• Title/Summary/Keyword: Polyethylene terephthalate

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MA 그라프트 폴리에스테르직물의 염색성에 관한 연구 (A Study on Dyeability of Polyester Fabrics Grafted with Methacrylic Acid)

  • 백천의;조승식;송화순
    • 한국의류학회지
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    • 제19권6호
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    • pp.946-954
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    • 1995
  • The purpose of this study is to modify the hydrophobic property and dyeability of polyethylene terephthalate fiber. Methacrylic acid (2nA) was graftpolymerized with benzoyl peroxide (BPO) as initiator onto polyethylene terephthalate fabrics. The results were as follow; 1. Graft-polymerization exhibited maximum graft ratio at a temperature of 100"C. 2. The polymer was gradually grafted in great amount to the surface of MA-g-PET as graft ration increase; with the cross-section examination of MA-g-PET, it was discovered that graft-polymeriation had also taken place inside the textile core. 3. Dyes absorption of basic dyes and disperse dyes was improved as craft ratio increase; with resistance to laundering, the former showed grade 3-4 and the latter showed grade 5.de 5.

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열 열화에 의한 폴리에틸렌 테레프탈레이트 필름의 전기 특성에 관한 연구 (A Study on Electricity Properties of Polyethylene Terephthalate Film due to Thermally Degradation)

  • 이성일
    • 한국전기전자재료학회논문지
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    • 제30권11호
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    • pp.693-698
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    • 2017
  • In this study, the thermal degradation properties of polyethylene terephthalate film has been examined by the capacitance, Tan ${\delta}$, thermography, FTIR, and SEM results at temperatures of $90{\sim}170^{\circ}C$ and frequencies of 0.3~3,000 kHz. It was found that the capacitance decreased with increasing thermal imaging temperature, probably caused by weakening of chemical bond with increasing temperature. Tan ${\delta}$ decreased upon increasing temperature from $90^{\circ}C$ to $170^{\circ}C$, probably due to the molecular motion of COOH radical or OH radical. The FT-IR measurement reveals that no structural change of the material occurs upon thermal radiation. The SEM measurement shows that the material is stabilized by thermal decomposition with increasing temperature; however, excessive thermal degradation obstructs the stabilization of the material.

RF Bias Effect of ITO Thin Films Reactively Sputtered on PET Substrates at Room Temperature

  • Kim, Hyun-Hoo;Shin, Sung-Ho
    • Transactions on Electrical and Electronic Materials
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    • 제5권3호
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    • pp.122-125
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    • 2004
  • ITO films were deposited on polyethylene terephthalate substrate by a dc reactive magnetron sputtering using rf bias without substrate heater and post-deposition thermal treatment. The dependency of rf substrate bias on plasma sputter processing was investigated to control energetic particles and improve ITO film properties. The substrate was applied negative rf bias voltage from 0 to -80 V. The composition of indium, tin, and oxygen atoms is strongly depended on the rf substrate bias. Oxygen deficiency is the highest at rf bias of -20 V. The electrical and optical properties of ITO films also are dominated obviously by negative rf bias.

재생 PET 섬유가 혼입된 섬유 보강 콘크리트의 균열저항특성 (Crack Resistance Properties of Fiber Reinforced Concrete with Recycled PET Fiber)

  • 김성배;김현영;이나현;김장호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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    • pp.545-546
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    • 2009
  • 본 연구에서는 재활용된 polyethylene terephthalate (RPET)로 만든 플라스틱 단섬유의 구조재료로써의 사용 가능성을 조사하였다. 실험은 균열제어 성능을 확인하기 위해 구속건조수축균열 시험을 평가하였다. 성능을 검증하기 위해서 가장 널리 상용되는 합성섬유인 poly propylene (PP) 섬유와 비교하였으며, 섬유의 혼입률을 0%, 0.5%, 0.75%, 1.0%로 변화시켜 혼입률에 따른 영향을 함께 검토하였다.

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Fiber surface and electrical conductivity of electroless Ni-plated PET ultra-fine fibers

  • Choi, Woong-Ki;Kim, Byung-Joo;Park, Soo-Jin
    • Carbon letters
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    • 제14권4호
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    • pp.243-246
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    • 2013
  • In this work, electroless Ni-plating on polyethylene terephthalate (PET) ultra-fine fibers surfaces was carried out to improve the electric conductivity of the fiber. The surface properties of PET ultra-fine fibers were characterized using scanning electron microscopy, X-ray diffraction, and contact angle analyses. The electric conductivity of the fibers was measured using a 4-point testing method. The experimental results revealed the presence of island-like nickel clusters on the PET ultra-fine fibers surfaces in the initial plating state, and the electric conductivity of the Ni-plated fibers was enhanced with increasing plating time and thickness of the Ni-layers on the PET ultra-fine fibers.

