• Journal of the Korean Chemical Society
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• v.57 no.5
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• pp.625-633
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• 2013

A type of polycyclotriphosphazene derivative (PCTPD), hexasulfanilic acid polycyclotriphosphazene (HSACP) and HSACP grafting SPEEK, sulfonated poly[2-(petachloropolycyclotriphosphazene-oxy)] etheretherketone (SPPSACPEEK) were synthesized, which were characterized by FTIR and $^{31}P$ NMR. Then three types of composite membranes such as HSACP grafting SPEEK, HSACP blending SPEEK, and nano $Y_2O_3$ doping and HSACP grafting SPEEK, respectively, were continuously prepared by solution-casting method. Comparing to SPEEK membranes with different amount of HSACP grafted or blended, grafting 15 wt% HSACP and doping 10 wt% nano $Y_2O_3$ SPEEK membrane conducted outstanding overall behavior of proton conductivity reaching $3.18 {\times}10^{-2}$ S/cm at $90^{\circ}C$ which was merely junior to SPEEK with 15 wt% HSACP grafted, methanol permeability coefficient getting $9.46{\times}10^{-8}cm^2{\cdot}s^{-1}$, swelling degree of 20.9% and solid residue of 98.98% which was superior to all specimen.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.11a
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• pp.449-452
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• 2004

The lap splice lengths of deformed steel reinforcing bars and GFRP bars with two different to surface type were experimentally compared using beam specimens. The purpose was to evaluate the length required of the GFRP bar to develop strength equivalent to the conventional steel reinforcing bar. The main test variable was the lap splice length. Two different GFRP bar surfaces were tested: (1) spiral-type GFRP bars and (2) sand coated GFRP bars. For the conventional steel bars (SD400 grade), strength over 400 MPa in tension was reached using the lap splice length of $30d_b$. Splice failure was observed in the specimen with the lap splice length of $20d_b$. For the spiral-type and sand coated GFRP bars, the tensile strength developed in the GFRP bars decreased with decreasing splice lengths. Development of the cracks on beam surfaces was clearly visible for the beams reinforced with the GFRP bars. Mid-span deflections, however, were significantly smaller than the comparable beams with conventional steel bars indicating potential ductility problem.

• Journal of electromagnetic engineering and science
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• v.14 no.3
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• pp.293-298
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• 2014

Large spaceborne antennas should be lightweight, a factor related to the development costs of launch vehicles. In order to overcome this drawback, a feasibility study of a new carbon fiber reinforced polymer (CFRP) named M55J/RS3 is carried out for a synthetic aperture radar (SAR) reflector antenna. In particular, the high resolution of detected images is taken into consideration. To validate the electrical performance, a test of the CFRP specimen is fabricated, and the transmission/reflection coefficients are measured using a standard X-band waveguide. Finally, the effective complex permittivity and effective electrical conductivity are derived from the obtained measured data. By applying the derived conductivity to the simulation of the radiation pattern, antenna gain, and beamwidth-instead of relying on the assumption of a perfect electric conductor-variations in electrical performance are also investigated and discussed.

• Steel and Composite Structures
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• v.22 no.6
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• pp.1487-1505
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• 2016

This paper presents the results of an experimental study on the behavior of a new type of composite FRP-concrete-steel member subjected to bi-axial eccentric loading. This new type of composite member is in the form of concrete-filled square steel tube slender columns with inner CFRP (carbon fiber-reinforced polymer) circular tube, composed of an inner CFRP tube and an outer steel tube with concrete filled in the two tubes. Tests on twenty-six specimens of high strength concrete-filled square steel tube columns with inner CFRP circular tube columns (HCFST-CFRP) were carried out. The parameters changed in the experiments include the slenderness ratio, eccentric ratio, concrete strength, steel ratio and CFRP ratio. The experimental results showed that the failure mode of HCFST-CFRP was similar to that of HCFST, and the specimens failed by local buckling because of the increase of lateral deflection. The steel tube and the CFRP worked together well before failure under bi-axial eccentric loading. Ductility of HCFST-CFRP was better than that of HCFST. The ultimate bearing capacity of test specimen was calculated with simplified formula, which agreed well with test results, and the simplified formula can be used to calculate the bearing capacity of HCFSTF within the parameters of this test.

• Journal of Surface Science and Engineering
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• v.50 no.6
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• pp.523-530
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• 2017

In this study, we developed the h-BN interphase for ceramic matrix composites (CMCs) through a wet chemical coating method, which has excellent price competitiveness and is a simple process as a departure from the existing high cost chemical vapor deposition method. The optimum condition for nitriding an h-BN interphase using boric acid and urea as precursors were derived, and the h-BN interphase coating through a wet method on a carbon preform of 2.5 D was conducted to apply the optimum conditions to the CMCs. In order to control the coating property via the wet coating method, four parameters were investigated such as dipping time of the specimen in the precursor solution, the ratio of boric acid and urea in the precursor, the concentration of solution where the precursor was dissolved, and the cycle of dipping and dry process. The CMCs was fabricated through polymer impregnation and pyrolysis (PIP) processes and a three-point flexural strength test was conducted to verify the role of the coated h-BN interphase.

