• Title/Summary/Keyword: Polymer binder

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Fabrication of $YBa_2Cu_3O_{7-{\delta}}$ Superconducting Coils with Polymer Binder (유기물 바인더를 사용한 $YBa_2Cu_3O_{7-{\delta}}$ 초전도 Coil의 제조)

  • 정해원;박승만;김재묵;김성수
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.355-360
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    • 1990
  • One of the possible ways to make a flexible wire of high-Tc superconductiong ceramics is the extrusion of a mixture slurry of superconducting powder with an appropriate polymer binder. The fabrication procedure for $YBa_2Cu_3O_{7-{\delta}}$ superconducting coils with this plastic mass is described. The major factors limiting the formation of extruded wire are the binder content, powder size, and entrapped gas in the mixture slurries. The optimum content of binder for both good flexbility and strength of wire was estimated to be 30wt%. The finer the powder size is, the more homogeneous structure the extruded wire has. The vacuum degassing before extrusion was necessary to remove the entrapped gas in as-extruded wire. The formability of wire depends greatly on the wire radius and binder content. After burning out the binder and the successive sintering, the contacts between the superconducting grains could be made. The resistivity vs. temperature behavior measured in the final wire showed the transition temperature of 90K with narrow transition width. However, the critical current densities of these wires are much lower in comparison to those of conventional bulk specimens.

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Physical Properties of Polymer Mortar Recycling Waste Concrete Powder as a Filler (폐콘크리트 미분말을 충전재로 재활용한 폴리머 모르타르의 물성)

  • Hwang, Eui-Hwan;Choi, Jae-Jin;Hwang, Taek-Sung
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.317-322
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    • 2005
  • Nowadays, recycling of aggregates from the waste concrete is in big demand due to the protection of environment and the shortage of aggregates that are needed for ever expanding construction projects. This study was undertaken to examine the feasibility of recycling waste concrete powder produced in the crushing process of demolished concrete as a filler material for polymer mortar. In this study, polymer mortar specimens were prepared by varying the mix proportion of polymer binder (ranging 9~15 wt%), waste concrete powder (ranging 0~20 wt%) substituted for silica powder, 0.1~0.3 mm fine aggregate (ranging 21~24 wt%) and 0.7~1.2 mm fine aggregate (ranging 44~47 wt%). For the prepared polymer mortar specimens, various physical properties such as strength, water absorption, heat water resistance, acid resistance, pore distribution and SEM observation were investigated in this work. As a result, physical properties of polymer mortar were observed to have remarkably improved with an increase of polymer binder, but greatly deteriorated with an increase of substitution quantity of waste concrete powder.

Tensile Properties and Adhesion of Hybrid-Type Anti-Corrosion Polymer Cement Slurry (하이브리드형 방식 폴리머 시멘트 슬러리의 인장특성 및 접착성)

  • Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.20 no.5
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    • pp.635-642
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    • 2008
  • In recent years, epoxy-coated reinforcing bars have been widely used in order to prevent the corrosion of ordinary reinforcing bar. However, they have a bad balance between performance and cost. Especially, they have a brittleness properties, low bond strength to cement concrete and no good bend-ability in the field. The purpose of this study is to evaluate the tensile properties and adhesion of hybrid-type anti-corrosion polymer cement slurry (PCS). PCSs are prepared with four types polymer dispersions using fly ash and silica fume, and tested for proper coating thickness, tensile properties, adhesion to steel plate and bend-ability. From the test results, the viscosity of PCS is effected by polymer dispersion types, and is a little decreased by using fly ash. The coating thickness of PCS has a proper thickness at polymer-binder ratio of 100%. It is apparent that the coating thickness has various values according to viscosity of PCS, water-binder ratio and polymer-binder rato. PCS has a good various anticorrosion properties and physical properties such as tensile strength, adhesion and bend-ability. It is also recommended that proper coating thickness to reinforcing bar is in the ranges of 150 to $250{\mu}m$ for bond strength, adhesion and bend-ability. It is also expected that the coated reinforcing bar using PCS is widely used instead of epoxy coated reinforcing bar in the industrial field.

Investigation of Physical Properties and Self Healing of Hardener-Free Epoxy-Modified Mortars with GGBFS (고로슬래그미분말을 혼입한 경화제 무첨가 에폭시수지 모르타르의 물리적 성질 및 자기치유 검토)

  • Jo, Young-Kug;Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.80-87
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    • 2020
  • The purpose of this study is to investigate the physical properties and self-healing effects of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS). The EMMs with GGBFS were prepared with various polymer-binder ratios and GGBFS contents, and tested for strengths, adhesion in tension, water permeation and self-healing effects. The conclusions obtained from the test results are summarized as follows. The compressive strength of the EMMs with GGBFS is reduced with increasing polymer-binder ratios because of reduction of the degree of hardening in the EMMs, and is somewhat inferior to that of unmodified mortars. In the flexural and tensile strengths, the flexural strength of the EMMs is almost constant with increasing polymer-binder ratios. However, the tensile strength of the EMMs is gradually increased with increasing polymer-binder ratios. Regardless of the GGBFS contents, the adhesion in tension of the EMMs increases sharply with increasing polymer-binder ratios. The water permeation of the EMMs is remarkably reduced with increasing polymer-binder ratios and GGBFS contents. The self-healing effect of the hardener-free EMMs with GGBFS is improved with increasing water immersion period at a GGBFS content of 20%.