미세 비아홀 펀칭 공정 중 이종 재료 두께에 따른 버 생성 (Thickness Effect of Double Layered Sheet on Burr Formation during Micro-Via Hole Punching Process)

  • 신승용;임성한;주병윤;오수익
    • 소성∙가공
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    • 제13권1호
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    • pp.65-71
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    • 2004
  • Recent electronic equipment becomes smaller, more functional, and more complex. According to these trends, LTCC(low temperature co-fired ceramic) has been emerged as a promising technology in packaging industry. It consists of multi-layer ceramic sheet, and the circuit has 3D structure. In this technology via hole formation plays an important role because it provides an electric path for the packaging interconnection network. Therefore via hole qualify is very important for ensuring performance of LTCC product. Via holes are formed on the green sheet that consists of ceramic(before sintering) layer and PET(polyethylene terephthalate) one. In this paper we found the correlation between hole quality and process condition such as PET thickness and ceramic thickness. The shear behavior of double layer sheet by micro hole punching which is different from that of single layer one was also discussed.

폴리머 재료에서의 광학적 물성의 온도의존성 (Temperature Dependence of Optical Properties on Polymer Materials)

  • 정승묵;신영곤;이상훈;송국현;김영진;이낙규;나경환
    • 반도체디스플레이기술학회지
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    • 제3권4호
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    • pp.5-11
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    • 2004
  • Optical properties of PET(Polyethylene terephthalate), PC(Polycarbonate), Acrylic resin and PE(Polyethylene) sheets were studied as a function of heat treating temperature of $60^{\circ}C$ to $150^{\circ}C$. By the heat treatment, optical properties of transmittance, absorbance, and reflectance showed a considerable change with different ways according to the materials. To understand the reason of optical property change, X-ray diffraction and surface morphology were also investigated. It was observed that small crystallite and pore that can cause scattering largely affect the transmittance. It was suggested that change of surface chemical bond induce the reflectance variation.

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실리콘 고무와 내열접착 향상을 위한 Polyethylene Terephthalate 섬유 접착층의 제조 및 특성 (Treatment and Characterization of Polyethylene Terephthalate Fibers with Silicone Rubber Adhesive for Heat-Resistant Adhesion)

  • 김지효;이상오;이재웅
    • 한국염색가공학회지
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    • 제31권2호
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    • pp.107-117
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    • 2019
  • In case of pure rubber materials, the initial quality of the rubber materials would be excellent, however, the durability against external impact might be poor. In order to overcome the relatively low durability, textile cord could be employed with silicone rubber. We have studied the improvement of heat-resistant adhesion properties of silicone adhesives between silicone rubber and PET fibers by applying various conditions including dip solution recipe. The silicone rubber used was a platinum catalyst curing type and platinum catalyst type silicone adhesive was used as an adhesive to obtain an optimum adhesive force. Furthermore, the bonding mechanism between silicone and PET fiber was established.

재활용 PET(polyethylene terephthalate)를 이용한 PBT(polybutylene terephthalate) 올리고머 제조 (Production of PBT(polybutylene terephthalate) Oligomer from Recycled PET(polyethylene terephthalate))

  • 조민정;양정인;노승현;조홍제;한명완
    • Korean Chemical Engineering Research
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    • 제54권4호
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    • pp.437-442
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    • 2016
  • 재활용 PET (Poly ethylene terephthalate)로부터 PBT (Poly butylene terephthalate)를 생산할 수 있는 새로운 방법을 모색하였다. 이 방법은 PET와 BD (1,4-butanediol)의 에스테르 교환반응을 통하여 BHBT (Bishydroxybutylterephthalate) 올리고머를 생성하는 글리콜리시스 반응과 BHBT의 축합 중합 반응을 통하여 PBT 올리고머를 생성하는 축중합 반응으로 이루어져 있다. 이를 통해 단기 수명 주기 제품인 버려지는 PET 페자원을 장기 수명 주기 제품인 PBT로 변환시켜 더 가치 있고 바람직한 재활용을 하고자 하였다. 본 연구에서는 글리콜리시스와 축중합 촉매로 zinc acetate를 사용하였고, 글리콜리시스 반응에 대하여 회분식 반응기와 반 회분식 반응기를 적용하여 성능을 비교하였다. 이를 위하여 생성되는 에틸렌글리콜(EG)의 양을 정량하여 해중합도를 추정할 수 있는 EG 수율과 부산물인 THF 생성량을 성능 척도로 하였다. 반응 도중에 EG를 제거하는 반회분식 반응기의 성능이 회분식 반응기에 비하여 보다 우수한 것으로 나타났다. 또한 반회분식 반응기의 경우 최적의 반응조건은 BD/PET 비율 4, 반응온도 $220^{\circ}C$ 이었으며, 최고 EG 수율은 91% 이었다. 또한 축 중합 반응이 진행됨에 따라 PBT 올리고머의 분자량이 증가하는 것을 보였다.