• Macromolecular Research
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• 제15권7호
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• pp.682-687
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• 2007

The equation of state developed herein is predicated on a hard-sphere reference with perturbations introduced via a potential function to account for electrostatic forces and for attraction between protein particles. During this process, the generalized Lennard-Jones (GLJ) pair potential function is employed. The GLJ pair potential function is employed to represent the protein-protein interaction in two-protein systems. Via the use of the relation between the equation of state and the chemical potential, the phase behavior in the aqueous two-protein system can be estimated. The partition coefficients can be obtained via these processes. The calculated values of the coefficients agree fairly well with the experimental data in the given pH and ionic strength range, with no additional adjustable model parameters.

• Macromolecular Research
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• 제16권5호
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• pp.418-423
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• 2008

Poly[(R)-3-hydroxy butyrate] (PHB) and methoxy poly(ethylene glycol) (mPEG) were conjugated by the transesterification reaction with tin(II)-ethylhexanoate (Sn(Oct)-II) as a catalyst. Hydrophobic PHB and hydrophilic mPEG formed an amphiphilic block copolymer which was formed with the self-assembled polymeric micelle in aqueous solution. In this study, we tried to determine the optimum ratio of hydrophobic/hydrophilic segments for controlled drug delivery. The particle size and shape of the polymeric micelle were measured by atomic force microscopy (AFM) and transmission electron microscopy (TEM). Their size were 61-102 nm with various block ratios. Griseofulvin was loaded in the polymeric micelle as a hydrophobic model drug. The loading efficiency and release profile were measured by high performance liquid chromatography (HPLC). The model drug in our system was constantly released for 48 h.

• Structural Engineering and Mechanics
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• 제36권4호
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• pp.447-461
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• 2010

Fiber reinforced polymer (FRP) bars have been widely used as reinforcement for concrete structures. However, under elevated temperatures, the difference between the transverse coefficients of thermal expansion of FRP rebars and concrete may cause the splitting cracks of the concrete cover. As a result, the bonding of FRP-reinforced concrete may not sustain its function to transfer load between the FRP rebar and the surrounding concrete. The current study investigates the cracking resistance of FRP reinforced concrete against the thermal expansion based on a mechanical model that accounts for the tensile softening behavior of concrete. To evaluate the efficacy of the proposed model, the critical temperature increments at which the splitting failure of the concrete cover occurs and the internal crack radii estimated are compared with the results obtained from the previous studies. Simplified equations for estimating the critical temperature increments and the minimum concrete cover required to prevent concrete splitting failure for a designated temperature increment are also derived for design purpose.

• Steel and Composite Structures
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• 제46권1호
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• pp.115-132
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• 2023

The present study experimentally and analytically investigates the effect of tensile reinforcement ratio and arrangement on the behavior of FRP strengthened reinforced concrete (RC) beams. The experimental part of the program was comprised of 8 RC beams that were tested under four-point bending. Results have shown that by keeping the total cross-section area of tensile reinforcing bars constant, in specimens with a low reinforcement ratio, increasing the number and decreasing the diameter of bars in the section lead to 21% and 29% increase in the load-carrying capacity of specimens made with normal and high compressive strength, respectively. In specimens with high reinforcement ratio, a different behavior was observed. Furthermore, the accuracy of the existing code provisions and analytical models in predicting the load-carrying capacity of the FRP strengthened beams failed by premature debonding mode were evaluated. Herein, a model is proposed which considers the tensile reinforcement ratio (as opposed to code provisions) to achieve more accurate results for calculating the load carrying capacity of FRP strengthened RC beams.

• Earthquakes and Structures
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• 제17권4호
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• pp.337-354
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• 2019

This paper presents the results of experimental and numerical studies conducted to investigate the behavior of exterior reinforced concrete beam column joints (BCJ) strengthened by using carbon fiber reinforced polymer (CFRP) sheets. Twelve reinforced concrete beam-column joints (BCJ) were tested in an experimental program by simulating the joints in seismically deficient old buildings. One group of BCJs was designed to fail in flexure at the BCJ interface, and the second group was designed to ensure joint shear failure. One specimen in each set was -retrofitted with CFRP sheet wrapped diagonally around the joint. The specimens were subjected to both monotonic and cyclic loading up to failure. 3D finite element simulation of the BCJs tested in the experimental program was carried out using the software ABAQUS, adopting the damage plasticity model (CDP) for concrete. The experimental results showed that retrofitting of the shear deficient, BCJs by CFRP sheets enhanced the strength and ductility and the failure mode changed from shear failure in the joints to the desired flexural failure in the beam segment. The FE simulation of BCJs showed a good agreement with the experimental results, which indicated that the CDP model could be used to model the problems of the monotonic and cyclic loading of beam-column reinforced concrete joints.

