• 제목/요약/키워드: Polymer matrix technique

검색결과 70건 처리시간 0.024초

Strengthening of C/C Composites through Ceramer Matrix

  • Dhakate, S.R.;Mathur, R.B.;Dhami, T.L.
    • Carbon letters
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    • 제5권4호
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    • pp.159-163
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    • 2004
  • The polymer-ceramic hybrid, known as 'ceramer', was synthesized by a sol-gel process by incorporating different amount of alkoxide as source of silicon in resorcinol-formaldehyde in presence of basic catalyst to get different percentage of silicon in ultimate carbonized composites. FTIR of the ceramer confirms that it is a network of Si-O-Si, Si-O-$CH_2$ and Si-OH type groups linked with benzene ring. Different amount of silicon in the ceramer exhibits varying temperature of thermal stability and lower coefficient of thermal expansion as compared to pure resorcinol-formaldehyde resin. The lower value of CTE in ceramer is due to existence of silica and resorcinol -formaldehyde in co-continuous phase. Unidirectional composites prepared with ceramer matrix and high-strength carbon fibers show lower value of flexural strength at polymer stage as compared to those prepared with resorcinol-formaldehyde resin. However, after heat treatment to $1450^{\circ}C$, the ceramer matrix composites show large improvement in the mechanical properties, i.e. with 7% silicon in the ceramer, the flexural strength is enhanced by 100% and flexural modulus value by 40% as compared to that of pure resorcinol-formaldehyde resin matrix composites.

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Nano Patterning Functional Polymers Using Nano-imprint Technique

  • 권현근;이규태
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.430.2-430.2
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    • 2014
  • Previous studies to enhance optical properties of opto-electronic devices involve patterning of inorganic materials. Patterning of inorganic material usually encompasses vacuum process that hinders productivity and increases cost. In this research, we successfully formed nano patterns with polymer matrix and fabricated photonic crystals. This process is anticipated to increase the performance of opto-electronic devices without any vacuum process. Moreover, nano imprint technology reduces cost and bolsters productivity.

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Thin-film passivation of the polymer EL device using parylene and its application to the passive matrix PELD system

  • Lee, Cheon-An;Jin, Sung-Hun;Jung, Keum-Dong;Lee, Jong-Duk;Park, Byung-Gook
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.669-672
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    • 2004
  • The thin-film passivation technology using the poly-para-xylylene (parylene) was applied to polymer electroluminescent devices. The fabricated device shows a good luminescent characteristic of maximum 11640 cd/$m^2$. The measured lifetime was reached up to 28 hours, which means the effectiveness of the passivation. Applying the parylene thin-film passivation technique, 10${\times}$10 passive matrix display system was implemented and obtained some still images.

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Property improvement of natural fiber-reinforced green composites by water treatment

  • Cho, Dong-Hwan;Seo, Jeong-Min;Lee, Hyun-Seok;Cho, Chae-Wook;Han, Seong-Ok;Park, Won-Ho
    • Advanced Composite Materials
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    • 제16권4호
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    • pp.299-314
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    • 2007
  • In the present study, natural fibers (jute, kenaf and henequen) reinforced thermoplastic (poly(lactic acid) and polypropylene) and thermosetting (unsaturated polyester) matrix composites were well fabricated by a compression molding technique using all chopped natural fibers of about 10 mm long, respectively. Prior to green composite fabrication, natural fiber bundles were surface-treated with tap water by static soaking and dynamic ultrasonication methods, respectively. The interfacial shear strength, flexural properties, and dynamic mechanical properties of each green composite system were investigated by means of single fiber microbonding test, 3-point flexural test, and dynamic mechanical analysis, respectively. The result indicated that the properties of the polymeric resins were significantly improved by incorporating the natural fibers into the resin matrix and also the properties of untreated green composites were further improved by the water treatment done to the natural fibers used. Also, the property improvement of natural fiber-reinforced green composites strongly depended on the treatment method. The interfacial and mechanical results agreed with each other.

