• Korean Chemical Engineering Research
• /
• v.59 no.1
• /
• pp.100-105
• /
• 2021

This paper proposes the polydimethylsiloxane (PDMS) blade coating method for fabrication of paper-based analytical device (PAD) that is able to monitor the disease diagnosis and progress without special analytical equipment. The mold that has PAD design is easily modified by using laser cutting technique. And the fabricated mold is used for hydrophobic barrier formation by blade coating. We have optimized the stable formation of PDMS hydrophobic barrier as blade coating condition, which is established by analyzing the structure of the PDMS hydrophobic barrier and change of hydrophilic channel size as thickness of the ink and contact time with the chromatography paper. Based on optimal condition, we demonstrate that PAD as biosensor can apply to detect protein, glucose, and metal ion without special analysis equipment.

• Polymer(Korea)
• /
• v.38 no.2
• /
• pp.138-143
• /
• 2014

${\alpha},{\omega}$-Hydroxypropyl polydimethylsiloxane (HO-PDMS) was prepared by hydrosilylation of hydrogen terminated polydimethylsiloxane with allyl alcohol. Polydimethylsiloxane modified urethane with isocyanate group (PSU) was prepared from cyclic trimer of hexamethylenediisocyanate with HO-PDMS. PDMS modified urethane base resin with acrylic group (PSUA) was prepared from the urethane reaction of PSU with isocyanate group and 2-hydroxyethylmethacrylate. Their structures were characterized using FTIR and NMR. Coating materials were prepared by mixing PSUA, acrylic hardner, photo-initiator, and solvent and coated on PET film to obtain flexible and hard coating film by UV irradiation. Transparency of coating film was 89.7%, contact angle, $88^{\circ}$, and pencil hardness, 3H.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.08a
• /
• pp.279-279
• /
• 2013

We report on the preparation of polydimethylsiloxane (PDMS) coated multi-walled carbon nanotubes (MWNTs) followed by their dispersion in various solvents. To disperse MWNTs without acids of surfactants, which are the commonly used methods, hydrophobic PDMS coating was selected. It was determined that the PDMS coated MWNTs are more dispersed in diverse solvents such as dimethyl formamide (DMF) and acetone than bare MWNTs. In case of DMF solvent, dispersion of MWNT was improved by 40 % upon PDMS-coating of MWNT, which was confirmed by UV/Vis absorption spectroscopy. In this work, the PDMS coated MWNTs dispersed solution was also used for the fabrication of film, which is conductive, transparent and superhydrophobic because of the reduced aggregation and increased water repellency of MWNTs.

• Membrane and Water Treatment
• /
• v.10 no.4
• /
• pp.251-257
• /
• 2019

Fabricating hydrophobic porous membrane is important for exploring the applications of membrane distillation (MD). In the present paper, poly(vinylidene fluoride) (PVDF) hollow fiber membrane was modified by coating polydimethylsiloxane (PDMS) on its surface. The effects of PDMS concentration, cross-linking temperature and cross-linking time on the performance of the composite membranes in a vacuum membrane distillation (VMD) process were investigated. It was found that the hydrophobicity and the VMD performance of the PVDF hollow fiber membrane were obviously improved by coating PDMS. The optimal PDMS concentration, cross-linking temperature and cross-linking time were 0.5 wt%, $80^{\circ}C$, and 9 hr, respectively.

• Membrane Journal
• /
• v.14 no.1
• /
• pp.57-65
• /
• 2004

The effect of porous support layer resistance and PDMS (polydimethylsiloxane) coating thickness on ethylene/nitrogen separation of composite membranes was studied with the model of Pinnau and Wijmans〔1〕. To control the support resistance (or permeance), PES porous membranes were prepared by phase inversion process with various PES/NMP dope concentrations. The thickness of selective PDMS top layer was controlled by using a spin coater. Its cross-section and coating thickness were observed by scanning electron microscope (SEM). Pure gas permeation test was done with ethylene and nitrogen, respectively. The experimental result for olefin/nitrogen separation process matched well with theoretical result from the model used. The result shows that optimization between PDMS coating thickness and support resistance is important to get PDMS composite membranes with best performance.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.7
• /
• pp.1967-1971
• /
• 2013

