• Title/Summary/Keyword: Polymer matrix composite

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Characterization of the mechanical behavior of PEKK polymer and C/PEKK composite materials for aeronautical applications below and above the glass transition temperature

  • Pedoto, Giuseppe;Smerdova, Olga;Grandidier, Jean-Claude;Gigliotti, Marco;Vinet, Alain
    • Advances in aircraft and spacecraft science
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    • v.7 no.6
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    • pp.475-493
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    • 2020
  • This paper is focused on the characterization of the thermomechanical properties of semicrystalline poly-ether-ether-ketone (PEKK) and of carbon fiberreinforced thermoplastic based laminated composites (C/PEKK) below and above the glass transition temperature (Tg). Differential Scanning Calorimetry (DSC), Dynamic Mechanical Analysis (DMA) and tensile tests are carried out on both pure PEKK polymer and [(±45)2, +45]s C/PEKK composite samples, showing a significant similarity in behavior. The employment of a simple micromechanical model confirms that the mechanical and physical behavior of the polymer and that of the matrix in the composite are similar.

Fabrication of PTFE/Al Composite Materials by Hot Press Process (가압소결에 의한 PTFE/AI 복합재료 제조)

  • 이길근;김우열
    • Journal of Powder Materials
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    • v.9 no.2
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    • pp.103-109
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    • 2002
  • To investigate the fabrication possibility of a polymer particle dispersed metal matrix composite, polytetrafluorothylene (PTFE) particles were incorporated into the Al by the powder metallurgy process. The characteristics of a PTFE/Al composite were evaluated by measuring the density and hardness, and analysis of XRD, FT-Raman and microstructure. And wear properties of these composites were evaluated under the dry wear condition. It was possible to obtain the PTFE particles stably dispersed Al matrix composites by the hot press process at the sintering temperature of $500^{\circ}C$. The wear coefficient of a PTFE/Al compoite decreased with increasing of the volume fraction of PTFE. The wear weight of a PTFE/Al composite increased with increasing of the volume fractionof PTFE in the range of 0~10 vol.%PTFE, and showed maximum value at 10 vol.%PTFE, and then decreased at 20vol.%PTFE.

Matrix Resin Systems with Different Molar Ratios to Improve the Properties of Fiber-reinforced Composites (섬유강화 복합재료의 물성향상을 위한 몰비가 다른 매트릭스 수지에 관한 연구)

  • 이상효;이장우
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.459-468
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    • 2000
  • To improve the mechanical properties of fiber-reinforced polymer matrix composites, laminated composites plates were fabricated using different matrix resins and glass or aramid fibers. The effect of matrix resin system were evaluated by tensile, flexural strength measurements. In the case of surface treated aramid fiber and unsaturated polyester resin composite, maximum flexural properties were observed in the composite prepared from the glass fiber treated with 0.5 wt% silane coupling agents. Vinylester resin composites show the highest tensile properties and isophthalic polyester composites have the highest flexural properties among the unsaturated polyester resin composites studied. The relationship between overlap laminated composites plates and mechanical properties of polymer composites is also investigated in order to improve mechanical properties of glass fiber and unsaturated polyester resin composites.

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Preparation and Properties of Polymer PTC Composites for Process Safety (공정안전용 Polymer PTC 소재의 제조 및 특성)

  • 강영구;조명호
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.101-108
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    • 2003
  • Polymeric positive temperature coefficient(PTC) composites have been prepared by incorporating carbon black(CB) into high density polyethylene(HDPE), polyphenylene sulfide(PPS) and polybutylene terephthalate(PBT) matrices. A PTC effect was observed in the composite, caused by the large thermal expansion due to He consecutive melting of HDPE, PPS and PBT crystallites. This theory is based upon the premise that the PTC phenomenon is due to a critical separation distance between carbon particles in the polymer matrix at the higher temperature. The influence of PTC characteristics of the PPS/CB composite can be explained by DSC result. HDPE, one of prepared composition, exhibit the higher performance PTC behavior that decreaseing of negative temperature coefficient(NTC) effect and improved reproducibility by chemically crosslinking. Also, PBT/CB and PPS/CB composites exhibit the higher PTC peack temperature than HDPE/CB PTC composite, individually $200^{\circ}C$ and $230^{\circ}C$. These PTC composite put to good use in a number of safety application, such as self$.$controlled heater, over-current protectors, auto resettable switch, high temperature proctection sensor, etc.

Equivalent Circuit Analysis of Flexible Piezoceramic/polymer 0-3 Composites for Hydrophone Applications (수중청음기를 위한 Piezoceramic/Polymer 0-3 Composite의 등가회로 해석)

  • Choi, H.I.;Park, J.H.;SaGong, G.
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.341-344
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    • 1989
  • A Modified equivalent circuit by combining a series and parallel of polymer matrix for estimating the dielectric constant ${\bar{K}}_{33}$ values changing the volume percent of $PbTiO_3$, the dependences of frequency for the 713 and dissipation factor for 0 - 3 composites was derived. The difference of the dielectric constant and dissipation factor between the calculated and measured values became smaller at higher volume percent of $PbTiO_3$. There was, good agreement between the calculated and observed results for 70 volume percent of $PbTiO_3$ and 30 volume percent of Eccogel composite at 1(KHz), 25($^{\circ}C$). The optimized variable x was 0.94 in $PbTiO_3$ ceramics. $PbTiO_3$ powder and Eccogel polymer were used as piezoelectric fillers and matrix, respectively.

