• Clean Technology
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• v.17 no.1
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• pp.1-12
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• 2011

Scientists and engineers have altered the properties of materials such as metals, alloys, polymers, ceramics, and so on, to suit the ever changing needs of our society. Man-made engineering materials generally demonstrate excellent mechanical properties, which often tar exceed those of natural materials. However, all such engineering materials lack the ability of self-healing, i.e. the ability to remove or neutralize microcracks without intentional human interaction. The damage management paradigm observed in nature can be reproduced successfully in man-made engineering materials, provided the intrinsic character of the various types of engineering materials is taken into account. Various self-healing ptotocols that can be applied for the organic materials such as polymers, ionomers and composites can be developed by utilizing suitable chemical reactions and physical intermolecular interactions.

• Tribology and Lubricants
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• v.39 no.6
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• pp.262-267
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• 2023

Research to replace metal mechanical elements with polymer materials has recently accelerated. However, polymers exhibit less favorable mechanical properties than metal materials, and are often easily worn-out owing to frictional heat when their mechanical elements contact while in relative motion. Therefore, research on the polymer tribological properties is required to employ polymer materials in mechanical elements operating under harsh conditions. In this study, we examine the effect of mechanical part operating temperatures on the material friction and wear characteristics of polymer materials. We conduct ball-on-disk friction tests under dry conditions at various temperatures, using a metal ball with high hardness and a polymer as the counter surface. Each test is repeated at least three times to ensure the reliability of the test results. Before the friction test, we analyze the surface hardness and roughness of each polymer specimen; after the friction test, we use a three-dimensional confocal microscope to compare and analyze the polymer specimen wear characteristics. Based on this study, we systematically elucidate the polymer material tribological characteristics. This information should be useful for selecting and utilizing polymer materials at various temperatures.

• KCI Concrete Journal
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• v.13 no.2
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• pp.58-66
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• 2001

Recently, polymer-modified mortar has been studied for proposed use on industrial floors as top coat with thin thickness, typically 5~15mm. The purpose of this study is to evaluate basic properties of self-leveling materials using polymer dispersions as kinds of SBR, PAE, St/BA with thin coat (under 3mm). Superplasticizer and thickener have been included in the mixes to reduce bleeding and drying shrinkage as well as to facilitate the workability required. The self-leveling materials using four types of polymer dispersion are prepared with polymer-cement ratio which respectively range from 50% and 75%, and tested for basic characteristics such as unit weight, air content, flow, consistency change and adhesion in tension. From the test results, the self-leveling materials using PAE emulsion at curing age of 28days are almost equal to those of conventional floor using urethane and epoxy resin. The adhesion in tension of self-leveling mortars using SBR latex and PAE emulsion at curing age of 3days is over 17 kgf/cm$^2$(1.67MPa). Consistency change is strongly dependent on the type of polymer dispersion. It is concluded that the self-leveling materials using polymer dispersions can be used in the same manner as conventional floor using thermosetting resin in practical applications, in the selection of polymer dispersions.

• Macromolecular Research
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• v.11 no.3
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• pp.133-145
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• 2003

We have developed novel lanthanide-cored supramolecular systems with highly efficient light-harvesting dendritic arrays for integrated planar waveguide-typed amplifiers. Er$^{3+}$ ions were encapsulated by the supramolecular ligands, such as porphyrins and macrobicyclics. The supramolecular ligands have been designed and synthesized to provide enough coordination sites for the formation of stable Er(III)-chelated complexes. For getting a higher optical amplification gain, also, the energy levels of the supramolecular ligands were tailored to maintain the effective energy transfer process from supramolecular ligands to erbium(III) ions. Furthermore, to maximize the light-harvesting effect, new aryl ether-functionalized dendrons as photon antennas have been incorporated into lanthanide-cored supramolecular systems. In this paper, molecular design, synthesis and luminescent properties of novel lanthanide-cored integrated supramolecular systems with highly efficient light-harvesting dendritic arrays will be discussed.d.

