• Title/Summary/Keyword: Polymer Composite Material

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Electrochemical Properties of Tin oxide-flyash Composite for Lithium Ion Polymer Battery (리튬 이온 폴리머 전지용 Tin oxide-flyash Composite 전극의 전기화학적 특성)

  • Kim, Jong-Uk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.88-90
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    • 2003
  • The purpose of this study is to research and develop tin oxide-flash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry and charge/discharge cycling of SnO-flyash/SPE/Li cells. The first discharge capacity of SnO-flyash composite anode was 720 mAh/g. The discharge capacity of SnO-flyash composite anode 412 and 314 mAh/g at cycle 2 and 10 at room temperature, respectively. The SnO-flyash composite anode with PVDF-PMMA-PC-EC-$LiClO_4$ electrolyte showed good capacity with cycling.

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Electrical applications of braided composite materials (브레이드 섬유강화 복합재료의 전기적 특성)

  • 한동희;조한구;한세원;박기호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.882-885
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    • 2001
  • This paper aims to investigate the characteristics of braided thermoplastic composite and pressure relief for polymer arrester. In general, braided composite has potential for improved impact and delamination resistance. Manufacturing processes of the braided composite could also be automated and could potentially lead to lower costs. Therefore, in consideration of characteristics of pressure relief for polymer arrester, the fabric pattern of braided composite was decided. And polymer arrester module was manufactured with braid.

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Influence Study of Aluminum Dross on Polypropylene Matrix-Polymer Composite Material Properties

  • Kongchatree, Khanob;Yaemphuan, Paiboon;Kaewwichit, Jesada;Roybang, Waraporn;Kimapong, Kittipong
    • International Journal of Advanced Culture Technology
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    • v.3 no.1
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    • pp.138-144
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    • 2015
  • This paper is aimed to study the influence of aluminium dross from Thai aluminum casting factory on polypropylene matrix-polymer composite material properties. The summarized experimental results are as follows. An increase in the amount of aluminum dross polymer composite material affected to increase hardness, modulus of elasticity and abrasion resistance. However, the increase of the aluminum dross had no effects to change the yield strength and the melting temperature of the polymer composite material. The aluminum dross also affected to form the crystallinity at $117-122^{\circ}C$ and directly increased the rigid property of the composite materials. The microstructure examination revealed that the aluminum dross was located in a polymer matrix and affected to increase the dark colour of the polymer composite material.

Electrochemical Properties of Graphene Composite for Lithium Polymer Battery (리튬 폴리머전지용 Graphene Composite의 전기화학적 특성)

  • 김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.359-362
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    • 2000
  • The purpose of this study is to research and develop graphene composite for lithium polymer battery. VO(graphene) composite is one of the promising material as a electrode active material for lithium polymer battery(LPB). We investigated AC impedance response and charge/discharge cycling of VO(graphene)/SPE/Li cells. The first discharge capacity of VO(graphene) cathode with 50wt.% V$_2$O$\sub$5/ was 150mAh/g, while that of VO(graphene) cathode with 85wt.% V$_2$O$\sub$5/ was 248mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The discharge capacity of VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ was 718 and 266mAh/g at cycle 1 and 10 at room temperature, respectively. The VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ in PVDF-PAN-PC-EC-LiC1O$_4$ electrolyte showed good capacity with cycling.

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Preparation and Characterization of Multiwalled Carbon Nanotubes/Lyocell Composite Fibers (다중벽 탄소나노튜브/리오셀 복합섬유의 제조 및 특성조사)

  • Lu, Jiang;Zhang, Huihui;Shao, Huili;Hu, Xuechao
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.436-441
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    • 2007
  • In this work, the multiwalled carbon nanotubes(MWNTs) were functionalized with sodium dodecylbenzene sulfonate(SDBS) and then MWNTs/Lyocell composite fibers were prepared. The properties of MWNTs, the functionlization on the surface of MWNTs and their dispersion in the cellulose matrix were characterized by TEM, SEM, WAXD and FT-IR. The results showed that SDBS has been coated successfully onto the surface of the MWNTs by functionlization. This can improve effectively the dispersion uniformity of MWNTs in NMMO aqueous solution and is helpful to prepare a spinnable spinning dope. Moreover, the resultant MWNTs/Lyocell composite fibers still have cellulose II crystal structure, and their tensile strength and initial modulus increased with the increasing draw ratio and reached the optimal value with adding 1 wt% MWNTs. The thermal stability of the composite fiber was also improved by the addition of the MWNTs.