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Densification of 4D Carbon Fiber Performs with Mesophase Pitch as Matrix-Precursor

  • Joo, Hyeok-Jong;Lee, Jae-Won
    • Carbon letters
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    • v.6 no.3
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    • pp.173-180
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    • 2005
  • In this study, AR (aromatic resin) pitch was employed as the matrix-precursor for carbon/carbon composite because it exhibits much higher coke yield than coal tar pitch. As a result, a fabrication process of carbon/carbon composites can be shortened. It has been known that the pitches may cause swolling problem during the carbonization process. In order to restrain the swelling occurrence, a small quantity of carbon black was added to the AR pitch. Due to addition of carbon black the swelling was decreased largely and the perform can be infiltrated with the AR pitch. The densification efficiency of the performs was compared with various matrix-precursors. The coke yield of matrixprecursors, the morphology and the degree of graphitization of carbon matrix were analyzed.

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Mechanical behaviour of a syntactic foam/glass fibre composite sandwich: experimental results

  • Papa, Enrico;Corigliano, Alberto;Rizzi, Egidio
    • Structural Engineering and Mechanics
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    • v.12 no.2
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    • pp.169-188
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    • 2001
  • This note presents the main results of an experimental investigation into the mechanical behaviour of a composite sandwich conceived as a lightweight material for naval engineering applications. The sandwich structure is formed by a three-dimensional glass fibre/polymer matrix fabric with transverse piles interconnecting the skins; the core is filled with a polymer matrix/glass microspheres syntactic foam; additional Glass Fibre Reinforced Plastics extra-skins are laminated on the external facings of the filled fabric. The main features of the experimental tests on syntactic foam, skins and sandwich panels are presented and discussed, with focus on both in-plane and out-of-plane responses. This work is part of a broader research investigation aimed at a complete characterisation, both experimental and numerical, of the complex mechanical behaviour of this composite sandwich.

Relations Between Dispersion of CNTs and Electrical Conductivity in the Hydrophobic CNT/PVDF Composite Film (소수성 CNT/PVDF 복합막에서 CNT의 분산과 전도성의 관계)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.462-466
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    • 2015
  • In this paper, we investigated the relations between dispersion of CNTs (carbon nanotubes) and electrical conductivity in the CNT/PVDF (polyvinylidene fluoride) composite film. By adding hydrophobic CNTs as filler into the PVDF matrix, we fabricated hydrophobic and electrically conducting polymer coating film. Dispersion of CNTs in the CNT/PVDF composite film plays a significant role in terms of electrical conductivity and wetting property. Spray coating method was used to form the CNT/PVDF composite films by injecting the dispersed CNTs in the PVDF solution with different weight ratios from 0.7 wt% to 7 wt%. We investigated the electrical properties and contact angles of the CNT/PVDF composite films with the CNT concentration. Finally we discussed the conducting mechanism and feasibility of the CNT/PVDF composite film for the conducting polymer films.

Property improvement of natural fiber-reinforced green composites by water treatment

  • Cho, Dong-Hwan;Seo, Jeong-Min;Lee, Hyun-Seok;Cho, Chae-Wook;Han, Seong-Ok;Park, Won-Ho
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.299-314
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    • 2007
  • In the present study, natural fibers (jute, kenaf and henequen) reinforced thermoplastic (poly(lactic acid) and polypropylene) and thermosetting (unsaturated polyester) matrix composites were well fabricated by a compression molding technique using all chopped natural fibers of about 10 mm long, respectively. Prior to green composite fabrication, natural fiber bundles were surface-treated with tap water by static soaking and dynamic ultrasonication methods, respectively. The interfacial shear strength, flexural properties, and dynamic mechanical properties of each green composite system were investigated by means of single fiber microbonding test, 3-point flexural test, and dynamic mechanical analysis, respectively. The result indicated that the properties of the polymeric resins were significantly improved by incorporating the natural fibers into the resin matrix and also the properties of untreated green composites were further improved by the water treatment done to the natural fibers used. Also, the property improvement of natural fiber-reinforced green composites strongly depended on the treatment method. The interfacial and mechanical results agreed with each other.

Polymer matrices for carbon fiber-reinforced polymer composites

  • Jin, Fan-Long;Lee, Seul-Yi;Park, Soo-Jin
    • Carbon letters
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    • v.14 no.2
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    • pp.76-88
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    • 2013
  • Carbon fibers (CFs) have high service temperature, strength, and stiffness, and low weight. They are widely used as reinforcing materials in advanced polymer composites. The role of the polymer matrix in the composites is to provide bulk to the composite laminate and transfer load between the fibers. The interface between the CF and the resin matrix plays a critical role in controlling the overall properties of the composites. This paper aims to review the synthesis, properties, and applications of polymer matrices, such as thermosetting and thermoplastic resins.