• Title/Summary/Keyword: Polyester film

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Studies on the Oxygen Permeability and It's Proofness of the Various Commercial Polymer Films (상업용 고분자 필름의 산소투과도 및 산소투과 방지도에 관한 연구)

  • Suh, Hwan-Kyu;Kim, Joon-Soo;Lee, Jung-Keun
    • Elastomers and Composites
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    • v.15 no.1
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    • pp.3-9
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    • 1980
  • The oxygen permeability and it's proofness of te various commercial polymer films have been investigated at the constant pressure and temperature. Oxygen proofness, the reciprocals of the oxygen permeability for the various samples, were determined by means of a coulometric oxygen permeability tester. The testing of sample films was performed at constant temperature $(23{\pm}1^{\circ}C)$ under 1 atm. for 24 hours. The order of the relative proofness observed are as follows; oriented Nylon (O. Nylon)> oriented Polyester (O. PET)>nonoriented Nylon (N. Nylon)>nonoriented Polyester (N.PET)> rigid Polyvinyl chloride (Rigid PVC)>semirigid Polyvinyl chloride (Semirigid PVC)> oriented Polypropylene (O. PP)>plasticized Polyvinyl chloride (P. PVC)> casted Polypropylene (C. PP)> low density Polyethylene (LDPE)>high density Polyethylene (HDPE, Inflation)> high density-polyethylene (HDPE, T-die) The oxygen proofness of the films was increased with the polarity cf polymer, the film thickness and mechanical orientation and decreased with the addition of plasticizer in PVC. For the use of wrapping materials, one film with the polar property in the main chain of the polymer molecule and the others with nonpolar property in it are laminated for the protection from oxygen and moisture.

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Study for Synthesis and Properties of Polyurethane Based on Polyester Polyol with Varying Hydroxyl Values for Automotive Pre-painted Metal Sheet Applications (자동차 선도장 강판용 폴리에스테르 폴리올 기반 폴리우레탄의 합성과 물성에 대한 연구)

  • Kang, Choong Yeol;Lee, Jae Young;Noh, Seung Man;Nam, Joon Hyun;Park, Jong Myung;Jung, Hyun Wook;Yu, Sang Soo
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.34-42
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    • 2011
  • The roll coating process is well-known for completely replacement coating system with an existing wet paint process for automotive which has low productivity and is not environment-friendly process. It is very important to evaluate the curing behavior, corrosion resistance and processing property as well as rheological behavior in order to realize a film flexibility and hardness simultaneously. In this study, we have synthesized the polyester resin modified with hydroxyl values and molecular weight to apply the pre-painted system, and then evaluated the curing behavior, deep drawing, tensile strength and rheological properties. It was observed that N-0375-40 of 40 (mg KOH/mol) hydroxyl values showed the most suitable for flexibility, film hardness, and curing behavior.

Preparation and Curing Behavior of Two-Packaged Polyurethane Coatings by Benzoic Acid Lactone Modified Polyester/HDI-Biuret (벤조산 락톤 변성폴리에스테르/HDI-Biuret에 의한 2액형 폴리우레탄 도료의 제조 및 경화거동)

  • Seo, Kum-Jong;Kwon, Soon-Yong;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.2
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    • pp.59-66
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    • 1998
  • Two-packaged polyurethane coatings were prepared by blending benzoic acid lactone modified polyester polyol(BLMPs) and HDI-biuret. BLMPs were synthesized by polycondensation of benzoic acid, viscosity depression component, with 1,4-butanediol, adipic acid, and polycaprolactone polyol. Kinematic viscosity of BLMP was gradually decreased with increasing benzoic acid content in BLMP. The low viscosity of modified polyester has an advantage of making a high-solid content coatings. After the film was coated with the prepared polyurethane coatings and cured at room temperature, the various physical properties were measured. They showed good physical properties such as flexibility, impact resistance, cross hatch adhesion, yellowness index, and rust resistance. These advantages are the results of introducing polycaprolactone polyol.

