• 제목/요약/키워드: Polarization of water

검색결과 358건 처리시간 0.032초

응축수 중에서 가스보일러용 STS 304의 부식거동에 관한 연구 (The Study on the Corrosion Behavior of STS 304 for Gas Boiler in the Condensed Water)

  • 윤병두;임우조;정기철
    • 한국가스학회지
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    • 제9권1호
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    • pp.21-25
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    • 2005
  • 가스보일러용 오스테나이트계 스테인리스강재(STS 304)의 부식거동에 관해 연구하기 위하여, 응축수중에서 전기화학적 부식시험을 수행하여. STS 304의 전기화학적 부식거동을 고찰하였다. 다음과 같은 결론을 얻었다. 1)중성환경인 pH=6.5에서 pH가 낮아질수록 STS 304의 분극저항은 감소하고, 부식전위는 비전위화된다. 2)중성 및 산성환경 중에서 STS 304의 부식반응기구는 음극지배로 판단된다. 3) pH가 중성 환경인 pH=6.5에서 강산성 환경인 pH=0.5로 낮아질수록 STS 304의 부동태 전위영역이 감소하고 부동태유지 전류밀도는 증가하고 있다.

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이중편파 레이더의 홍수예보 활용성 평가 (Assessment of Dual-Polarization Radar for Flood Forecasting)

  • 김정배;최우석;배덕효
    • 한국수자원학회논문집
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    • 제48권4호
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    • pp.257-268
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    • 2015
  • 본 연구에서는 이중편파 레이더 추정강우의 홍수예보 활용성을 평가하였다. 비슬산 강우레이더 100 km 반경 내 AWS (Automatic Weather System) 123개 관측소를 대상으로 레이더 추정강우의 오차를 레이더 반경 및 강우강도의 증가에 따라 평가하였다. 이중편파 레이더 추정강우가 단일편파 레이더 추정강우에 비해 오차가 작은 것으로 확인되었다. 또한, 이중편파 레이더 추정강우의 홍수예보 활용성 평가 및 적용을 위해 유역평균강우량을 산정하여 평가하였다. 평가 결과, 이중편파 레이더 추정강우가 단일편파 레이더 추정강우에 비해 관측치에 유사하게 나타났으며, 강우형태에 관계없이 강우 강도가 강한 부분에서 이중편파 레이더의 정확도가 향상됨을 보였다. 그러나 차등반사도를 통해 산정된 강우는 과대추정되는 경향이 나타났다. 연속형 저류함수모형인 SURR 모형에 적용하여 남강댐 유역에 대한 유출해석을 수행하였다. 이중편파 레이더 추정강우를 통한 유출량이 단일편파 레이더 추정강우에 비해 유출용적오차는 약 12~63%, 첨두유량오차는 약 30~42% 감소하였으며, 평균제곱근오차 또한 감소하는 것으로 나타났다. 또한 이중편파 레이더에 의해 산정된 유역평균강우량을 유출모형에 적용할 경우 AWS 강우로부터 추정된 유출결과보다 더 우수한 경우가 있어 향후 홍수예보 활용 시 예보의 정확도 향상에 기여하리라 판단된다.

LiBr-$H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향 (The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using LiBr-$H_2O$ Working Fluids)

  • 임우조;정기철;윤병두;강성수
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2001년도 추계학술대회 논문집(Proceeding of the KOSME 2001 Autumn Annual Meeting)
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    • pp.92-97
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    • 2001
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using LiBr-$H_2O$ working fluids. In the fresh water and 62 %lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(Cl220T-OL) and Ni-Al bronze was carried out. And Polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: As the experimental temperature increase, the change of corrosion rate of Ni-Al bronze become duller than SS 400 and Cu in 62 % lithium bromide solution. Open circuit potential of SS 400 is less noble than that of Cu and Ni-Al bronze in fresh water, but that becomes noble than Cu and Ni-Al bronze in 62 % lithium bromide solution. The corrosion sensitivity of Ni-Al bronze was controlled than that of Cu and SS 400 in 62% LiBr solution.

