• Title/Summary/Keyword: Polyester resin

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Characterization of Polymer and Nano-MMT-composite as Binder of Recycled-Pet Polymer Concrete (폴리머콘크리트의 결합제로서 PET재활용 폴리머와 나노 MMT 복합체의 특성)

  • Jo, Byung-Wan;Park, Seung-Kook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.292-295
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    • 2004
  • Recently, polymer-clay hybrid materials have received considerable attention from both a fundamental research and application point of view. This organ-inorganic hybrid, which contains a nanoscale dispersion of the layered silicates, is a material with greatly improved thermal and mechanical characteristics. Two classes of nanocomposites were synthesized using an unsaturated polyester resin as the matrix and sodium montmorillonite as well as an organically modified montmorillonite as the reinforcing agents. X -ray diffraction pattern of the composites showed that the interlayer spacing of the modified montmorillonite were exfoliated in polymer matrix. The mechanical properties also supported these findings, since in general, tensile strength, modulus with modified montmorillonite were higher than the corresponding properties of the composites with unmodified montmorillonite. Adding organically modified clay improved the tensile strength of unsaturated polyester by $22\%$ and the tensile modulus of unsaturated polyester was also improved by $34\%$.

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Manufacture of Soluble Micro-fiber and Low Melting Polymer for Interior Synthetic Leather (인테리어용 인조가죽을 위한 용출형 극세사와 저온 융착사의 제조)

  • Ahn, Young-Moo
    • Korean Journal of Human Ecology
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    • v.12 no.4
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    • pp.529-537
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    • 2003
  • This study was conducted to manufacture the soluble micro-fiber and to synthesize low melting polymer for the interior fabric not to use the polyurethane resin causing some problems. Low melting polyester for weft yarn was introduced by adding 30-40 mol% ratio of isophthalic acid to a main chain of polyethylene terephthalate to decrease the melting temperature up to heat setting temperature. Micro-fiber for warp yarn consisted of both soluble and insoluble components with multi-layered structure. When the soluble micro-fiber was treated by alkaline hydrolysis with 3-5% concentration of NaOH, it showed the turning point at 28% weight loss since soluble polyester was hydrolyzed approximate five times faster than regular polyester.

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Dielectric Characterization of Unsaturated Polyester Curing (불포화 폴리에스터의 경화에 따른 유전특성 연구)

  • 오경성;김홍경;김명덕;남재도
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.728-736
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    • 2002
  • The thermal and dielectric properties of unsaturated polyester resin system during cure were analyzed under Isothermal conditions. Both $varepsilon$′ and $varepsilon$" decreased and dipole relaxation was observed under isothermal conditions during cure. The ionic conductivity decreased linearly with the conversion according to the Kienle-Rate equation (ln($varepsilon$"$_{ionic}$we$_{0}$)=C$_{r}$$alpha$+C$_{0}$) up to $alpha$=0.15, after which it aparted from the relationship due to the entanglement of polymer chains. The effect of ionic conductivity was revealed to be larger than that of dipole motion during the whole cure through the electrical modulus analysis. Although dielectric motion was analyzed with Debye model, it was observed only at a narrow time region of middle stage of cure. In order to estimate the dielectric properties during the whole cure, the Havriliak-Negami model was considered and modified with the strong effect of ionic conductivity. The changes of $varepsilon$′ and $varepsilon$" were well estimated with this modified Havriliak-Negami model.

Nonthermal plasma on the shear bond strength of relining resin to thermoplastic denture base resin (열가소성 의치상 레진과 첨상용 레진의 접착 강도에 저온플라즈마가 미치는 효과)

  • Manaloto-Ceballos, Liezl;Labriaga, Wilmart;Song, So-Yeon;Park, Jin-Hong;Lee, Jeong-Yol;Shin, Sang-Wan
    • The Journal of Korean Academy of Prosthodontics
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    • v.56 no.3
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    • pp.199-205
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    • 2018
  • Purpose: This study evaluated the effect of nonthermal plasma treatment on the bond strength of autopolymerizing relining resin to the injection molded thermoplastic denture base resins (TDBRs) with different surface treatments. Materials and methods: Acrylic Resin (Acrytone), Polyester (Estheshot-Bright), Polyamide (Valplast) and Polypropylene (Weldenz) were subjected to various surface treatments: No treatment, Nonthermal plasma, Sandblasting, Sandblasting and nonthermal plasma. Specimens were bonded using an autopolymerizing relining resin. Shear bond strength was tested using universal testing machine with crosshead speed of 1 mm/min. Statistical analysis by two-way analysis of variance with Tukey's test post hoc was used. Results: Acrytone showed significantly higher shear bond strength value among other TDBR group while Weldenz had the lowest. The sandblasting and nonthermal plasma condition had significantly higher shear bond strength value in all of the resin groups (P < .05). Conclusion: The use of nonthermal plasma treatment showed limited effect on the shear bond strength between TDBRs and relining resin, and combination of nonthermal plasma and sandblasting improved the shear bond strength between TDBR and reline material.

