 라텍스 혼입 폴리머 시멘트 모르타르의 성질에 영향을 미치는 중요한 인자는 MMA 결합재량의 변화에 의한 세공경분포의 변화와 폴리머-시멘트비로 나타났다.

• 한국세라믹학회지
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• 제51권2호
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• pp.127-131
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• 2014

Precipitated calcium carbonate(PCC) inorganic fillers for plastic offera higher replacement ratio with improved mechanical properties than any other inorganic fillers. Due to its secure economic feasibility, its fields of application areexpanding. For optimized PCC grain size and polymer replacement ratio, it is good to maintain at least $0.035{\mu}m$ grains and keep double the grain size of distance between particles, depending on the molecular weight and volume replacement rate of the polymer. PCC has unique characteristics, ie, with smaller grain size, dispersibility decreases, and if grain size is not homogenous, polymer cracking occurs. The maximum replacement ratio of PCC is approximately 30%, but in the range of 10 - 15% it produces the highest mechanical strength. When mixed with a biodegradable plastic like starch, it also improves initial environmental degradability.

• 한국농공학회논문집
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• 제54권2호
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• pp.157-166
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• 2012

Most of the roads are paved with impermeable materials such as asphalt concrete and cement concrete, and in the event of heavy rainfall, rainwater directly flows into river through a drainage hole on the pavement surface. This large quantity of rainwater directly spilled into the river frequently leads to the flooding of urban streams, damaging lowlands and the lower reaches of a river. In recent years there has been a great deal of ongoing research concerning water permeability and drainage in pavements. Accordingly, in this research, a porous polymer concrete was developed for permeable pavement by using unsaturated polyester resin as a binder, recycled aggregate as coarse aggregate, fly ash and blast furnace slag as filler, and its physical and mechanical properties were investigated. Also, 3 types of permeable polymer block by optimum mix design were developed and rainfall runoff reduction effects by permeability pavement using permeable polymer block were analyzed based on hydraulic experimental model. The infiltration volume, infiltration ratio, runoff initial time and runoff volume in permeability pavement with permeable polymer block of $300{\times}300{\times}80$ mm were evaluated for 50, 100 and 200mm/hr rainfall intensity.

• 대한기계학회논문집A
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• 제21권10호
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• pp.1609-1618
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• 1997

Thermo-mechanical behaviors of polymer matrix composite(PMC) with continuous TiNi fiber are studied using theoretical analysis with 1-D analytical model and numerical analysis with 2-D multi-fiber finite element(FE) model. It is found that both compressive stress in matrix and tensile stress in TiNi fiber are the source of strengthening mechanisms and thermo-mechanical coupling. Thermal expansion of continuous TiNi fiber reinforced PMC has been compared with various mechanical behaviors as a function of fiber volume fraction, degree of pre-strain and modulus ratio between TiNi fiber and polymer matrix. Based on the concept of so-called shape memory composite(SMC) with a permanent shape memory effect, the critical modulus ratio is determined to obtain a smart composite with no or minimum thermal deformation. The critical modulus ratio should be a major factor for design and manufacturing of SMC.

• 공업화학
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• 제19권6호
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• pp.652-660
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• 2008

급냉 제강슬래그를 재활용하기 위하여 제강슬래그의 치환율을 다양하게 변화시켜 만든 EVA-폴리머 시멘트 모르타르의 기계적강도와 물성에 대하여 조사하였다. EVA-폴리머 시멘트 모르타르 공시체는 폴리머-시멘트비를 5단계(0, 5, 10, 15, 20 wt%), 급냉 제강슬래그의 치환율을 5단계(0, 25, 50, 75, 100 wt%)로 각각 변화시켜 총 25 종류의 공시체를 제작하였다. 공시체의 제 성능을 조사하기 위하여 후레쉬 모르타르의 물-시멘트비, 단위용적중량, 공기량과 경화 공시체의 압축 및 휨강도, 흡수시험, 내열수성시험, 세공분포측정 및 SEM에 의한 미세조직 관찰 등을 실시하였다. 그 결과 급냉 제강슬래그의 치환율이 증가됨에 따라 물-시멘트비는 감소되었으나 단위용적중량은 현저히 증가 되었다. 폴리머-혼화제 및 급냉 제강슬래그의 첨가량 증가에 따라 흡수율은 감소되었으나, 압축 및 휨강도는 현저히 증가되었다. 내열수성시험에 의하여 기계적강도는 현저히 감소되었으나, 세공량과 공극률은 현저히 증가되었다. 전자현미경 관찰에서 내열수시험 전의 조직은 견고하게 융착되어 있었으나 내열수시험 후의 조직에서는 폴리머-혼화제가 분해 또는 열화되어 있는 것을 관찰할 수 있었다.

