• Title/Summary/Keyword: Polarization curve

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Circular Polarization Spectroscopy in ^{87}Rb D_2$ line and Laser Frequency Stabilization (^{87}Rb D_2$ 전이선에 대한 원편광 분광 연구 및 레이저 주파수 안정화)

  • 문한섭;김승일;김현아;김중복;이호성
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.317-323
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    • 1995
  • Doppler-free circular polarization spectroscopy in 87Rb Dz line has been carried out by using a diode laser whose linewidth was narrowed by an external cavity, and experimental results were compared with an optical pumping polarization spectroscopy theory. A dispersive spectrum obtained in a weak pump beam was completely fitted to a single cycle optical pumping theory. The laser frequency was locked to a Rb atomic hyperfine transition line without any frequency modulation by using the dispersive curve as an error signal. ignal.

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Corrsion of Ni-Ze Electrodeposited Alloy (아연-니켈합금 전기도금층의 부식특성)

  • 예길촌;신현준
    • Journal of the Korean institute of surface engineering
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    • v.21 no.2
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    • pp.39-46
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    • 1988
  • Corrosion behavior of 5-26wt% Ni-Zn electrodeposited alloys was investigated by means of dipping electrochmical polarization measurement and galvanic coupling test. The weight loss and anodic polarization curve of coatings were measured by means of dipping and polarization measurement respectively. The galvanic protection effect of alloy coatings was measured by galvanic coupling test and the surface morpholgy of coatings was observed after corrosion testing. Our findings support thous of previous investigations showing that ${\gamma}$single phase coatings, while galvanic pprotection effect of dual phase coatings improved in comparison with ${\gamma}$single phase coating. The formation of colony in coating of ${\gamma}$and η+${\gamma}$ dual phsae caused the localized corrsion and increased the corrosion rate of the Ni-Zn coating.

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Application of Potential-pH Diagram and Potentiodynamic Polarization of Tungsten

  • Seo, Yong-Jin;Park, Sung-Woo;Lee, Woo-Sun
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.3
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    • pp.108-111
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    • 2006
  • The oxidizer-induced corrosion state and microstructure of surface passive metal-oxide layer greatly influenced on the removal rate of tungsten film according to the slurry chemical composition of different mixed oxidizers. In this paper, the actual polishing mechanism and pH-potential equilibrium diagram obtained from potentiodynamic polarization curve were electrochemically compared. An electrochemical corrosion effect implies that slurries with the highest removal rate (RR) have the high dissolution rate.

Corrosion Resistance of the Roll Formed Steel Bolts with the Various Types of Coating Methods (1) (다양한 코팅 방법에 따른 전조한 강 볼트의 내부식성 (1))

  • Mamatov, S.;Hamrakulov, B.;Son, Y.H.;Kim, I.
    • Transactions of Materials Processing
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    • v.28 no.2
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    • pp.71-76
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    • 2019
  • Corrosion resistance is one of the essential properties required in steel bolts. The various types of coatings are used to improve the corrosion resistance of steel bolts. But, roll formed, subsequently Zn alloy electrodeposited and top coated steel bolt easily takes place the white storage stain or white rust under high humidity condition. To investigate the corrosion resistance of roll formed and subsequently the various types of coated steel bolts, their polarization curves were measured by potentio-dynamic tester in this study. Based on the measured polarization curves, the more times of chromate and top coating on roll formed steel bolt, the higher corrosion resistance was shown. The roll formed steel bolt, which was Zn-Ni electro-deposited, two times chromated, one time inorganic top coated, one time organic top coated and annealed, showed the best corrosion resistance.

Characteristics of Ultra-thin Polymer Ferroelectric Films (초박막 폴리머 강유전체 박막의 특성)

  • Kim, Kwang-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.19 no.4
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    • pp.84-87
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    • 2020
  • The properties of ultra-thin two-dimensional (2D) organic ferroelectric Langmuir-Blodgett (LB) films of the poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] were investigated to find possible applicability in flexible and wearable electronics applications. In the C-V characteristics of the MFM capacitor of 2-monolayer of 5 nm films, a butterfly hysteresis curve due to the ferroelectricity of P(VDF-TrFE) was confirmed. Typical residual polarization value was measured at 2μC/㎠. When the MFM capacitor with ultra-thin ferroelectric film was measured by applying a 10 Hz bipolar pulse, it was shown that 65% of the initial polarization value in 105 cycles deteriorated the polarization. The leakage current density of the 2-monolayer film was maintained at about 5 × 10-8 A/㎠ for the case at a 5MV/cm electric field. The resistivity of the 2-monolayer film in the case at an electric field at 5 MV/cm was more than 2.35 × 1013 Ω·cm.

Effect of Gas Diffusion Layer Property on PEMFC Performance (기체확산층 물성이 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.31 no.5
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    • pp.568-574
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    • 2020
  • Gas diffusion layer (GDL) is one of the main components of PEMFC as a pathway of reactants from a flow field to an electrode, water transport in reverse direction, heat management and structural support of MEA. In this study, the effect of GDL on fuel cell performance was investigated for commercial products such as 39BC and JNT30-A3. Polarization curve measurements were performed at different flow rates and relative humidity conditions using 25 ㎠ unit cell. The parameters on operating conditions were calculated using an empirical equation. The electrical resistance increased as the GDL PTFE content increased. The crack of microporous layer had influence on the concentration loss as water pathway. In addition, the ohmic resistance increased as the relative humidity decreased, but decreased as the current density increased due to water formation. Curve fitting analysis using the empirical equation model was applied to identify the tendency of performance parameters on operating conditions for the gas diffusion layer.