Study on the Manufacture of Resin Concrete of Machine Tool Bed with High Damping Capacity (고감쇠 레진 큰크리트 공작기계 베드 제작에 관한 연구)

  • 서정도;방경근;이대길;김태형;박보선
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.429-433
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    • 1997
  • High-speed and high-precision are trendy at present in the development of machine tools which are required for various fields of industry such as semiconductor, automobde, mold fabricat~on and so on. High damping capacity of the structure is an iniportant factor to ohtain precise products without vibration during manufacturing caused by rapid trarisportatm and rotation of spindle unit Resin concrete have high potential for machine tool bed due to its good damping characteristics. In this study, the statlc and dynamic characteristics of the machine tool bed were analysed. Also, the hybrid machine tool bed, made of steel base and polyester resin concrete material, was manufactured and its good dynamic characteristics were proved experimentally.

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An Experimental Study on the Bending Behavior of F.R.P. Sandwich Structure with 2nd Reinforced Bonding (2차 접착된 Sandwich 구조의 굽힘에 관한 실험연구)

  • Kim, Ik Tai
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.1
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    • pp.47-51
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    • 2016
  • It has made a special study of bending behavior of F.R.P. sandwich beams with bonded 2nd-reinforced plies. Specimen's faces were made of chopped mat 300-450, roving clothes 570, core is urethane foam, resin is 713bp unsaturated polyester for ship construction and the mixture weight ratio of resin versus fiber was 55:45 for bending analysis. The purpose of this paper is to study the exact bending behavior of bonded area's deflection and stiffness depends upon various bonded F.R.P. (2nd reinforced ply) length and thickness on which covered joints and to find the optimum design for the sandwich structures. All results and suggestions are based on experiment and using thick face calculation.

A Study on the Early Strength Prediction of Lightweight Polymer Mortars by the Maturity Method (적산온도법에 의한 경량 폴리머 모르터의 초기강도 예측에 관한 연구)

  • 이윤수;대빈가언;연규석
    • Magazine of the Korea Concrete Institute
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    • v.10 no.6
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    • pp.191-202
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    • 1998
  • The maturity method in which the strength increase of cement concrete is expressed as a function of an intergral of the curing period and temperature of the concrete has often been applied to its strength prediction. For the purpose of the application of the maturity method to the compressive strength prediction for lightweight polymer mortars using an unsaturated polyester resin as a binder, the lightweight polymer mortars with various catalyst and accelerator contents, are prepared. tested for compressive strength, and the datum temperatures for the maturity equations are estimated. The maturity is calculated by using the maturity equations with the estimated datum temperature. The compressive strengths of the lighweight polymer mortars are predicted from the maturity-compressive strength relationships.

A Study on the Impact Fracture Behavior of Side Plate of 35 Ton Class FRP Ship (35톤급 FRP선박 외판재의 충격파괴거동에 관한 연구)

  • Kim, H.J.;Lee, J.J.;Koh, S.W.;Kim, J.D.
    • Journal of Power System Engineering
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    • v.9 no.4
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    • pp.137-142
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    • 2005
  • The effects of temperature and initial crack length on impact fracture behavior of side plate material of 35 ton class FRP ship, which are composed by glass fiber and unsaturated polyester resin, were investigated. Impact fracture toughness of GF/PE composites displayed maximum value when the temperature of specimen is room temperature and $50^{\circ}C$, and with decrease in temperature of specimen, impact fracture toughness decreased. Impact fracture energy of GF/EP composites decreased with increase in initial crack length of specimen, and this value decreased rapidly when the temperature of specimen is lowest, $-25^{\circ}C$,. It is believed that sensitivity of notch on impact fracture energy were increased with decrease in temperature of specimen. As the GF/EP composites exposed in low temperature, impact fracture toughness of composites decreased gradually owing to the decrease of interface bonding strength caused by difference of thermal expansion coefficient between the glass fiber/polyester resin. Further, decrease of interface bonding strength of composites with decrease in specimen temperature was ascertained by SEM photograph of impact fracture surface.

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Effect of Allyl Modified/Silane Modified Multiwalled Carbon Nano Tubes on the Electrical Properties of Unsaturated Polyester Resin Composites

  • Swain, Sarojini;Sharma, Ram Avatar;Patil, Sandip;Bhattacharya, Subhendu;Gadiyaram, Srinivasa Pavan;Chaudhari, Lokesh
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.6
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    • pp.267-272
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    • 2012
  • Considering the properties of the carbon nano tubes (CNT), their inclusion into the polymer matrix vastly increases the properties of the resultant composite. However, this is not the case due to the poor interfacial adhesion of the CNT and the polymer matrix. The present approach focuses on increasing the interaction between the polymer matrix and the CNT through the chemical modification of the CNT resulting in allyl ester functionalized carbon nanotubes (ACNT) and silane functionalized carbon nano tubes (SCNT) which are capable of reacting with the polymer matrix during the curing reaction. The addition of ACNT/SCNT into unsaturated polyester resin (UPR) resulted in the improvement of the electrical properties of resulted nanocomposites in comparison to the CNT. The surface resistivity, volume resistivity, dielectric strength, dry arc resistivity, and the comparative tracking index of the nanocomposites were significantly improved in comparison to CNT. The chemical modification of CNT was confirmed via spectroscopy.