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Polarization Behavior and Corrosion Inhibition of Copper in Acidic Chloride Solution Containing Benzotriazole

  • Sang Hee Suh;Youngjoon Suh
    • Corrosion Science and Technology
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    • 제22권3호
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    • pp.137-152
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    • 2023
  • Polarization behavior and corrosion inhibition of copper in acidic chloride solutions containing benzotriazole were studied. Pourbaix diagrams constructed for copper in NaCl solutions with different BTAH concentrations were used to understand the polarization behavior. Open circuit potential (OCP) depended not only on chloride concentration, but also on whether a CuBTA layer was formed on the copper surface. Only when the (pH, OCP) was located well in the CuBTA region of the Pourbaix diagram, a stable corrosion inhibiting CuBTA layer was formed, which was confirmed by X-ray Photoelectron Spectroscopy (XPS) and a long-term corrosion test. The OCP for the CuBTA layer decreased logarithmically with increasing [Cl-] activity in the solution. A minimum BTAH concentration required to form a CuBTA layer for a given NaCl concentration and pH were determined from the Pourbaix diagram. It was found that 320 ppm BTAH solution could be used to form a corrosion-inhibiting CuBTA layer inside the corrosion pit in the sprinkler copper tube, successfully reducing water leakage rate of copper tubes. These experimental results could be used to estimate water chemistry inside a corrosion pit.

Mg 합금유전양긍에 의한 온수보일러의 음극방식거동에 관한 연구 (Study on the Cathodic Protectioin Behavior of Hot Water Boiler by Mg-Alloy Galvanic Anode)

  • 정기철
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2000년도 춘계학술대회 논문집(Proceeding of the KOSME 2000 Spring Annual Meeting)
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    • pp.115-121
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    • 2000
  • As the development of industry water quality of river is going to bad because of waste water of an industrial complex and general home agricultural chemicals exhaust of $SO_3$ and CO gas acid rain and so on. Corrosion damage of boiler factory equipment and so forth occur quickly due to using of the polluted water resulting in increasing leak accident. Especially working life of hot water boiler using the polluted water becomes more short and energy loss increases. The cathodic protection method is the most economical and reliable one to prevent corrosion damage of steel structures. Mg-base alloys galvanic anode protection of cathodic protection method is suitable for than application of hot water boiler using water with high specific resistance such as tap water. This paper is studied on the cathodic protection characteristics of how water boiler. In tap water and 0.001mol/$\ell$ NaCl solution the characteristics of anodic polarization of Mg-base alloys galvanic anode and tube material is investigated the measurement of cathodic protection potential according to the time elaspsed is carried out.

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Water level fluctuations of the Tonle Sap derived from ALOS PALSAR

  • Choi, Jung-Hyun;Trung, Nguyen Van;Won, Joong-Sun
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2008년도 International Symposium on Remote Sensing
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    • pp.188-191
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    • 2008
  • The Tonle Sap, Cambodia, is a huge lake and periodically flooded due to monsoon climate. The incoming water causes intensive flooding that expands the lake over vast floodplain and wetland consisting mainly of forests and shrubs. Monitoring the water-level change over the floodplain is essential for flood prediction and water resource management. A main objective of this study is flood monitoring over Tonle Sap area using ALOS PALSAR. To study double-bounce effects in the lake, backscattering effect using ALOS PALSAR dual-polarization (HH, HV) data was examined. InSAR technique was applied for detection of water-level change. HH-polarization interferometric pairs between wet and dry seasons were best to measure water level change around northwestern parts of Tonle Sap. The seasonal pattern of water-level variations in Tonle Sap studied by InSAR method is similar to the past and altimeter data. However, water level variation measured by SAR was much smaller than that by altimeter because the DInSAR measurement only represents water level change at a given region of floodplain while altimeter provides water level variation at the central parts of the lake.

