• Title/Summary/Keyword: Polymer material

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ESPI를 이용한 자외선조사량에 따른 폴리머애자의 탄성계수 변화 연구 (Elasticity Modulus Change Research of Polymer Ultraviolet Dosage by using ESPI)

  • 김경석;김동수;장호섭;박찬주;장완식;정현철
    • 한국생산제조학회지
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    • 제19권4호
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    • pp.485-490
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    • 2010
  • Recently, environment problems have effects on the electronic equipments. Security problems are presented. For security reasons, it is necessary to study electronic equipments. In this paper, we handle the Elasticity modulus on the polymer insulator by UV irradiation. The types of material are used in this experiment, is the EPDM (Ethylene Propylene Diene Monomer). For increasing the reliability, real material specimens are used. For this study, we used ESPI (Electronic speckle pattern interferometry), UTM (Universal thesting machine) device, Accelerated weathering tester. Through this measurement, we evaluated how much UV irradiation has effect on polymer insulator and how long does it take to change the polymer insulator. Also this paper will give a help in electronic industry and the method of measuring the insulator elasticity modulus of polymer could be utilized in life estimation and replacement time of the products of electronic equipment that is used in real industrial fields.

리튬 폴리머전지용 PMMA/PVDF계 고분자 전해질의 이온 전도 특성 (Ion Conduction Properties of PMMA/PVDF based Polymer Electrolyte for Lithium Polymer Battery)

  • 이재안;김종욱;구할본;이헌수;손명모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.347-350
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PMMA/PVDF electrolytes as a function of a mixed ratio were reported for PMMA/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PMMA/PVDF, plasticizer and Li salt. The ion conductivity of PMMA/PVDF electrolytes was 10$\^$-3/S/cm, which may be applicable to a constituent of lithium secondary battery. 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and AC impedance were used for the determination of transference numbers in PMMA/PVDF electrolyte film. The transference number of 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte is 0.55.

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Study on gamma radiation attenuation and non-ionizing shielding effectiveness of niobium-reinforced novel polymer composite

  • Akman, Ferdi.;Ogul, H.;Ozkan, I.;Kacal, M.R.;Agar, O.;Polat, H.;Dilsiz, K.
    • Nuclear Engineering and Technology
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    • 제54권1호
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    • pp.283-292
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    • 2022
  • Advanced radiation applications have been widely used and extended to many fields. As a result of this fact, choosing an appropriate shielding material based on the radiation application has become vital. In this regard, the integration of elements into polymer composites has been investigated and contributed to the quantity and quality of radiation shielding materials. This study reports photon attenuation parameters and electromagnetic shielding effectiveness of a novel polymer composite prepared with a matrix reinforced with three different proportions (5, 10, and 15 wt%) of niobium content. Addition of Nb dopant improves both photon attenuation and electromagnetic shielding effectiveness for the investigated composites. Therefore, Nb(15%) polymer composite with highest concentration has been found to be the best absorber for ionizing and non-ionizing radiations. Consequently, the performed analyzes provide evidences that the prepared Nb-reinforced polymer composite could be effectively used as photon radiation attenuator and electromagnetic shielding material.

Electroactive Polymer Composites as a Tactile Sensor for Biomedical Applications

  • Kim GeunHyung
    • Macromolecular Research
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    • 제12권6호
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    • pp.564-572
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    • 2004
  • Modem applications could benefit from multifunctional materials having anisotropic optical, electrical, thermal, or mechanical properties, especially when coupled with locally controlled distribution of the directional response. Such materials are difficult to engineer by conventional methods, but the electric field-aided technology presented herein is able to locally tailor electroactive composites. Applying an electric field to a polymer in its liquid state allows the orientation of chain- or fiber-like inclusions or phases from what was originally an isotropic material. Such composites can be formed from liquid solutions, melts, or mixtures of pre-polymers and cross-linking agents. Upon curing, a 'created composite' results; it consists of these 'pseudofibers' embedded in a matrix. One can also create oriented composites from embedded spheres, flakes, or fiber-like shapes in a liquid plastic. Orientation of the externally applied electric field defines the orientation of the field-aided self-assembled composites. The strength and duration of exposure of the electric field control the degree of anisotropy created. Results of electromechanical testing of these modified materials, which are relevant to sensing and actuation applications, are presented. The materials' micro/nanostructures were analyzed using microscopy and X-ray diffraction techniques.

Dye-sensitized solar cells using size dependent SBM binder

  • 박경희;김은미;조홍관;왕교;홍창국;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.116-116
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    • 2009
  • $TiO_2$ pastes was synthesized to obtained of high efficiency dye-sensitized solar cells using size dependent co-polymer. SBM co-polymer binder is consist of styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The photoanodes were characterized by ATR-Fourier Transform spectrometer, X-ray diffraction (XRD) and morphology was investigated by field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density, AC impedance and monochromatic incident photon-to-current conversion efficiency (IPCE). DSSC based on the 100nm size co-polymer binder was obtained conversion efficiency of 8.1% under irradiation of AM 1.5(100 $mWcm^2$).