• 청정기술
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• 제5권2호
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• pp.69-78
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• 1999

수용성 에멀젼형 절삭유의 한외여과 및 정밀여과 특성을 실험적으로 연구하였다. 한외여과막의 경우 오일/물 에멀젼의 투과 거동은 film model을 잘 따랐으나 정밀여과막인 ASYPOR막의 경우에는 이러한 거동을 벗어났다. 본 연구에서 사용된 모든 분리막의 경우 운전압력이 투과유속에는 큰 효과를 나타내지 않았다. 저압에서는 투과 초기 및 후기에서의 투과유속 감소율이 적은 반면 고압에서는 초기 투과유속은 매우 컸으나 투과유속의 감소율이 커서 후기에는 모두 비슷한 투과유속을 보여 주었다. 소수성이 큰 polycarbonate 정밀여과막의 경우 일반적인 경우와는 달리 운전시간이 증가함에 따라 투과유속이 증가하는 경향을 나타내었다. 교반하지 않은 cell에서의 임계투과압력은 150 ppm의 에멀젼 농도에서 약 $2.2kg_f/cm^2$이었으나 500 ppm의 농도에서는 $3.8kg_f/cm^2$ 압력에서 나타났다.

• Tribology and Lubricants
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• 제22권5호
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• pp.243-251
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• 2006

Molecular dynamics simulations of nanoimprint lithography NIL) are performed in order to investigate effects of process parameters, such as stamp shape, imprinting temperature and adhesive energy, on nanoimprint lithography process and pattern transfer. The simulation model consists of an amorphous $SiO_{2}$ stamp with line pattern, an amorphous poly-(methylmethacrylate) (PMMA) film and an Si substrate under periodic boundary condition in horizontal direction to represent a real NIL process imprinting long line patterns. The pattern transfer behavior and its related phenomena are investigated by analyzing polymer deformation characteristics, stress distribution and imprinting force. In addition, their dependency on the process parameters are also discussed by varying stamp pattern shapes, adhesive energy between stamp and polymer film, and imprinting temperature. Simulation results indicate that triangular pattern has advantages of low imprinting force, small elastic recovery after separation, and low pattern failure. Adhesive energy between surface is found to be critical to successful pattern transfer without pattern failure. Finally, high imprinting temperature above glass transition temperature reduces the imprinting force.

• International Journal of Automotive Technology
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• 제7권5호
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• pp.555-564
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• 2006

The aim of this paper is to contribute to the efficient design of traffic light poles involved in vehicle frontal collisions by developing a computer-based, finite-element model capable of capturing the impact characteristics. This is achieved by using the available non-linear dynamic analysis software "LS-DYNA3D", which can accurately predict the dynamic response of both the vehicle and the traffic light pole. The fiber reinforced polymer(FRP) as a new pole's material is proposed in this paper to increase energy absorption capabilities in the case of a traffic pole involved in a vehicle head-on collision. Numerical analyses are conducted to evaluate the effects of key parameters on the response of the pole embedded in soil when impacted by vehicles, including: soil type(clay and sand) and pole material type(FRP and steel). It is demonstrated from the numerical analysis that the FRP pole-soil system has favorable advantages over steel poles, where the FRP pole absorbed vehicle impact energy in a smoother behavior, which leads to smoother acceleration pulse and less deformation of the vehicle than those encountered with steel poles. Also, it was observed that clayey soil brings a slightly more resistance than sandy soil which helps reducing pole movement at ground level. Finally, FRP pole system provides more energy absorbing leading to protection during minor impacts and under service loading, and remain flexible enough to avoid influencing vehicle occupants, thus reducing fatalities and injuries resulting from the crash.

• 폴리머
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• 제39권2호
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• pp.261-267
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• 2015

The inclusion complexes (ICs) between polylactic acid (PLA) and ${\beta}$-cyclodextrin (CD) were prepared by co-precipitation method in this work. The orthogonal experiments were designed to investigate the influence of different factors on the formation of inclusion complexes. The results suggested that the optimum scheme of inclusion compounds could be obtained when the feeding ratio of CD to PLA (wt%) was 20:1, stirring speed was 6 kr/min and the stirring time was 30 min. The structures and properties of the inclusion complexes were characterized by $^1H$ NMR, FTIR, DSC, FT-Raman, XRD and TGA. The DSC results demonstrated that the crystallization behavior of the inclusion complexes nearly disappeared. It was found that ${\beta}$-CD-PLA inclusion complex had a better thermal stability compared with the neat PLA. The model of the inclusion complexes was proposed on the basis of XRD, $^1H$ NMR and DSC results.

• Elastomers and Composites
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• 제59권1호
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• pp.34-41
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• 2024

In this study, the effects of the type and content of silica on the mechanical and tear properties of chloroprene rubber (CR), which is mainly used as a jacket material for mining cables, were studied. The crosslinking density (ΔM) and reinforcing factor (α_f) defined using cure characteristics increased with increasing silica content, whereas the cure rate decreased. The hardness, tensile strength, and modulus of the CR compounds increased depending on the silica content and structural development. The reinforcing behavior of the silica-filled CR compounds according to the silica type and content showed the best fit with the Thomas equation of the predictive model. Tear strength was evaluated using two standard test methods, ASTM D470 and DIN VDE 0472-613, and the results were compared. The tear strength increased as the silica content increased, regardless of the test method, and the different tear strengths obtained by the two standard test methods showed a linear relationship with each other, indicating a high correlation.