• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1484-1486
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• 2005

To achieve the high reliability performance in IPS cell, finding a good combination of Liquid Crystal (LC) materials and Polyimide (PI) is very important as they play a key role in IPS cell. Several LC materials and PIs have been introduced for preparation of their different combinations. Electro optical characteristics such as voltage holding ratio, residual DC and AC image sticking have been investigated for the different system of the LC material and PI in the test panels in an attempt to find the effects on the display reliability performance and image sticking.1)3)

• 한국정보디스플레이학회:학술대회논문집
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• 2003.07a
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• pp.571-574
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• 2003

Three ring type liquid crystalline compounds having 4-alklycyclohexyl group, 1,2-difluorobenzene and phenylisothiocyanate moieties as main skeleton were designed to have negative dielectricity. However, the compounds with 2,3,2'-trifluoro-3'-isothiocyanated biphenylcyclohexane core did not exhibit the nematic liquid crystalline phase because of two conformers by interaction of isothiocyanate and adjacent fluorine atoms. Also, 4-alkyl-2,2',3'-trifluoro-3-isothiocyanated biphenylcyclohexane core was designed expecting to have uniform conformers of isothiocyanate group. In the course of developing polyimides for VA mode LCD, we synthesized alkyl-3,5-diaminobenzene efficiently with various length of alkyl chains from commercially available di-t-butyl malonate and 3,5-dinitrobenzoyl chloride as starting material.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.12
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• pp.2624-2630
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• 2002

Organic/inorganic hybrid materials have rapidly become a fascinating research field. In this study, $polyimide/TiO_2$ composites were synthesized from nano-sized anatase $TiO_2$ and two types of polyimide, that is, BPDA-PPD and PMDA-ODA. Nano-sized $TiO_2$ particles were prepared from $TiOEt_4$ solution by the sol-gel method. The synthesized PI/$TiO_2$ composites were characterized by using XRD, TGA, FT-IR, TEM, and Atomic Force Microscope(AFM). $TiO_2$ particles were dispersed well in polyimides and the mechanical and thermal stability of polyimide was improved with $TiO_2$ nano particles.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.155-155
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• 1999

반도체 소자의 초고집적화와 고속화에 따라 최소 선폭이 급격히 줄어듬에 따라 현재 사용되고 있는 다층금속배선의 층간절연막 0.18$\mu\textrm{m}$ 급 이상의 소자에 적용할 경우 기생정전용량이 증가하여 신호의 지연 및 금속배선간에 상호간섭현상으로 반도체 소자의 동작에 심각한 문제가 대두되고 있다. 이러한 물제를 해결하기 위하여 nonoporous silica, fluorinated amorphous carbon, polyimides, poly(arylene)ether, parylene, AF4, poly(tetrafluoroethylene), divinyl siloxane bisbenzocyclobutene, Silk, 그리고 유무기 hybrid nanofoam 등이 저유전물질로 각광을 받고 있으며, 여기에 대한 연구가 우리나라를 비롯하여 미국, 일본 등에서 많은 연구가 이루어지고 있다. 따라서 본 연구에서는 2003년에 개발될 0.13$\mu\textrm{m}$급 이상의 차세대 반도체 소자에 적용될 수 있는 저유전물질 개발현황과 이들 물질 중 4GDRAM 급이상의 소자에 적용가능성이 가장 높은 유무기 hybrid nanofoam, a-C:F와 C:F-SiO2 박막에 대한 특성에 대하여 소개하고자 한다.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.770-772
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• 2002

A new dry-processing method of organic gate dielectric film in field-effect transistors (FETs) was proposed. The method use vapor deposition polymerization (VDP) that is continuous and low temperature process. It has the advantages of shadow mask patterning and dry processing in flexible low-cost large area applications. Here, 80 nm-thick Al as a gate electrode was evaporated through shadow mask. Gate insulators used two different polyimides. The one material was 4,4'-oxydiphtahlic anhydride (ODPA) and 4,4'-oxydianiline (ODA). Another was 2,2-bis(3,4-dicarboxyphenyl) Hexafluoropropane Dianhydride (6FDA) and 4,4' -oxydianiline (ODA). These were co-deposited by high-vaccum thermal-evapora and cured at 150 $^{\circ}C$ for 1 hour, respectively. Pentacene as a semiconductor and 100 nm-thick Au as a source and drain electrode were evaporated through shadow mask.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.1083-1084
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• 2002

We prepared the blend alignment layers made from coumarin based photopolymer and polyimides for liquid crystal(LC) alignment using linearly polarized ultraviolet(UV) exposure. The alignment properties of LC were found to depend on the type of polyimide in the blend alignment layers. The degree of photereaction of polyimide was important factor for LC alignment direction on the blend alignment layers.

• Proceedings of the Korean Fiber Society Conference
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• 2003.10b
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• pp.175-176
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• 2003

Generally, The protone exchange membrane (PEM) contains cationic exchange groups such as SO3$\^$-/ group. The poly(styrene sulfonic acid) (PSSA) and its copolymers are widely studied because of easily synthetic method and higher conductivities. However, PSSA is not used individually because of poor physical properties such as brittleness and relatively lower Tg. So some researchers are concerned engineering plastics (EP) such as polyimides, polysulfone, polyketones, and poly(2,6-dimethyl-1,4-phenylene oxide) (MPPO) etc. (omitted)

• Fibers and Polymers
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• v.3 no.2
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• pp.60-67
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• 2002

In the present study, the fluorescence behavior ova phenylethynyl-terminated imide (LaRC PETI-5) resin, a bismaleimide (BMI) resin, and various LaRC PETI-5/BMI blends with different blend compositions has been characterized as a function of heat-treatment temperature, using a steady-state fluorescence technique with a front-face illumination method far solid-state films. It is observed that there are distinguishable changes in the spectral shape, size, and position of fluorescence with varying heat-treatment temperature in the pure and blend samples. The result is qualitatively explained in terms of charge transfer complex formation as well as microenvironmental change with local mobility and viscosity occurring in the LaRC PETI-5, BMI, and their blends during the cure process. The result also implies that a steady-state fluorescence technique may be a useful tool to understand the processing conditions of polyimides and their blends in the film form on the basis of their thermo-photophysical responses.

• 한국정보디스플레이학회:학술대회논문집
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• 2000.01a
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• pp.41-42
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• 2000

Photosensitive polyimides containing cinnamoyl and coumarin side groups were synthesized in a high molecular weight, giving a good quality of films. Nematic liquid-crystal (LC) molecules on the film were aligned along the direction with an angle of $97-99^{\circ}$ respect to the polarization of ultraviolet (UV) light. The LC alignment was induced mainly by the photoaligned polymer chains made by the first UV-exposure even though the film was treated by multiple exposures with changing the polarization of UV light. From these results, it is concluded that the LC alignment on the film is induced by the photodimerization rather than the trans-cis photoisomerization.

• 한국정보디스플레이학회:학술대회논문집
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• 2000.01a
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• pp.213-214
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• 2000

New light-emitting polyimides were synthesized from the conventional polycondensation of 5,5'-bis(4-aminophenyl)-2,2'bifuryl (PFDA) with fluorinated and non-fluorinated aromatic dianhydrides, providing a good quality of thin films: 6F-PFDA PI and ODPA-PFDA PI. Their UV-visible absorbance and photoluminescent characteristics were investigated. The polymers emit blue and blue-greenish light in a quantum yield of 7.3-14.9%, depending on the polymer backbone.