Effect of gypsum content on the properties of PVC/Gypsum polymer blend material (PVC/Gypsum 복합체에서 Gypsum 의 영향)

  • N. V. Gian;Thai Hoan;Kim, M. Y.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.221-224
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    • 2003
  • Polyvinyl chloride (PVC)/gypsum Polymer blend materials were prepared by melt blending of PVC with gypsum and additives. Effect of gypsum content on the properties of PVC/gypsum Polymer blend material was studied by investigating physico-mechanical properties, thermal properties and morphology development. It was found that the replacement of gypsum for methylene-butadiene-sarene (MBS) component in PVC/gypsum polymer blend material enhanced the tensile strength, but gradually decreased its impact strength. Besides, with the increase of gypsum content, the elongation at break of material gradually decreased. The Presence of the different gypsum contents made a shift of g1ass transition temperature and increased the thermal stability as well as the processing temperature range of polymer blends. The observation of morphology, the results of the physico-mechanical properties and thermal properties proved simultaneously that PVC/gypsum Polymer blend material with the gypsum content of 22.56 wt.% reached the optimum results among five kinds of PVC/gypsum Polymer blend materials investigated.

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Energy dissipation of steel-polymer composite beam-column connector

  • Wang, Yun-Che;Ko, Chih-Chin
    • Steel and Composite Structures
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    • v.18 no.5
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    • pp.1161-1176
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    • 2015
  • The connection between a column and a beam is of particular importance to ensure the safety of civil engineering structures, such as high-rise buildings and bridges. While the connector must bear sufficient force for load transmission, increase of its ductility, toughness and damping may greatly enhance the overall safety of the structures. In this work, a composite beam-column connector is proposed and analyzed with the finite element method, including effects of elasticity, linear viscoelasticity, plasticity, as well as geometric nonlinearity. The composite connector consists of three parts: (1) soft steel; (2) polymer; and (3) conventional steel to be connected to beam and column. It is found that even in the linear range, the energy dissipation capacity of the composite connector is largely enhanced by the polymer material. Since the soft steel exhibits low yield stress and high ductility, hence under large deformation the soft steel has the plastic deformation to give rise to unique energy dissipation. With suitable geometric design, the connector may be tuned to exhibit different strengths and energy dissipation capabilities for real-world applications.

고충전 polymer/ceramic composite에서 유전 특성의 mixing rule

  • Lee, Ji-Ae;Sin, Hyo-Sun;Hong, Yeon-U;Yeo, Dong-Hun;Kim, Jong-Hui;Yun, Ho-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.309-309
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    • 2008
  • 전자 산업의 발달로 인해 전자기기에 소형화, 경량화 및 다기능화가 요구되면서 고밀도화, 고집적화가 필요하게 되었다. 이와 같은 부품의 고집적화 기술로 최근 제시되고 있는 방법 중 하나는 ceramic powder로 구성된 유전층에 polymer를 infiltration시키고 cure 과정을 거쳐 소결공정 없이 유전층을 완성하는 것이다. 그리고 이 유전층을 layer 단위로 build up하는 방법을 이용하여 반복적으로 형성하는 기술이 연구되고 있다. 그러나 고충전된 polymer/ceramic composite에서 유전 특성은 기존에 알려진 저충전 구조에서의 mixing 이론을 따를 것인지에 대한 실증적인 연구는 이루어지지 않았다. 본 연구에서는 ceramic powder $Al_2O_3$를 이용하여 polymer의 함량을 최소화하여 paste 를 제조하고, 스크린 프린팅 방법으로 인쇄하여 ceramic layer를 제작하였다. 그리고 이 위에 polymer infiltration 과정을 동하여 고충전 ceramic/polymer composite layer를 제작하였다. 또한, $Al_2O_3$를 filter로 사용한 저충전 polymer/ceramic composite에서의 mixing rule과 비교하여 복합체의 유전 특성을 설명하였다.

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Relations Between Dispersion of CNTs and Electrical Conductivity in the Hydrophobic CNT/PVDF Composite Film (소수성 CNT/PVDF 복합막에서 CNT의 분산과 전도성의 관계)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.462-466
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    • 2015
  • In this paper, we investigated the relations between dispersion of CNTs (carbon nanotubes) and electrical conductivity in the CNT/PVDF (polyvinylidene fluoride) composite film. By adding hydrophobic CNTs as filler into the PVDF matrix, we fabricated hydrophobic and electrically conducting polymer coating film. Dispersion of CNTs in the CNT/PVDF composite film plays a significant role in terms of electrical conductivity and wetting property. Spray coating method was used to form the CNT/PVDF composite films by injecting the dispersed CNTs in the PVDF solution with different weight ratios from 0.7 wt% to 7 wt%. We investigated the electrical properties and contact angles of the CNT/PVDF composite films with the CNT concentration. Finally we discussed the conducting mechanism and feasibility of the CNT/PVDF composite film for the conducting polymer films.

Effect of polymer addition on air void content of fine grained concretes used in TRCC

  • Daskiran, Esma Gizem;Daskiran, Mehmet Mustafa;Gencoglu, Mustafa
    • Computers and Concrete
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    • v.20 no.2
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    • pp.165-176
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    • 2017
  • Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.