• 제목/요약/키워드: Polymer material

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광중합 가능한 폴리머 표면에 in-situ 광배향법을 이용한 프리틸트각 제어 (Control of Pretilt Angle using a in-situ Photoalignment Method on Photo-Crosslinkable Polymer Surface)

  • 정은아;황정연;서대식;김재형;한은주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.350-353
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    • 2001
  • Aligning capabilities for nematic liquid crystal (NLC) using a in-situ photodimerization method on various photo-crosslinkable polyimide (PI) based polymer and blending photopolymer surfaces were stuided. High pretilt angle of the NLC can be measured by obliquely polarized UV exposure on a photo-crosslinkable polyirnide based polymer surface containing biphenyl (BP), decyl (de), and cholesteryl (chol) group, respectively, However, the low pretilt angle of the NLC was measured by obliquely polarized UV exposure on the blending photopolymer (PI and cinnamate materials) surfaces. Consequently, the pretilt angle of the NLC generated on the photo-crosslinkable polyimide based polymer surfaces using the in-situ photodimerization method was higher than that of the blending photopolymers.

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새로운 광중합 가능한 폴리이미드계 몰리머을 이용한 액정 배향 특성 (Liquid Crystal Aligning Capabilities on a New Photo-Crosslinkable Polyimide Based Polymer)

  • 황정연;서대식;이상렬;김재형;한은주
    • 한국전기전자재료학회논문지
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    • 제14권5호
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    • pp.430-434
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    • 2001
  • We synthesized a new photo-crosslinkable polymer (polyimide (PI)-chalcone-biphenyl (BP)) and liquid crystal (LC) aligning capabilities for nematic (N) LC with obliquely polarized UV exposure on a photo-crosslinkable polymer were studied. The high pretilt angle in NLC was obtained by polarized UV exposure on a PI-Chal-BP surface for 3 min. The high pretilt angle generated in NLC is attributed to the biphenyl moieties and the photo-dimerized chalclone group of a photopolymer. Also, good thermal stability of a PI-Chal-BP were obtained by thermogravimetric analysis (TGA) measurement until 450$^{\circ}C$. Finally, good voltage-transmittance curves and response time were observed by UV exposure on a PI-Chal-BP surface for 3min.

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EPDM 고분자 애자에 대한 표면방전 및 누설전류파형의 고조파분석 (Harmonics Analysis of Leakage Current Waveforms and Surface Discharge for EPDM Polymer Insulator)

  • 박재준;양태규
    • 한국전기전자재료학회논문지
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    • 제17권9호
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    • pp.1013-1021
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    • 2004
  • This paper presents the results of spectrum analysis of leakage current waveforms on contaminated polymer insulators under fog conditions. This is a basic study on development of a monitoring for aging degree and surface pollution state using distortion rate(%) of 3rd and 5th harmonics according fundamental frequency[60Hz] under environment conditions. Arcing on the surface was always associated with distortion in the leakage current ; hence the low frequency components of the leakage current can be used as a means to evaluate the surface degradation. The results indicate that the distortion rate by spectrum analysis is available for the monitoring of contamination condition of EPDM Polymer insulators.

저온 공정을 이용한 플라스틱 STN 셀의 전기 광학 특성 (Electro-Optical Characteristics of Plastic STN Cell using Low Temperature Process)

  • 김강우;황정연;김종환;서대식
    • 한국전기전자재료학회논문지
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    • 제17권10호
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    • pp.1095-1099
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    • 2004
  • We investigated the electro-optica](EO) performances of the super twisted nematic liquid crystal display(STN-LCD) on the polyimide(PI) surface using polymer film. The NLC(Nematic Liquid Crystal) pretilt angles generated are about 18$^{\circ}$by the rubbing alignment method on thin plastic substrates. However, the pretilt angle are at about 13$^{\circ}$ lower on the glass substrate than on thin plastic substrate. Monodomain alignment of the plastic STN-LCD can be observed. A stable voltage-transmittance(V-T) curve of the plastic STN-LCD was observed on the polyimide(PI) surfaces using polymer film. Also, a faster response time for the plastic STN-LCD on the polyimide(PI) surfaces using polymer film can be achieved.

광중합법을 이용한 네마틱액정의 배향 안정성 및 프리틸트각의 발생 (Pretilt Angel Generation and Alignment Stability for Nematic Liquid Crystal Using a Photodimerization Method)

  • 황정연;서대식;김재형;한은주
    • 한국전기전자재료학회논문지
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    • 제14권4호
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    • pp.336-340
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    • 2001
  • We have investigated the generation of pretilt angle and alignment stability for a nematic liquid crystal (NLC) with obliquely polarized UV exposure on the three kinds of photo-polymer. High pretilt angle of the NLC was obtained by polarized UV exposure on a PM4Ch surface for 1 min. But, the low pretilt angle of he NLC on a PVCi surface was observed. The pretilt angle generated is attributed ot the photosensitivity by the long side chaining of photo-polymer. Also, a good thermal stability of the three kinds of photo-polymer were obtained by thermogravimetric analysis (TGA) measurement until 300$^{\circ}C$. Finally, the good LC aligning capabilities using the photodimerization method were observed by annealing-treatment until 150$^{\circ}C$.