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폴리머 재료를 이용한 새로운 비휘발성 단위 메모리 셀과 주변회로 제안 (New nonvolatile unit memory cell and proposal peripheral circuit using the polymer material)

  • 김정하;이상선
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2005년도 추계종합학술대회
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    • pp.825-828
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    • 2005
  • In this paper, we propose a new nonvolatile unit memory cell and proposal peripheral circuit using the polymer material. Memory that relies on bistable behavior- having tow states associated with different resistances at the same applied voltage - has attracted much interest because of its nonvolatile properties. Such memory may also have other merits, including simplicity of structure and manufacturing, and the small size of memory cells. We have plotted the load line graphs for the use of a polymer memory character, hence we have designed in the band-gap reference shape of a write/erase drive, and then designed in the 2-stage differential amplifier shape of a sense amplifier in the consideration of a low current characteristic of a polymer memory cell. The simulation result shows that is has high gain about 80dB by sensing the very small current.

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Formation and Characterization of Chemically Combined [TEACOOH]-Montmorillonite/Polycaprolactone Nanocomposites

  • Cho, Sung-Jun
    • 한국세라믹학회지
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    • 제44권2호
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    • pp.71-78
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    • 2007
  • A [TEACOOH]-Montmorillonite intercalations complex obtained from Na-Montmorillonite and 10-Carboxy-n-triethylammonium bromide was used to attempt the polymerization of ${\varepsilon}$-caprolactone between the layer spaces of the intercalations complex to achieve Montmorillonite-Polycaprolactone nanocomposites in which the inorganic material (montmorillonite) is chemically combined with the organic polymer (polycaprolactone). The results of X-ray-, IR-, and TEM-analyses for samples obtained after polymerization showed that a polycondensation reaction was successfully produced. For a more precise investigation of the polymeric reaction products the polymerized products were separated from the silicate layers and analyzed with an IR-spectrometer. A comparison of the results of the IR-analyses of the separated polymer with that of the polymer synthesized by the reaction of ${\varepsilon}$-caprolactone with only the organic cation and without montmorillonite showed that the two obtained polymers are the same compound.

유전율이 양인 액정을 이용한 FFS모드의 스위칭시 Optical Bounce 발생 원인에 관한 연구 (Origin of Optical Bounce during switching in the FFS Mode using a LC with Positive Dielectric Anisotropy)

  • 하경수;정준호;김민수;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.63-64
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    • 2009
  • Optical bounce during switching in the fringe field switching (FFS) mode using a liquid crystal (LC) with positive dielectric anisotropy has been observed. According to the analysis, it occurs at two positions which are center and edge of the pixel electrode, which decreases decaying response time. The former is major and mainly associated with increase in twist angle instantaneously during switching off resulted from decrease in tilt angle near by LC molecules at center. This paper discusses the origin of such optical bounces.

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거리측정용 PZT-고분자 3-3형 복합압전체 트랜스듀서의 펄스에코 응답특성 (Pulse-echo Response of Ultrasonic Transducer Fabricated by PZT-Polymer 3-3 Type Composite Resonator for Distance Measurement Applications)

  • 주용관;박정학;최헌일;사공건
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.205-208
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    • 1995
  • PZT powders were prepared by the molten salt synthesis method. The porous PZT specimens were prepared from a mixture of PZT and Polyvinylalcohol(PVA) powders by BURPS(Burnout Plastic Sphere) technique. The pulse-echo response of PZT-polymer 3-3 type composite transducer with various PVA wt.% were studied, The fall time of pulse-echo response of PZT-polymer 3-3 type composite transducer was shorten to that of solid PZT-maded transducer. Therefore, a good transmitting and receiving properties could be obtained. The distance between transducer and reflector was in good agreement both solid PZT and PZT-polymer 3-3 type composite fabricated transducer.

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유기/무기 복합 절연재료의 전기적 특성 (Electrical Properties of Organic/lnorganic Hybrid Composites for Insulation materials)

  • 깅상철;김현석;옥정빈;안명진;박도현;이건주
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.78-83
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    • 2001
  • In this work, the surface of inorganic fillers were modified with some functional groups such as stearic acid, aliphatic long chain, vinylsilane and aminosilane to control the interaction between inorganic fillers and polymer matrix. Ethylene-vinyl acetate copolymers (EVA) with various amount of vinyl-acetate content and copolyether-ester elastomer were used as polymer matrix. The addition of inorganic fillers increases flame retardancy, but results in steep drop of electrical and mechanical properties, which may be caused by the defect in the interface between organic/inorganic hybrid composites. The hybrid composites are found to show better mechanical properties and higher volume resistivities as inorganic fillers are well dispersed and have good adhesion with polymer matrix. Also, the most effective type of functional group coated on fillers depends on the chemical structure of polymer.

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