Properties of Epoxy-Modified Mortars with Alkali Activators and Ground Granulated Blast Furnace Slag (알칼리자극제 및 고로슬래그미분말을 병용한 에폭시수지 혼입 폴리머 시멘트 모르타르의 성질)

  • Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.1
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    • pp.85-92
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    • 2021
  • The purpose of this study is to investigate the properties of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS) and alkali activators. The hardener-free EMMs with a GGBFS content of 20% using 4 types of alkali activators were prepared with various polymer-binder ratios, and tested for strengths, water absorption, carbonation depth, chloride ion and H2SO4 penetration depth. The conclusions obtained from the test results are summarized as follows: The compressive strength of the EMMs with a GGBFS content of 20% attains a maximum at a polymer-binder ratio of 10%. The flexural strength of the hardener-free EMMs using Ca(OH)2 as a alkali activator is improved with increasing polymer-binder ratios. However, the flexural strength of the EMMs using NaCO3, Na2SO4 and Li2CO3 is gradually decreased with increasing polymer-binder ratios. Regardless of the type of alkali activator, the water absorption, chloride ion penetration and carbonation depth are remarkably decreased with increasing polymer-binder ratios due to the epoxy film formed in the EMMs. The H2SO4 penetration depth of the hardener-free EMMs with a GGBFS content of 20% is gradually increased with increasing polymer-binder ratio. In this study, the properties of hardener-free EMMs using Ca(OH)2 as a alkali activator are more excellent than those of other alkali activators.

Characterization of Segmented Block Copolyurethane Network Based on Glycidyl Azide Polymer and Polycaprolactone

  • Min, Byoung-Sun;Ko, Seung-Won
    • Macromolecular Research
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    • v.15 no.3
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    • pp.225-233
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    • 2007
  • To improve the poor mechanical and low-temperature properties of glycidyl azide polymer (GAP)-based propellants, the addition of binders was investigated using GAP and flexible polymer backbone-structural polycaprolactone (PCP) at various weight(wt) ratios, and varying the ratio of Desmodur N-100 pluriisocyanate (N-100) to isophorone diisocyanate (IPDI). Using Gee's theory, the solubility parameter of the PCP network was determined, in order to elucidate the physical and chemical interaction between GAP and PCP. The structure of the binder networks was characterized by measuring the cross-link densities and molecular weights between cross-links ($M_c$) obtained by a swelling experiment using Flory-Rhener theory. The thermal and mechanical properties of the segmented block copolyurethane (GAP-b-PCP) binders prepared by the incorporation of PCP into the binder recipes were investigated, along with the effect of the different curatives ratios.

Controlled Release of Nifedipine in Multi-layered Granule System (다중층 과립 시스템에서 니페디핀의 방출 제어)

  • Lee, Soo-Young;Youn, Ju-Yong;Kim, Byung-Soo;Kim, Moon-Suk;Lee, Bong;Khang, Gil-Son;Lee, Hai-Bang
    • Journal of Pharmaceutical Investigation
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    • v.37 no.4
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    • pp.229-235
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    • 2007
  • Multi-layered granules were prepared by a fluidized-bed coater and uniformed granules were obtained with a size range between $950{\sim}1000{\mu}m$ in diameter. The granule system was composed of three layers, i.e. seed layer with sugar sphere bead and a water-swellable polymer, middle layer with a drug, solubilizer and polymer, and the top layer of porous membrane with a polymeric binder. The aim of this work is to find out the dependence of a drug dissolution rate on the amount of a water-soluble binder and a solubilizer in the granule system. The results showed that the higher amount of hydrophilic binder in the porous membrane, gave the bigger pore size and porosity and made faster dissolution rate and also the higher amount of solubilizer in drug layer enhanced the dissolution rate of drug.

An Experimental Study on the Physical Properties with Changes to Si/Al Mol Ratio of Inorganic Polymer Mortar Binder (무기폴리머계 모르타르의 결합재 Si/Al 몰비 변화에 따른 물리적 특성)

  • Choi, Hae-Young;Park, Dong-Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.749-752
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    • 2008
  • This experimental study compared polymer cement mortar with inorganic polymer binder mortar for physical properties by Si/Al mol ratio change of inorganic polymer binder. As the result of this experiment, We found that when Si/Al mol ratio goes up flexural strength and compressive strength increases but workability becomes worse. And according to the keeping them for 28 days we found that physcal property becomes worse when Si/Al mol ratio is larger than 2.61. When Si/Al mol ratio of inorganic polymer binder is from 2.43 to 2.61 compressive strength increases than over 32% after keeping for 7 days and over12 % for 28 days

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Photopolymer Composed of a Photosensitive Polymer Binder Bearing a Chalcone Moiety in the Repeating Unit

  • Cho, Min-Ju;Yoon, Hyuk;Feng, Dejun;Yoon, Han-na;Choi, Dong-Hoon
    • Journal of Information Display
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    • v.7 no.2
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    • pp.6-11
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    • 2006
  • New photopolymers were designed and prepared using the photosensitive polymer binders. Holographic gratings were successfully fabricated in these photopolymer samples by a conventional optical interference method. We also investigated the effect of photocrosslink in the polymer binder on the diffraction behavior of a new photopolymer. The dynamic behavior of the grating formation was monitored by changing exposure intensity in terms of the diffraction efficiency. Particularly, we focused our efforts in observing the variation of diffraction efficiency during a post UV curing process. The surface topographical change of photopolymer layer before and after Vis/UV light exposure was observed by atomic force microscope (AFM). We inscribed the gratings of the glass diffuser on the surface of the photopolymer and investigated their diffusing properties. The diffusers with photopolymer with the main chain polymer binder showed relatively good viewing angle of around ${\pm}30{\circ}$. Two kinds of photopolymer showed similar uniformity of around 47-54%.