Improving the mechanical properties of table tennis by adding nanocomposite in its polymer matrix

  • Shuping Xu;Lixin Liang
    • Advances in nano research
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    • 제16권4호
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    • pp.365-374
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    • 2024
  • This study delves into the significant impact of integrating nanomaterials, specifically carbon and graphene nanoparticles, into the polymer matrix of aluminum alloy 356, utilizing the vortex casting technique, with the aim of improving the mechanical properties of table tennis equipment. Athletes and their coaching teams have long been on a quest for high-performance sports gear, recognizing its pivotal role in unlocking the full potential of players. The dedication of engineers to craft designs, select materials with precision, and uphold stringent testing standards reflects the commitment to meeting the demands of the sporting world. Yet, to remain at the forefront, sports engineering must continually align with contemporary technologies, and nanotechnology has emerged as a transformative force in this regard. This study not only underscores the meticulous efforts in material integration but also highlights the remarkable strides made possible by nanotechnology. Aluminum nanocomposites, particularly, showcase a groundbreaking fusion of exceptional strength and reduced weight, marking a notable achievement in sports equipment innovation. The research outcomes are compelling, revealing a substantial enhancement in the mechanical performance of the sports structures under scrutiny. This promising development hints at a potential paradigm shift in the manufacturing of sports equipment, promising a new era of elevated athlete performance and enhanced safety during the rigors of physical education training. This study stands as a testament to the tangible impact of nanotechnology on the ever-evolving landscape of sports equipment.

복합재료의 열화도 및 경화도에 따른 초음파 특성 연구 (The Evaluation of the thermal degradation and the degree of cure of glass/epoxy composite by ultrasonic technique)

  • 강길호;최원종;박상윤
    • Composites Research
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    • 제16권6호
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    • pp.33-40
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    • 2003
  • 복합재료의 열화에 의한 미세한 손상을 실제적으로 관찰하기는 쉽지 않다. 복합재료의 열화는 심각한 blistering이 일어나기 전에 chain scission, oxidation 등의 분자적인 상변화 과정을 거쳐 모재 또는 모재와 강화제 사이의 계면에서 미세한 delamination이 발생하고 성장한다. 복합재료의 열화에 의한 초기 열손상은 기계적인 특성에 큰 영향을 주게 된다. 본 연구에서는 복합재료 부품이 열이나 화염에 단기간 노출되었을 경우 및 경화도에 따른 초음파 투과 특성을 분석하였다. 온도와 시간에 따라 열화 시험을 실시하고 초음파 탐상을 통하여 absorption coefficient를 측정한 결과 열화에 의한 미소 균열과 분자 적인 상변화에 의하여 열화도가 높을수록 높은 absorption coefficient값을 보였다 경화온도를 달리하여 경화된 복합재료의 초음파 탐상 결과 경화 온도가 높을수록 absorption coefficient 값은 높아졌으며 material velocity는 낮아지는 경향을 보였다. 이는 높은 온도에서 경화될수록 수분 및 휘발 성분에 의한 void와 같은 결함이 많이 발생하고 분자 구조적인 측면에서 높은 온도에서 경화된 경우 초음파 흡수율이 높은 망상구조가 형성되기 때문이다.

Vertically Aligned Nematics at Polymer interfaces and Its device implications

  • Srinivasarao, Mohan;Park, Jung-Ok;Zhou, Jian
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.558-561
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    • 2005
  • In-situ photopolymerization of alkyl acrylate monomers in the presence of a nematic fluid provides a cellular matrix of liquid crystalline droplets in which the chemical structure of the encapsulating polymer exerts control over the alignment (anchoring) of the liquid crystalline molecules. Control is obtained by variation of the alkyl side chains and through copolymerization of two dissimilar monofunctional acrylates. Two monofunctional acrylates with opposing tendencies on copolymerization provide control over the tunability of anchoring over a wide temperature range. Using various acrylates we show that a uniform vertical alignment can be achieved over a large area. Utilizing this technique and a nematic with negative dielectric anisotropy, we have fabricated highly flexible liquid crytal based devices, with high contrast and fast response time, without using any alignment layer.