• Macromolecular Research
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• v.16 no.6
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• pp.561-566
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• 2008

NR composites with different curing systems were aged thermally at 60, 70, 80, and $90^{\circ}C$ for 2-185 days in a convection oven, and the changes in the crosslink density were investigated as a function of the accelerated thermal aging. The overall crosslink densities increased with increasing aging time irrespective of the aging temperatures and curing systems. The changes in crosslink density were enhanced by increasing the aging temperature. The degree of the increased crosslink density was in the following order: "the conventional cure system > the semi-EV system > the EV system". For short term thermal aging, the change in crosslink density with the aging time was complicated, particularly for low temperature aging. The activation energies of the change in crosslink density with thermal aging using the conventional and semi-EV cure systems increased and then remained relatively constant with increasing aging time, whereas that of the specimen with an EV cure system tended to increase linearly. The experimental results were explained by the dissociation of the existing polysulfidic linkages and the formation of new cross links through the crosslinking-related chemicals remaining in the sample.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.914-917
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• 2005

The paper proposes a new sonic resonance test for a dynamic elastic constant measurement which is based on time-average electronic speckle pattern interferometry(TA-ESPI)and Euler-Bernoulli equation. Previous measurement technique of dynamic elastic constant has the limitation of application for thin film or polymer material because contact to specimen affects the result. TA-ESPI has been developed as a non-contact optical measurement technique which can visualize resonance vibration mode shapes with whole-field. The maximum vibration amplitude at each vibration mode shape is a clue to find the resonance frequencies. The dynamic elastic constant of test material can be easily estimated from Euler-Bernoulli equation using the measured resonance frequencies. The TA-ESPI dynamic elastic constant measurement technique is able to give high accurate elastic modulus of materials through a simple experiment and analysis.

• Earthquakes and Structures
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• v.17 no.4
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• pp.337-354
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• 2019

This paper presents the results of experimental and numerical studies conducted to investigate the behavior of exterior reinforced concrete beam column joints (BCJ) strengthened by using carbon fiber reinforced polymer (CFRP) sheets. Twelve reinforced concrete beam-column joints (BCJ) were tested in an experimental program by simulating the joints in seismically deficient old buildings. One group of BCJs was designed to fail in flexure at the BCJ interface, and the second group was designed to ensure joint shear failure. One specimen in each set was -retrofitted with CFRP sheet wrapped diagonally around the joint. The specimens were subjected to both monotonic and cyclic loading up to failure. 3D finite element simulation of the BCJs tested in the experimental program was carried out using the software ABAQUS, adopting the damage plasticity model (CDP) for concrete. The experimental results showed that retrofitting of the shear deficient, BCJs by CFRP sheets enhanced the strength and ductility and the failure mode changed from shear failure in the joints to the desired flexural failure in the beam segment. The FE simulation of BCJs showed a good agreement with the experimental results, which indicated that the CDP model could be used to model the problems of the monotonic and cyclic loading of beam-column reinforced concrete joints.

• International journal of steel structures
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• v.18 no.4
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• pp.1284-1296
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• 2018

Carbon fiber reinforced polymer (CFRP), plates bonding repair method is one of the simple repair methods for cracked steel structures. In this study, the influence of width of CFRP plates on bending fatigue life of out-of-plane gusset joint strengthened with CFRP plates was investigated from the experimental and numerical point of view. In the bending fatigue test of cracked out-of-plane gusset joint strengthened with CFRP plates, the effect of width of CFRP plates on crack growth life was clarified experimentally. Namely, it was revealed that the crack growth life becomes larger with increasing the width of CFRP plates. In the numerical approach, the stress intensity factor (SIF) at the surface point of a semi-elliptical surface crack was estimated based on the linear fracture mechanics. Furthermore, the extended fatigue life of cracked out-of-plane gusset joint strengthened with CFRP plates was evaluated by using the estimated SIF at the surface point and the empirical formula of the aspect ratio of semi-elliptical crack. As the results of numerical analysis, the estimated fatigue life of the specimen strengthened with CFRP plates showed the good agreement with the test results.

• Structural Monitoring and Maintenance
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• v.9 no.3
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• pp.259-270
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• 2022

This study explores the use of the recently developed "strain-sensing smart skin" (S⁴) method for noncontact strain measurements on cement-based samples. S⁴ sensors are single-wall carbon nanotubes dilutely embedded in thin polymer films. Strains transmitted to the nanotubes cause systematic shifts in their near-infrared fluorescence spectra, which are analyzed to deduce local strain values. It is found that with cement-based materials, this method is hampered by spectral interference from structured near-infrared cement luminescence. However, application of an opaque blocking layer between the specimen surface and the nanotube sensing film enables interference-free strain measurements. Tests were performed on cement, mortar, and concrete specimens with such modified S⁴ coatings. When specimens were subjected to uniaxial compressive stress, the spectral peak separations varied linearly and predictably with induced strain. These results demonstrate that S⁴ is a promising emerging technology for measuring strains down to ca. 30 𝜇𝜀 in concrete structures.