A Study on Characteristics of Coated Films on Wood Surface by Nitrocellulose Lacquer, Aminoalkyd, Polyester, and Polyurethan (니트로셀룰로오스락카, 아미노알키드, 폴리에스테르 및 폴리우레탄 도료(塗料)의 도막성능(塗膜性能)에 관(關)한 고찰(考察))

  • Lee, Phil-Woo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.17 no.1
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    • pp.12-21
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    • 1989
  • This experiment was executed to investigate the characteristics of gloss and color difference in coated films by N.C. Lacquer, Aminoalkyd, Polyester. and Polyurethan coating after chemical (distilled water, ethyl alcohol. acetic acid, and sodium hydroxide) and heating ($120^{\circ}C$) treatments, cold-check test, and U.V. radiation. The results obtained were summarized as follows 1. The gloss decreasing rate by water resistance test was the least among chemicals treated on coated films. 2. The color difference of coated films chemical treatments highly and similarly increased, except the alkali treatment showing a little increase. 3. In the color difference by U.V. radiation, the polyester coated film showed generally large difference compared with the other coated films.

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Nanofabrication of Microbial Polyester by Electrospinning Promotes Cell Attachment

  • Lee, Ik-Sang;Kwon, Oh-Hyeong;Wan Meng;Kang, Inn-Kyu;Yoshihiro Ito
    • Macromolecular Research
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    • v.12 no.4
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    • pp.374-378
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    • 2004
  • The biodegradable and biocompatible poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), a copolymer of microbial polyester, was fabricated as nanofibrous mats by electrospinning. Image analysis of the electrospun nanofibers fabricated from a 2 wt% 2,2,2-trifluoroethanol solution revealed a unimodal distribution pattern of fiber diameters with an observed average diameter of ca. 185 nm. The fiber diameter of electrospun fabrics could be controlled by adjusting the electro spinning parameters, including the solvent composition, concentration, applied voltage, and tip-to-collector distance. Chondrocytes derived from rabbit ear were cultured on a PHBV cast film and an electrospun PHBV nano-fibrous mat. After incubation for 2 h, the percentages of attached chondrocytes on the surfaces of the flat PHBV film and the PHBV nanofibrous mat were 19.0 and 30.1 %, respectively. On the surface of the electrospun PHBV fabric, more chondrocytes were attached and appeared to have a much greater spreaded morphology than did that of the flat PHBV cast film in the early culture stage. The electro spun PHBV nanofabric provides an attractive structure for the attachment and growth of chondrocytes as cell culture surfaces for tissue engineering.

Synthesis and Properties of Novel Y-type Nonlinear Optical Polyester Containing Dioxynitroazobenzene Group with Enhanced Thermal Stability of Dipole Alignment

  • Kim, Mi-Sung;Cho, You-Jin;Song, Mi-Young;Lee, Ju-Yeon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3361-3366
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    • 2011
  • New Y-type polyester (3) containing nitrophenylazoresorcinoxy groups as NLO chromophores, which are components of the polymer backbone, was prepared and characterized. Polyester 3 is soluble in common organic solvents such as N,N-dimethylformamide and acetone. It shows a thermal stability up to $240^{\circ}C$ in thermogravimetric analysis with glass-transition temperature ($T_g$) obtained from differential scanning calorimetry near $116^{\circ}C$. The second harmonic generation (SHG) coefficient ($d_{33}$) of poled polymer film at the 1064 nm fundamental wavelength is around $4.63{\times}10^{-9}$ esu. The dipole alignment exhibits a thermal stability even at $4^{\circ}C$ higher than $T_g$, and there is no SHG decay below $120^{\circ}C$ due to the partial main-chain character of polymer structure, which is acceptable for NLO device applications.

Detergency of Triolein in Mixed Burfactant Solutions (혼합 계면활성제용액에서 Triolein의 세척성)

  • 정혜원
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.2
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    • pp.390-397
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    • 1996
  • The effects of the mixture of surfactants on the removal of triolein applied to cotton and polyester fabrics were studied. The sunactants which were usually formulated to the Iriundry detergents, such as sodium dodecyl sulfonate (LAS), sodium lauryl sulfate (AS), $\alpha$-olefin sulfonate (AOS, C=14), sodium laurethoxy sulfate (AES, EO=3) and lauryl ethoxylate (AE, EO=7) were used. Washing was done at 40'C, 60"C, 80'c and the surfactant concentration was 0.05%. Backscattered electron imaging was made to study the location of triolein in the yarns. Triolein was removed easily from polyester than cotton fabrics.01eic acid added triolein wa9 removed greater than triolein only, except in AE solutions. In AE solutions, the removal of triolein was increased as the tremperature went higher and the increasing rate of the removal of triolein only was greater than that of oleic acid added triolein. In the result, more triolein was removed from triolein only than from oleic acid added triolein at 80t When the other surfactant was added to LAS, AES was the best to cotton fabrics, AOS was to polyester fabrics. Triolein was located in the lumen and grooves of the fibers and the deeper interfiber spaces. Triolein did not make thin film arround the cotton fiber in the surface, but polyester fibers. These are the main reason why the removal of triolein was difficult from cotton fabrics.rics.

