• Korean Chemical Engineering Research
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• 제55권6호
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• pp.837-845
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• 2017

D염색공단의 폴리에스테르 알카리 감량폐수 및 호발폐수가 혼합된 실제 종합염색폐수를 처리하기 위하여 D염색공단의 종합폐수처리장 반송슬러지를 고정한 폐타이어담체를 충전한 재순환 유동상 바이오필터와 소성된 $TiO_2$ 코팅-glass bead를 광촉매담체로 적용한 UV/광촉매반응기를 결합한 재순환 통합시스템을 구축하여 운전하였다. 그 결과로서 재순환 통합시스템의 총 $COD_{cr}$ 제거율과 총 색도 제거율 추이는 각각 약 81% 및 55% 정도를 유지하였다. 이러한 재순환 통합시스템의 총 $COD_{cr}$ 및 총 색도 제거율의 제고효과는 각각 최대 약 7% 및 3%로 평가되었다. 재순환 통합시스템의 유동상 바이오필터 및 광촉매반응공정은 총 제거율에 대한 상대기여도로서 각각 총 $COD_{cr}$ 제거율의 약 94% 및 6%를 처리하고, 총 색도 제거율의 약 86% 및 14%를 처리하였다. 이와 같이 재순환 통합시스템의 광촉매반응공정에서는 총 제거율에 대한 색도 제거율의 상대기여도가 $COD_{cr}$ 제거율의 상대기여도보다 약 2.4배 정도 컸다. 따라서 본 연구의 재순환 통합시스템에서 광촉매반응공정은 $COD_{cr}$ 제거보다 아조결합과 같이 염료에서 색을 나타내는 화학결합을 깨는 역할에 더욱 효율성이 있었다. 또한 본 연구의 재순환 통합시스템에서 각 단위공정들의 $COD_{cr}$ 및 색도 제거율이, 재순환 통합시스템의 총 $COD_{cr}$ 및 색도 제거율에 미치는 영향에 대한 모델식과 대수적 상관관계를 구하고 분석하였다.

• 한국염색가공학회지
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• 제18권1호
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• pp.33-43
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• 2006

The purpose of this study was to eximine the effect of different yam twisting methods on mechanical properties and 3D CAD images of plain knitted fabrics made of composite yarns. Six yams were used in this study: four different composite yams of the six consist of acetate and functional polyester (Poly-m) with the ratio of 70:30, and the rest two are the original acetate $100\%$ yam and the poly-m $100\%$ yarn. The four kinds of composite yarns were processed in combinations of twisting processes such as interlacing, false twisting, two for one twisting, combined twisting and single covering, and the two original yams were knitted without any twisting process. Sixteen mechanical properties of all the six knitted fabrics, knitted under the same knitting conditions, were measured by KES-FB system with the outer knit condition. The results were as follows; 1) When the sample applied with the false twisting process at the temperature as high as $220^{\circ}C$, ENT, B, HB, G and RC values of samples increased which leads to increasing dimensional stability. 2) To gain the high bending and shear properties in the single covering process, selecting the core yarn with such properties is the most important factor. 3) Interlacing process effected to increase RC value. 4) False twisting process after interlacing process gave bulkiness and un-interlaced part in yam was increased SMD value. The SMD value of the kilted fabric of the composite yarn, which was put through the combined twist process, was higher than those of which simple process such as the two for one twist or the single covering process applied. In order to achieve the silk-like surface feel of knitted fabric, the sin91e covering process is recommended. 5) Examining the simulation images of the knifed fabrics of composite yarn, which were generated by the 3D CAD system based on the mechanical properties of the fabric, led that appearance could be changed as different twisting methods were applied.

• 감성과학
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• 제7권4호
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• pp.25-33
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• 2004

본 연구에서는 경사와 위사의 장력에 기인되는 감성 봉제용 직물의 마찰특성을 KES-FB 계측기를 이용하여 분석하였다. 직물의 마찰특성은 직물표면의 마찰계수, 마찰계수의 평균편차, 그리고 표면요철도를 측정하였다. 이들 표면특성치를 분석하기 위해서 75d/36f PET 필라멘트를 경사로 사용하고 100d/192f PET 필라멘트를 위사로 사용하여 5매 주자직 직물을 Omega와 Picanol 직기에서 각각 제직하고 이들을 같이 연결하여 염색가공 공정을 진행시켰다. 이들 가공된 직물의 직물표면특성은 제직시 측정된 경사와 위사의 장력특성과 함께 분석되어 졌으며 직물의 중앙부위와 양 셀베지 부분의 직물 위치에 따른 표면특성의 차이가 분석되어졌다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제44차 학술발표회
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• pp.85-85
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• 2011

