• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.271-271
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• 2006

The present article describes a novel method of preparing the sulfonated polysulfone-based PEMs for DMFC, which are excellent in film quality, proton conductivity, methanol impermeability and mechanical properties. No depression in film quality or difficulty in film preparation is observed, even though sulfonated group of the PEMs are kept as high as 70 mol %. Allyl-terminated cooligo-PESs containing the organic sulfonate groups were solvent-cast into films and then thermally treated for cross-linking. Cross-linked sulfonated polysulfone-based PEMs gave unprecedented reduction of methanol cross-over and high ionic conductivity through in-situ thermal polymerization and cross-linking of telechelic sulfonated sulfone oligomers during a membrane preparation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.2
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• pp.133-138
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• 2001

We studied the optical properties of poly(3-hexylthiophene) for applying to the emitting material of organic electro luminescent device. The infrared spectrum and NMR of synthesized polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. We confirmed that poly(3-hexylthiophene) contains the HT(head-to-tail)-HT(head-to-Tail) linkage larger than 65% based on NMR analysis. FTIR and raman spectroscopy show that poly(3-hexylthiophene) has two main vibration levels which have an energy about 0.18eV and 0.36eV. Electronic absorption spectra shifted to the shorter wavelength with increasing temperature, which is related to a conformational transition of the polymer. Photoluminescence spectrum generated at low temperature(10K) is separated at 669nm, 733nm and 812nm that it's because of phonon energy generated from the lattice vibration.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.581-584
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• 2001

For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.145-146
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• 2005

This study performs a simulation for an accumulation mechanism of contaminants, which were produced in an industrial belt of inland, on the surface of insulators. From the simulation, silicon insulators presented higher accumulation than that of EPDM(Ethylene Propylene Diene Terpolymer : EPDM) insulators on the same distance in the case of the Virgin polymer insulator, and this result presented the same result in the insulator applied in actual fields. In the case of the accumulation test for the Virgin insulator and insulators used in actual fields, it is evident that the Virgin insulator presented more accumulation than that of the insulator used in actual fields. The results can be caused by the generation of LMW (Low Molecular Weight) on the external material of polymer insulators, and the level of the accumulation can be changed according to the degree of the continuous generation of LMW.

• Textile Coloration and Finishing
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• v.26 no.4
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• pp.277-282
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• 2014

Two tert-butyl substituted phthalocyanines(Pcs), in metal-free and metallated forms, were synthesized and the fluorescence responses toward various nitro derivatives, including picric acid(PA), 2,4-dinitrotoluene(DNT), 1,4-dinitrobenzene(DNB), 4-nitrotoluene(NT), nitrobenzene(NB), 1,4-benzoquinone(BQ), and nitromethane(NM) were investigated. Among the various nitro derivatives, current Pc derivatives exhibited efficient and exclusive fluorescence quenching in the presence of picric acid, which was readily observed by a naked eye. Quenching efficiency was estimated by the Stern-Volmer relationship, in which quenching constant, KSV, was calculated to be in the range of $10^4M^{-1}$. It was also found out that the aggregational behaviors of these Pcs are heavily dependent on the nature of solvent systems, subsequently affecting the quenching efficiency.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.8
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• pp.758-763
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• 2006

We has been studied the thin film encapsulation effect for organic light-emitting diodes (OLED). To evaluate the passivation properties of the passivation layer materials, we have carried out the fabrication of green light emitting diodes with ultra violet(UV) light absorbing polymer resin, $SiO_2,\;and\;SiN_x$, respectively. From the measurement results of shrinkage properties according to the exposure time to the atmosphere, we found that $SiN_x$ thin film is the best material for passivation layer. We have investigated the emission efficiency and life time of OLED device using the package structure of $OLED/SiN_x/polymer$ resin/Al/polymer resin. The emission efficiency of this OLED device was 13 lm/W and life time was about 2,000 hours, which reach 95 % of the performance for the OLED encapsulated with metal.

• 한국정보디스플레이학회:학술대회논문집
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• 2009.10a
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• pp.188-191
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• 2009

A high efficiency deep blue phosphorescent organic light-emitting diode (PHOLED) was developed using a new wide triplet bandgap host material (PPO1) with a phenylcarbazole and a phosphine oxide unit. The wide triplet bandgap host material was synthesized by a phosphornation reaction of 2-bromo-Nphenylcarbazole with chlorodiphenylphosphine. A deep blue emitting phosphorescent dopant, tris((3,5-difluoro-4-cyanophenyl)pyridine)iridium (FCNIr), was doped into the PPO1 host and a high quantum efficiency of 17.1 % and a current efficiency of 19.5 cd/A with a color coordinate of (0.14,0.15) were achieved in the blue PHOLED. The quantum efficiency of the deep blue PHOLED was better than any other quantum efficiency value reported up to now.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.125-128
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• 1998

The electro-optical properties of PDLCs ( Polymer Dispersed Liquid Crystals ) that have been interested for applications to projection display devices lately are significantly improved. For this improvement, we optimized not only the material parameters of liquid crystal and polymer but also the process conditions. Using TL series liquid crystals and polymer PN393 provided from Merck, we obtained the optimized process conditions such as cell gap, LC concentration, curing temperature and curing time. Under these conditions, we have achieved PDLC cells of threshold voltage 2.6V. contrast ratio 260 and negligible hysteresis.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.40 no.12
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• pp.1242-1251
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• 1991

This paper is to investigate the tree growth phenomena and the characteristics of $\varepsilon$' and tan$\delta$ for the effect of ultrasonic wave on polymer insulation material. The conclusions are as follows. 1) As the pressure amplitude of ultrasonic wave is larger and its irradiated time is longer, tree inception voltage and its breakdown voltage in specimen are smaller, and tree growing is faster. 2) As the irradiated quantity of ultrasonic wave is more increased, the value of tan$\delta$ is larger, but the value of $\varepsilon$' is almost constant. 3) The effect by the pressure amplitude of ultrasonic wave is greater than that by its irradiated time on the insulation characteristics of polymer material.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.63-66
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• 1999

The effects of UV and ozone on the weathershed materials for 5 polymer insulators were investigated. This study was carried by material characterizations such as surface microstructure, thermal property, chemical structure and contact angle. The aged specimens are compared with new ones. In case of UV, the chalking of fillers and cracking of surface were increased with the increase of UV radiation time. In case of ozone, aged specimens are not different from new ones. From this study, It can be concluded that UV has more effect on the surface properties of weathershed materials than ozone.