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해양환경 중에서 Glass Flake 라이닝 강재의 부식방지에 관한 연구 (A Study on the Corrosion Control of Glass Flake Lining for Mild Steel in Marine Environment)

  • 임우조;김성훈
    • 수산해양교육연구
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    • 제12권2호
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    • pp.164-175
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    • 2000
  • Port facilities and marine structures used in marine environment were encountered to corrosion damages because of the influence of Cl-. Generally, to protect these accidents, anti-corrosion paint and epoxy coating have been used. But they were still remained erosion-corrosion damage like impingement erosion, cavitation erosion and deposit attack. It is necessary to develope the new composite lining material in order to protective those corrosion damages. In this paper, polyester glass flake, vinylester glass flake lining and epoxy coating for SS400 were investigated by the electrochemical polarization test and the impingement-cavitation erosion test for corrosion behaviour under the sea water. The main results obtained are as follows ; 1) Epoxy coating appear potentiodynamic polarization behaviour, but polyester glass flake and vinylester glass flake lining do not appear potentiodynamic polarization behaviour. 2) Open circuit potential of polyester glass flake lining is more noble than that of epoxy coating and corrosion current density of polyester glass flake lining is less drained than that of epoxy coating in sea water. 3) Open circuit potential of vinylester glass flake lining is more noble than that of polyester glass flake lining and corrosion current density of vinylester glass flake lining is less drained than that of polyester glass flake lining in the sea water.

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스프링클러 동배관의 공식부식 발생원인 (Investigation on Causes of Pitting Corrosion in Sprinkler Copper Tubes)

  • 이재봉;정호석
    • Corrosion Science and Technology
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    • 제13권1호
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    • pp.6-14
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    • 2014
  • Copper metal is widely used in tubes installed in sprinkler water services because of its excellent corrosion resistance. Copper corrosion is considered to be insignificant in water system and the incident of copper pipeline failure is relatively low. However, pitting corrosion is a major problem with all copper tubes. In this study, leaked sprinkler copper tubes were collected from three different locations and examined on the causes of pitting corrosion of copper tubes in sprinkler water plumbing systems. Electrochemical tests such as potentiodynamic polarization, as well as surface and chemical analyses were performed. Results show that pitting corrosion of copper tubes were found as Type I pitting that the carbon film formed on the copper tubes have a harmful effects, causing the pinhole failure in the pipe and resulting in leakage of water. The contermeasures on Type I pitting corrosion of copper tubes were proposed.

동 도금 수세 폐수로부터 구리 분말 제조에 관한 연구 (A Study on the Manufacture of the Cu Powder from Electrochemical Recovery of Waste Rinse Water at the Cu Electroplating Process)

  • 김영석;한성호
    • 한국표면공학회지
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    • 제36권2호
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    • pp.194-199
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    • 2003
  • Polarization measurements were peformed to investigate the electrochemical behavior of copper ions and limiting current density in waste rinse water from copper electroplating processes. A newly designed cyclone type electrolyzer was tested to recover the copper powder. Synthetic solutions were prepared using analytical grade $CuSO_4$ to the desired waste water concentration and pH was adjusted with $H_2$$SO_4$. Electrowinning was peformed at room temperature and the solution was cycled with a pump. Results showed that more than 99 percent of Cu was recovered and the size of the recovered Cu powder ranges from 0.1 - $0.5\mu\textrm{m}$. The chemical composition of the Cu powder mainly consists of $Cu_2$O and Cu and can be easily reduced to pure Cu powder.

분극저항에 의한 온라인 부식속도 측정 시스템에 관한 연구 (Study on an On-line Measurement System of Corrosion Rate by Linear Polarization Resistance)

  • 문전수;이재근;이재봉;박필양
    • Corrosion Science and Technology
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    • 제11권4호
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    • pp.135-140
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    • 2012
  • The linear polarization resistance method is one of the widely used techniques for the corrosion rate monitoring in the water circulating systems of plants. The measurement is simple and rapid, so that a continuous on-line monitoring is possible without any shutdown of plants. A 2-electrode polarization corrosion rate measurement system was installed in a laboratory using a data acquisition board and PC. The signal processing parameters were optimized for the accurate corrosion rate measurement, and the polarization resistance was compensated with the solution resistance measured by the high frequency sine wave signal of an output channel. The precision of corrosion rate data was greatly improved by removing the initial noise signals on measuring the polarization resistance.