• Elastomers and Composites
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• v.44 no.3
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• pp.196-208
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• 2009

Sophisticated polymeric materials with 'responsive' properties are beginning to reach the market. The use of reversible, noncovalent interactions is a recurring design principle for responsive materials. Recently developed hydrogen-bonding units allow this design principle to be taken to its extreme. Supramolecular polymers, where hydrogen bonds are the only force keeping the monomers together, form materials whose (mechanical) properties respond strongly to a change in temperature or solvent. In this review, we describe some examples of hydrogen-bonded supramolecular polymers that can be utilized for self-healing materials. Synthesis of a rubber-like material that can be recycled might not seem exciting. But one that can also repeatedly repair itself at room temperature, without adhesives, really stretches the imagination. Autonomic healing materials respond without external intervention to environmental stimuli in a nonlinear and productive fashion, and have great potential for advanced engineering systems.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1990.06a
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• pp.1-6
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• 1990

Metal-Polymer Research Institute of Bneloressian Academy of Sciences is taking an active part in research and developments in field of polymer materials and composites. Many of these materials are devoted to use as a construction materials for machine parts, protective and decorative coatings on metals, films preventing corrosion in packaging of electronic, machinery and other components. This list can be continued by mentioning polymer capsulation coating for fertilizers, polymer filters produced by extruding and transfer of melted fibers etc.

• Korean Journal of Materials Research
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• v.29 no.11
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• pp.664-669
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• 2019

In this paper, a water-based green polymer mud is synthesized by simple compounding method. Effects of different kinds of tackifiers, their molecular weight on the viscosity of polymer mud and the effects of different fluid loss additives on mud fluid loss are studied. The results show that when polystyrene and anionic polyacrylamide with molecular weight of 8 ~ 10 million are used as the main thickening ingredient, polymer mud with high viscosity and high stability can be obtained. When the prepared polymer mud is formulated as NPAM: PEO: Hydroxypropyl cellulose(HPC) : Water = 42:10:10:100000 (unit: kg), the viscosity can reach 20.6 s, the filtration loss in 7.5 min is 24 mL, and the sand content is only 0.1 %. Compared with traditional bentonite mud, the green environment-friendly polymer mud has the advantages of small amount of waste, low environmental pollution, and low pulping cost, and can meet the construction needs for most topography and geomorphology drilling engineering.

• Macromolecular Research
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• v.14 no.2
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• pp.235-239
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• 2006

• Macromolecular Research
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• v.17 no.9
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• pp.721-724
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• 2009

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1485-1490
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• 2014

We have designed and developed a new ladder type tetrafused ${\pi}$-conjugated building block such as dihydroindolo[3,2-b]indole (DINI) and investigated its role as an electron rich unit. The photovoltaic properties of a new semiconducting ${\pi}$-conjugated polymer, poly[[5,10-bisoctyl-5,10-dihydroindolo[3,2-b]indole-[5,6- bis(octyloxy)-4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole]], represented by PDINI-OBTC8 are described. The new polymer PDINI-OBTC8 was synthesized in donor-acceptor (D-A) fashion, where fused ${\pi}$-conjugated tetracyclic DINI, and 5,6-bis(octyloxy)-4,7-di(thiophen-2-yl) benzo[c][1,2,5]thiadiazole (OBTC8) were employed as electron rich (donor) and electron deficient (acceptor) moieties, respectively. The conventional bulk heterojunction (BHJ) device structure ITO/PEDOT:PSS/PDINI-OBTC8:PCB71M/LiF/Al was utilized to fabricate polymer solar cells (PSCs), which comprises the blend of PDINI-OBTC8 and [6,6]-phenyl-$C_{71}$-butyric acid methyl ester ($PC_{71}BM$) in BHJ network. A BHJ PSC that contain PDINI-OBTC8 delivered power conversion efficiency (PCE) value of 1.68% with 1 vol% of 1,8-diidooctane (DIO) under the illumination of A.M 1.5G 100 $mW/cm^2$.