화학적 혹은 생물학적인 방법으로 합성된 생분해성 고분자(biodegradable polymers)는 환경 문제와 인간의 생명 유지와 같은 인간 생활과 밀접한 관계가 있는 적용 분야로 인해 많은 관심을 받고 있으며, 국내 플라스틱의 폐기량만 해도 2003년을 기준으로 연간 4,000톤을 쉽게 넘고 있고 재활용되는 양은 전체의 1/3 수준이며, 나머지 2/3는 소각되거나 매립되고 있다. 폴리에스테르계 생분해성 섬유는 "미생물이 분비하는 효소로, 분해 가능한 화학합성 섬유"로서, 미생물이 분비하는 가수분해 효소에 의해 고분자 쇄가 절단, 저분자량 화합물이 돼 미생물의 체내로 흡수되며, 이것이 미생물의 체내에서 효소작용에 의해 산화탄소와 물로 분해되는 섬유로 정의된다. 생분해성 고분자 중 화학합성 고분자인 지방족 폴리에스테르계 생분해성 고분자는 특히 환경 산업으로부터 많은 관심을 받고 있으며, 이러한 결정성 폴리에스테르계 고분자의 물성은 고분자의 결정화도 뿐만 아니라, 압력, 온도 등에 의해서 변할 수 있는 결정 구조에 의해 크게 영향을 받는다. 생분해성 섬유는 실용화가 이미 시작됐고, 다용도화와 수요 확대를 위해 많은 연구소와 대학, 기업들이 연구개발을 진행하고 있으며, 향후 석유자원이 고갈된다는 것은 명백한 사실이므로 이에 따라 화석자원의 절약과 유효 이용을 위해서라도 바이오 베이스 폴리머를 주원료로 한생분해성 섬유의 개발은 매우 중요한 의미를 갖는다. 본 연구에서는 합성섬유 중에서 75%의 비중을 차지하는 폴리에스테르를 대체 가능한 고내열생분해성 폴리에스테르계 직물을 제조하여 범용 폴리에스테르와 염색온도에 대한 염색성을 고찰하였다. 염색온도($100^{\circ}C$, $110^{\circ}C$, $120^{\circ}C$, $130^{\circ}C$)별, 3종의 분산염료의 농도(0.25,0.5,1.0,2.0%o.w.f)별 Build-up성 및 균염성을 비교하였으며, 염색 시료의 견뢰도를 평가하였다.

• 한국의류학회지
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• 제31권11호
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• pp.1611-1620
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• 2007

The precaution to spray with agricultural chemicals is very important, in particular personal protective equipment against pesticide in order to protect farmers# pesticide poisoning. The Ministry of Agriculture and Forestry has proclaimed the announcement of pesticide proof clothing(PPC) in 1983, and revised it in 1987. The announcement had many performance items to achieve the high-quality protective clothing for pesticide including weight, density, force strength, dimensional change(in washing and drying), fastness(dyeing, washing, sweating and rubbing) and water resistance of clothes. Announcement of the PPC has better durability and penetration resistance function than former days, but the plenty of farmers didn#t wear it because of the intolerable heat. To increase wearing rates, the pesticide proof clothing must be estimated the water-vapour resistance. From the results, the developed PPC with polyester treated water-repellent showed the more excellent comfort than an existing PPC with nylon coated polyurethane. But the developed PPC appeared to have the low water-vapour resistance. Therefore, it is suggested that the property of pesticide penetration must be evaluated through the field test in the future study.

• 한국염색가공학회지
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• 제21권1호
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• pp.38-45
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• 2009

First of all, the properties imparted to PET fabrics are resistance to and recovery from creasing or wrinkling when wet or dry; high resistance to stretch in the filament yarns but not in the staple; high abrasion resistance; good texture and appearance; resistance to heat ageing; good chemical resistance and good resistance, behind glass, to sunlight. But, the low moisture regain of PET fabric conduces to static troubles in textile processing. Furthermore, garments made from PET may, during wear, develop electric charges which attract to the fabric particles of soil(dirt, swarf, dust) flying in the air, so that the cuffs of shirts, for example, become soiled quickly and are not easily laundered clean. The sericin constitutes 25$\sim$30％ of silk protein and surrounds the fibroin fiber with sticky layer that supports the formation of a cocoon. The useful biochemical properties of sericin protein are oxidation resistant, antibacterial, UV resistant, hydrophilic property, and good affinity with hydrophobic material. These properties can be used as an improving reagent or a coating agent for natural and synthetic fibers, fabrics, and other intermediate products. The sericin is also applied to cross-link, and can be blended with other materials. In this study, we modified the surface of PET fabric by mixture of sericin finishing agent; sericin, polyuretane binder and 1,2,3,4-butanetetracarboxylic acid (BTCA) cross-link agent. Also, we investigated the finshing effect; moisture regain, stiffness, handle, drape and electrostatic. The moisture regain of PET fabric treated with sericin finishing agent was higher than that of untreated PET fabric. As a result of evaluating influence about handle of PET fabrics treated with sericin finishing agent, it was confirmed that the sericin finishing agent could be use as a linen like finishing agent.

• 한국염색가공학회지
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• 제8권3호
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• pp.36-51
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• 1996

In order to investigate the degradation behavior of PET fabrics, sodium diethylene glycolate (SDEG)-diethylene glycol (DEG) solutions were prepared and PET fabrics were treated in the solution. The dissolution rate constant and apparent activation energy of the PET fabrics were calculated by Eyring's and Arrhenius's equation respectively and measured dyeing properties, moisture and antistatic properties. Then compared SDEG-treated fabrics with NaOH-treated. The results were as follows; 1. PET fabrics decreased their weight in SDEG-DEG solution, and the decreasing rate showed a linear relationship to the treating time at constant temperature and concentration of SDEG-DEG solution. 2. The dissolution rate constant showed a linear relationship to the concentration of SDEGDEG solution and an exponential relationship to treating temperature. 3. Apparent activation energy of dissolution was 23.45 kcal/mol. 4. The K/S values and the ΔL values of fabrics treated with SDEG-DEG solution are higher and lower respectively than fabrics treated with NaOH. 5. SDEG-DEG solution treatment improved fabric's moisture regain and it reached almost maximum at about 40% weight loss. 6. In the both reagent the light, wet and sublimation fastness of fabrics are similar. 7. SDEG-DEG solution gave more electrical discharge effect to the fabrics than that of NaOH. 8. NaOH treated PET microfiber have crater-like surface, while SDEG-DEG solution give bathochromic effect to the PET microfiber because which has wrinkles on the surface.