Switching Dynamics Analysis by Various Models of Hf0.5Zr0.5O2 Ferroelectric Thin Films (Hf0.5Zr0.5O2 강유전체 박막의 다양한 분극 스위칭 모델에 의한 동역학 분석)

  • Ahn, Seung-Eon
    • Korean Journal of Materials Research
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    • v.30 no.2
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    • pp.99-104
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    • 2020
  • Recent discoveries of ferroelectric properties in ultrathin doped hafnium oxide (HfO2) have led to the expectation that HfO2 could overcome the shortcomings of perovskite materials and be applied to electron devices such as Fe-Random access memory (RAM), ferroelectric tunnel junction (FTJ) and negative capacitance field effect transistor (NC-FET) device. As research on hafnium oxide ferroelectrics accelerates, several models to analyze the polarization switching characteristics of hafnium oxide ferroelectrics have been proposed from the domain or energy point of view. However, there is still a lack of in-depth consideration of models that can fully express the polarization switching properties of ferroelectrics. In this paper, a Zr-doped HfO2 thin film based metal-ferroelectric-metal (MFM) capacitor was implemented and the polarization switching dynamics, along with the ferroelectric characteristics, of the device were analyzed. In addition, a study was conducted to propose an applicable model of HfO2-based MFM capacitors by applying various ferroelectric switching characteristics models.

Electroplating on the Lead Frames Fabricated from Domestic Copper Plate (국산동판을 사용한 리드프레임 도금기술에 관한 연구)

  • Jang, Hyeon-Gu;Lee, Dae-Seung
    • Journal of the Korean institute of surface engineering
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    • v.19 no.3
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    • pp.92-108
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    • 1986
  • An electroplating on the lead frame fabricated from domestic copper plate was studied experimentally. In this study, nickel was plated on the thin copper lead frame and silver layer was coated on the nickel film in the cyanide electrolyte. The effect of process variables such as current density, plating time, coating thickness and flow rate of electrolytic solution on the properties of coating was investigated. Some samples on each step were fabricated during electroplating. The results obtained from polarization measurement, observation of SEM photograph, adhesion test of coating and microhardness test are as follows. On silver plating, polarization resistance of potentiostatic cathodic polarization curve is reduced as the flow rate of Ag electrolytic solution increases. And above resistance is also reduced when the minor chemicals of sodium cyanide and sodium carbonate are added in potassium silver cyanide bath. The reduced polarization resistance makes silver deposition on the cathode easy. An increase in the current density and the coating thickness causes the particle size of deposit to coarsen, and consequently the Knoop microhardness of the coating decreases. On selective plating an increase in the flow rate of plating solution lead to do high speed plating with high current density. In this case, the surface morphology of deposit is of fine microstructure with high Knoop hardness. An increasing trend of the adhesion of coating was shown with increasing the current density and flow rate of electrolytic solution.

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Implementation of Fuel Cell Simulator for Ship Using the Programmable Power Supply (전력공급장치를 이용한 선박용 연료전지 시뮬레이터의 구현)

  • Park, Do-Young;Oh, Jin-Seok
    • Journal of Advanced Marine Engineering and Technology
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    • v.36 no.8
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    • pp.1117-1122
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    • 2012
  • In order to study to apply the fuel cell, the study about the power system design and the load control is needed. However, to experiment the fuel cell need the auxiliary device and the complex control technology. For this reason the simulator is needed and such study is in progress actively. In this paper, the PEMFC (Polymer Electrolyte Membrane Fuel Cell) that is applied the vehicle, the small sized ship was simulated based on LabVIEW. The characteristic of fuel cell simulator was implemented based on a simulation data using the programmable power supply. The I-V characteristic according to various factors and the polarization curve of fuel cell were analysed.

A Study on Corrosive Behavior of Spring Steel by Shot-Peening Process (쇼트피닝 가공을 통한 스프링강의 부식거동에 관한 연구)

  • An, Jae-Pil;Park, Keyung-Dong
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.325-330
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    • 2004
  • Recently, the request for the high strength of material is more and more increased in the area of industrial environment and machinery. To accomplish the high strength of materials, carbonizing treatment, nitrifying treatment, shot-peening method are representatively applied, however, shot-peening method is generally used among the surface processes. Shot peening is a cold working process used to impact Compressive residual stressed in the exposed surface layers. Benefits due to shot peening are increase in resistance to fatigue, stress corrosion cracking, fretting, galling, erosion and closing of pores. In this study, the influence of shot peening on the corrosion was investigated on spring steel immersed in 3.5% NaCl. The immersion test as performed on the two kinds of specimens. Corrsion potential, polarization curve, residual stress and etc, were investigated from experiment results. From test result the effect of shot peening on the corrosion was evaluated. The important results of the experimental study on the effects of shot peened on the environment corrosion of spring steels are as follows; In case of corrosion potential, shot peened specimen shows more activated negative direction as compared with parent mental. Surface of specimen, which is treated with the shot peened is placed as more activated state against inner base metal. It can cause t도 anti-corrosion effect on the base metal.

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