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리튬이온전지용 Urethane기 겔폴리머전해질에 관한 연구 (A Study on Urethane-Based Gel Polymer Electrolyte for Lithium ion Battery)

  • 김현수;김성일;최관영;문성인;김상필
    • 한국전기전자재료학회논문지
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    • 제15권12호
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    • pp.1033-1038
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    • 2002
  • In this study, urethane acrylate macromer was synthesized and it was used in a gel polymer electrolyte (GPE), and then its electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were Prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor consisting of urethane acrylate (UA), hexanediol dimethacrylate (HDDA) and benzoyl peroxide (BPO) had a low viscosity relatively ionic conductivity of the gel polymer electrolyte with UA at room temperature and -20$\^{C}$ was ca. 4.5 $\times$ 10$\^$-3/S$.$cm$\^$-1/ and 1.7 x 10$\^$-3/ S$.$cm$\^$-1/, respectively GPR was stable electrochemically up to potential of 4.i V vs. Li/Li$\^$+/. LiCoO$_2$/GPE/graphite cells showed good a high-rate and a low-temperature performance.

에폭시 복합재료의 내트래킹성에 미치는 상호침입망목의 효과 (The Effect of Interpenetrating Polymer Network upon Tracking Resistance of Epoxy Composite Materials)

  • 김탁용;이덕진;손인환;김명호;김경환;김재환
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.225-229
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    • 1996
  • In this study, in order to develop outdoor insulating materials, SIN(simultaneous interpenetrating polymer network) was introduced to Epoxy resin and the environment resistance was investigated. The single network structure specimen(E series) formed of Epoxy resin alone and simultaneous interpenetrating polymer network specimen (EM series) in which epoxy resin was taken as the first network and methyl methacrylate resin as the second network were manufactured. Ten kinds of specimens were manufacture by filler (SiO$_2$) content. SEM were utilized in order to confirm their network structure changes, and AC voltage dielectric strength was measured. Also, UV-test and tracking test were carried out investigate the environment resistance characteristic. Therefore the variations of network structure were happened as a result of SEM test, and it was confirmed that simultaneous interpenetrating polymer network specimens were more excellent than single network structure specimens.

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배전급 주상 변압기용 폴리머 부싱 설계 및 제조기술 (Design and Manufacture Technology of Polymer Bushing for Pole Mount Transformer)

  • 조한구;이운용;천종욱;박영두;강영길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 춘계학술대회 논문집
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    • pp.145-149
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    • 2005
  • Recently, polymer insulator and bushing that are used for high voltage application have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. The pole mount transformer installed in distribution system is acting direct role in supply of electric power and the electric power device should drive safely for long tenn. In this paper, the polymer bushing of pole transformer is designed adaptively to current assembly method, designed bushing is manufactured on basis of that result. The electric field of designed transformer is investigated by FEM program.

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Energy dissipation of steel-polymer composite beam-column connector

  • Wang, Yun-Che;Ko, Chih-Chin
    • Steel and Composite Structures
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    • 제18권5호
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    • pp.1161-1176
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    • 2015
  • The connection between a column and a beam is of particular importance to ensure the safety of civil engineering structures, such as high-rise buildings and bridges. While the connector must bear sufficient force for load transmission, increase of its ductility, toughness and damping may greatly enhance the overall safety of the structures. In this work, a composite beam-column connector is proposed and analyzed with the finite element method, including effects of elasticity, linear viscoelasticity, plasticity, as well as geometric nonlinearity. The composite connector consists of three parts: (1) soft steel; (2) polymer; and (3) conventional steel to be connected to beam and column. It is found that even in the linear range, the energy dissipation capacity of the composite connector is largely enhanced by the polymer material. Since the soft steel exhibits low yield stress and high ductility, hence under large deformation the soft steel has the plastic deformation to give rise to unique energy dissipation. With suitable geometric design, the connector may be tuned to exhibit different strengths and energy dissipation capabilities for real-world applications.

The influence of polymer compounds on the HTS films

  • Soh, Deaw-Ha;Korobova, N.;Park, Jung-Cheul;Jeon, Yong-Woo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.112-115
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    • 2000
  • In this work the results of the systematic investigations on the effect of organic addition by using polymer compound as starting materials on the superconducting properties of YBCO electrophoretic deposited films on silver substrate are presented. The characteristics of the films were examined by X-ray diffraction and SEM observation. Our results show that the adhesion and microstructure of these films are sensitive to the nature of polymer compounds and sintering conditions (electrophoretic deposition, drying and heat-treatment procedures). To develop optimum microstructures for samples processed in this manner it is necessary to have an understanding of how these processes affect the microstructure and hence the properties of ceramic superconductors.

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