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Micromechanical 시험법과 AE를 이용한 세라믹 PZT 및 고분자 PVDF 센서에 따른 단섬유 강화 에폭시 복합재료의 비파괴 손상감지능 비교 (Comparison of Nondestructive Damage Sensitivity of Single Fiber/Epoxy Composites Using Ceramic PZT and Polymeric PVDF Sensors By Micromechanical Technique and Acoustic Emission)

  • 정진규;김대식;박종만;윤동진
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 춘계학술발표대회 논문집
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    • pp.135-138
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    • 2004
  • Conventional piezoelectric lead-zirconate-titanate (PZT) senor has high sensitivity, but it is very brittle. Recently polymer films such as polyvinylidene fluoride (PVDF) and poly(vinylidene fluoride­trifluoroethylene) (P(VDF-TrFE)) copolymer have been used as a sensor. The advantages of polymer sensor are the flexibility and mechanical toughness. Simple process and possible several shapes are also additional advantages. Polymer sensor can be directly embedded in a structure. In this study, nondestructive damage sensitivity of single basalt fiber/epoxy composites was investigated with sensor type and thermal damage using AE and oscilloscope. And AE waveform for epoxy matrix with various damage types was compared to each other. The damage sensitivity of two polymer sensors was rather lower than that of PZT sensor. The damage sensitivity of PVDF sensor did not decrease until thermal damage temperature at $80^{\circ}C$ and they decreased significantly at $110^{\circ}C$ However, the damage sensitivity of P(VDF-TrFE) sensor at $110^{\circ}C$ was almost same in no damage sensor. For both top and side impacts, the difference in arrival time increased with increasing internal and surface damage density of epoxy matrix.

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Effect of graphite particulate on mechanical properties of glass fibre reinforced composite

  • Bhattacharjee, Antara;Roy, Kanchan;Nanda, B.K.
    • International Journal of Aerospace System Engineering
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    • 제7권1호
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    • pp.16-20
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    • 2020
  • The recent trend is increasing towards the usage of polymer matrix composites since they have a wide variety of applications. They have applications in the field of aircraft and space industry, sporting goods, medical devices, marine and automotive applications and also in commercial usage. The most commonly used fibre-reinforced polymer matrix composite is Glass fibre reinforced epoxy (GFRE) composite which is used in aviation, sports and automotive industries. However, the strength of GFRE composites is not adequate for structural applications. Therefore, the current research focuses on increasing the strength of GFRE composites by reinforcing with micro Graphite (Gr) particulates. The Gr used is an ultra-fine powder with particle size 250 ㎛. Gr is known to have good wear resistance, thermal conductivity and can operate at high temperatures. Gr particulates are mixed with the epoxy matrix in various weight ratios. Hand-lay technique is used for fabricating the composites. Mechanical properties such as tensile strength, elongation, compressive strength and flexural strength are obtained experimentally to study the effect of change in Gr content (0-5 wt. %). The tests were done as per ASTM standards.

Effect of hygrothermal aging on GFRP composites in marine environment

  • Garg, Mohit;Sharma, Shruti;Sharma, Sandeep;Mehta, Rajeev
    • Steel and Composite Structures
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    • 제25권1호
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    • pp.93-104
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    • 2017
  • In the present work, the effect of hygrothermal aging on the glass fibre and epoxy matrix interface has been investigated by destructive and non-destructive techniques. The glass fiber reinforced polymer (GFRP) composite laminates were prepared using Vacuum Assisted Resin Infusion Molding (VARIM) technique and the specimens were immersed in simulated seawater, followed by quantitative measurement. Besides this, the tensile tests of GFRP specimens revealed a general decrease in the properties with increasing aging time. Also, exposed specimens were characterized by a non-destructive ultrasonic guided Lamb wave propagation technique. The experimental results demonstrate a correlation between the drop in ultrasonic voltage amplitude and fall in tensile strength with increasing time of immersion. Hence, the comparison of the transmitted guided wave signal of healthy vis-a-vis specimens subjected to different extents of hygrothermal aging facilitated performance evaluation of GFRP composites.