Aim of our study is finding adsorbents suitable for pre-concentration of chemical warfare agents (CWAs). We considered Tenax, bare silica and polydimethylsiloxane (PDMS)-coated silica as adsorbents for dimethyl methylphosphonate (DMMP) and dipropylene glycol methyl ether (DPGME). Tenax showed lower thermal stability, and therefore, desorption of CWA simulants and decomposition of Tenax took place simultaneously. Silica-based adsorbents showed higher thermal stabilities than Tenax. A drawback of silica was that adsorption of CWA simulant (DMMP) was significantly reduced by pre-treatment of the adsorbents with humid air. In the case of PDMS-coated silica, influence of humidity for CWA simulant adsorption was less pronounced due to the hydrophobic nature of PDMS-coating. We propose that PDMS-coated silica can be of potential importance as adsorbent of CWAs for their pre-concentration, which can facilitate detection of these CWAs.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2012.02a
• /
• pp.188-188
• /
• 2012

ZnO particles with a size range of 50-150 nm were coated with polydimethylsiloxane (PDMS) with a thin film thickness of 3-4 nm using a simple ambient-pressure chemical vapor deposition methods. Surfaces consisting of the PDMS-coated ZnO nanoparticles were found to be superhydrophobic with a water contact angle higher than $160^{\circ}$. The superhydrophobicity was sustained in the presence of UV light. Photocatalytic activity and photocorrosion of ZnO were nearly completely quenched in the presence of PDMS coating. It is suggested that our PDMS-coating can be of potential interest for the application of ZnO in UV protection agents and energy and electronic devices.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2014.02a
• /
• pp.167.1-167.1
• /
• 2014

We report a facile method to fabricate superhydrophobic, transparent and conductive film using multi-walled carbon nanotubes (MWCNTs) which are coated by polydimethylsiloxane (PDMS). In order to prepare a film, PDMS coated MWCNTs were dispersed in solvents and the solution was drop-casted on substrates. It was demonstrated that the PDMS coating enhanced the dispersion of MWCNTs in diverse solvents such as dimethyl formamide(DMF) and acetone without the use of acids or surfactants, which are the common methods. In the case of DMF solvent, dispersion of MWCNT was improved by 40 % upon PDMS-coating of MWCNT. Enhanced dispersion of MWCNTs made it possible to fabricate transparent and conductive film homogeneously on the substrate and PDMS-coating on MWCNTs also made the surface hydrophobic. We can fabricate a uniform and multifunctional MWCNT film (transparent, conductive, superhydrophobic and flexible) which is applicable on large area without any physical damage and expensive equipment.

• Elastomers and Composites
• /
• v.27 no.4
• /
• pp.267-274
• /
• 1992

Polydimethylsiloxane(PDMS)-containing polyurethane coating materials were synthesized because PDMS-based elastomers have unique properties including an extremely low glass transition temperature, good thermal and oxidative stability, and good dielectric properties. In this experiment a vinyl copolymer which consisted of vinyl chloride, vinyl acetate, vinyl alcohol, and maleic acid was used, and Coronate L was used as a polyisocyanate. PDMS-containing polyurethane was synthesized from polydimethylsiloxane, MDI, and 1,4-butanediol. Films were casted by reaction of viny copolymer, Coronate L, and PDMS-containing polyurethane. Thickness of tile films were $150-170{\mu}m$ and the films were characterized by IR, DSC, and Instron.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2013.02a
• /
• pp.218-218
• /
• 2013

We report a simple and cost-effective method to fabricate transparent superhydrophobic surface on various substrates. The surface was fabricated by coating hydrophobic PDMS (polydimethylsiloxane) film on the silica nanoparticle and subsequent fixing of the hydrophobic silica nanoparticles onto substrates. The water contact angle for the prepared surface was determined to be over $150^{\circ}$, whichindicates that the surface is highly repellent to water. The hierarchical structure and roughness of the surface were examined by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Additionally, transparency of the prepared surface was measured with UV-VIS spectrometer. The transmittance of the superhydrophobic surface was ~80%, which is lower than that without PDMS-coated silica by only 5 to 10%. It is also notable that the superhydrophobic surface fully recovers its original transmittance after self-cleaning process. Also the PDMS coating is stable under a wide range of pH conditions, UV radiation and salinity conditions, which is essential for the practical use. Moreover, our fabrication method is applicable in large scale production.