• 폴리머
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• 제32권6호
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• pp.603-609
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• 2008

본 연구에서는 MMA(methyl methacrylate)와 BA(buthyl acrylate)를 단량체로 이용한 폴리머 시멘트 모르타르의 단량체 비에 따른 성질을 파악하고 시멘트 혼화용 폴리머로 활용하기 위한 기초적 자료를 얻고자 하였다. 본 연구결과 MMA/BA를 이용한 폴리머 시멘트 모르타르의 전 세공용적은 MMA/BA의 단량체 비가 증가할수록 감소하는 것으로 나타났다. 강도특성에서는 전체적으로 MMA/BA의 단량체 비가 70 : 30, 그리고 80 : 20일 때, 폴리머 시멘트 비가 15%일 때 가장 우수한 증진효과를 나타냈다. 폴리머 시멘트 모르타르의 내구성을 측정하는 흡수율, 염화물 이온 침투 저항성, 중성화 저항성에서는 단량체 비에 따른 개선보다는 폴리머 시멘트 비에 따른 개선효과가 더 큰 것으로 나타났다.

• 한국농공학회논문집
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• 제52권1호
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• pp.69-77
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• 2010

Research on permeable pavement like asphalt and concrete pavement with porous structure has been increasing due to environmental and functional need such as reduction of run off and flood, and increase and purification of underwater resource. This study was performed to evaluate permeability, strengths and durability of permeable polymer concrete (PPC) using recycled aggregate that is obtained from waste concrete. Also, 6mm length of polypropylene fiber was used to increase toughness and interlocking between aggregate and aggregate surrounded by binder. In the test results, regardless of kinds of aggregates and fiber contents, the compressive strength and permeability coefficient of all types of PPC showed the higher than the criterion of porous concrete that is used in permeable pavement in Korea. Also, strengths of PPC with increase polypropylene fiber volume fraction showed slightly increased tendency due to increase binder with increase of fiber volume fraction. The weight reduction ratios for PPC after 300 cycles of freezing and thawing were in the range of 1.6~3.8 % and 2.2~5.6 %, respectively. The weight change ratio was very low regardless of the fiber volume fraction and aggregates. The weight reduction ratios of PPC with fiber and aggregate were in the range of 1.3~2.7 % and 2.2~3.2 % after 13 weeks and was very low regardless of the fiber volume fraction and aggregates.

• 농업과학연구
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• 제37권2호
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• pp.277-283
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• 2010

Research on permeable pavement like asphalt and concrete pavement with porous structure has been increasing due to environmental and functional need such as reduction of run off and flood. This study was performed to evaluate void ratio, permeability coefficient, and compressive strength of permeable polymer concrete (PPC) using crushed and recycled coarse aggregate that is obtained from waste concrete. Also, 6 mm length of polypropylene fiber was used to increase toughness and interlocking between aggregate and aggregate surrounded by binder. Binder and filler used were unsaturated polyester resin and CaCO3, respectively. The mix proportions were determined to satisfy the requirement for the workability and slump according to aggregate sizes 5~10 mm. In the test results, regardless of kinds of aggregates and fiber contents, the void ratio, permeability coefficient and compressive strength of all types of PPC showed the higher than the criterion of porous concrete that is used in permeable pavement in Korea. Also, strengths of PPC with increase polypropylene fiber volume fraction showed slightly increased tendency due to increase binder with increase of fiber volume fraction. Accordingly, polypropylene fiber and recycled coarse aggregate can be used for permeable pavement.