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Polyester Film Laminating Technology for Chip Condenser

  • Lee, Yun Dai;Son, Yang Soo;Ahn, Joong Geol
    • Corrosion Science and Technology
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    • v.3 no.4
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    • pp.172-177
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    • 2004
  • Biaxially oriented polyethylene terephthalate copolymer(BO - PET)film laminated aluminiums have been applied for chip condenser case. The BO PET film is characterized by high molecular which gives high corrosion resistance, good adhesion and high heat resistance. The higher orientation lowers formability of the film. So, optimum orientation has to be controlled during the laminating process. And to confirm the adhesion between BO PET and aluminium and to guarantee the formability of PET laminated aluminums, we have controlled the chromium oxides weight on the aluminium and laminating condition ( laminating temperature, soaking temperature and lag time after nip roll and quenching conditions) This paper discusses the effect of the laminating conditions on the formability of laminated aluminums. As results, it is clear that the orientation of the BO PET film decreased with an increase in the strip temperature. When the film temperature is over the melting point of the film, its orientation drastically decreased.

Water Repellent Finish of Polyester Fabric Using Carbontetrafluoride Plasma Treatment (4불화탄소 플라즈마처리에 의한 폴리에스테르 직물의 발수가공)

  • 모상영;이용운;김태년;천태일
    • Textile Coloration and Finishing
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    • v.6 no.3
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    • pp.27-36
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    • 1994
  • In order to produce a water repellent surface on polyester fabric, samples were treated in the atmosphere of $CF_4$ glow discharge plasma. The samples used in the study were ployester fabric and poyester film. The purpose of film treatment is for the comparison of hydrophobicity with fabric sample at same treatment condition. Radio frequency(13.56MHz) generator was used as electric source and its in put power is 100 Watt. Water repellency was evaluated by contact angle measurement. Result obtained are as follows. 1) Fiber interstice of original fabric was ana lysed as 0.43$\mu$m, and this value was sufficiently ideal for making water repellent fabric. 2) The most favorable setting position of substrate was the center area between two electrodes. 3) Fabric contact angle was higher than film contact angle at same treatment condition, and its difference was more than 50${\circ}$. And it was incapalbe of fabric contact angle measurement when the film contact angle was less than 90${\circ}$. because the fabric is susceptible to absorption of water by the capillary effect. 4) Fabric contact angle can not revealed the precise defferences of surface hydrophobicity, however, the film contact angle showed the real hydrophobic nature. 5) It was not sufficient method to evaluate the hydrophobicity of fabric surface by merely measure of the water contact angle. 6) It showed high water repellent nature at 0.06 torr of $CF_4$ plasma gas pressure and duration of 45 seconds treatment, and it can not be anticipated more improved nature if the pressure and duration of treatment time were increased.

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Insulated Characteristics of PET Film under $SF_6$ ($SF_6$ 가스중 PET Film의 절연특성)

  • Kim, J.D.;Jung, J.G.;Joo, S.C.;Lee, D.J.;Park, J.Y.;Lee, Y.G.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2120-2122
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    • 1999
  • $SF_6$ gas has been widely used the gas insulated transmission line, gas insulated transformer and gas insulated substation and Polyester film used as the turn insulation with other material. $SF_6$ gas has been actively studied in domestic and foreign countries. In general, when dielectric surface electric field exceed any electric field strength on air, corona discharge is occurred from the dielectric surface. This paper presents the insulation strength of turn insulation of $SF_6$-PET film studied under application of AC voltage, constitute of the plane to plane with PET Film. The results obtained in experimental are summarized that Partial Discharge Initial Voltage(PDIV) of turn insulation depend on gas pressure, but Breakdown Voltage(BDV) did not depend on gas pressure.

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