• 제목/요약/키워드: Polarization analysis

검색결과 756건 처리시간 0.03초

광변형 고분자의 동적 진동에 관한 멀티스케일 해석 (Multiscale Analysis on Vibration of the Photo Responsive Polymer)

  • 윤정훈;;정하영;최준명;조맹효
    • 한국전산구조공학회논문집
    • /
    • 제29권6호
    • /
    • pp.571-575
    • /
    • 2016
  • 광변형 고분자(PRP)는 PRP 내부에 함유된 아조벤젠(azobenzene)의 광이성질화 현상에 의해 자외선을 받을 경우 수축을 하고, 이 상태에서 적외선을 받을 경우 원래대로 돌아오는 성질을 가지고 있다. 본 논문에서는 PRP의 진동 현상에 대한 동적해석이 논의된다. PRP의 광변형 양상을 예측하기 위해 양자역학, 고분자역학, 연속체 역학을 아우르는 멀티스케일 모델링 기법이 제안된다. PRP의 동적 진동 양상을 예측하기 위해 간단한 1D 빔 모델이 사용되었으며, FFT기법을 통해 진동 주파수 해석이 진행된다. 해석 결과 빛의 입력에 따른 PRP의 진동 양상은 빛의 편광 방향에 영향을 받는다는 것을 알 수 있다.

원자력발전소용 316 스테인리스강 배관의 부식특성에 미치는 유도가열벤딩공정의 영향 (Effect of Induction Heat Bending Process on the Corrosion Properties of 316 Stainless Steel Pipes for Nuclear Power Plant)

  • 신민철;김영식;김경수;장현영;박흥배;성기호
    • Corrosion Science and Technology
    • /
    • 제13권3호
    • /
    • pp.87-94
    • /
    • 2014
  • Recently, the application of bending products has been increased since the industries such as automobile, aerospace, ships, and plants greatly need the usage of pipes. For facility fabrication, bending process is one of key technologies for pipings. Induction heat bending process is composed of bending deformation by repeated local heat and cooling. Because of local heating and compressive strain, detrimental phases may be precipitated and microstructural change can be induced. This work focused on the effect of induction heat bending process on the properties of ASME SA312 TP316 stainless steel. Evaluation was done on the base metal and the bended areas before and after heat treatment. Microstructure analysis, intergranular corrosion test including Huey test, double loop electropotentiokinetic reactivation test, oxalic acid etch test, and anodic polarization test were performed. On the base of microstructural analysis, grain boundaries in bended extrados area were zagged by bending process, but there were no precipitates in grain and grain boundary and the intergranular corrosion rate was similar to that of base metal. However, pitting potentials of bended area were lower than that of the base metal and zagged boundaries was one of the pitting initiation sites. By re-annealing treatment, grain boundary was recovered and pitting potential was similar to that of the base metal.

VOIDS LENSING OF THE CMB AT HIGH RESOLUTION

  • SANGKA, ANUT;SAWANGWIT, UTANE;SANGUANSAK, NUANWAN
    • 천문학논총
    • /
    • 제30권2호
    • /
    • pp.397-399
    • /
    • 2015
  • Recently, cosmic voids have been recognized as a powerful cosmological probe. A number of studies have focused on the effects of the gravitational lensing by voids on the temperature (and in some cases polarization) anisotropy of the Cosmic Microwave Background (CMB) background at relatively large to medium scales, l ~ 1000. Many of these studies attempt to explain the unusually large cold spot in CMB temperature maps and dynamical evidence of dark energy via detections of late-time integrated Sachs Wolfe (ISW) effect. Here, the effects of lensing by voids on the CMB temperature anisotropy at small scales, up to l = 3000, will be investigated. This work is carried out in the light of the benefits of adding large catalogues of cosmic voids, to be identified by future large galaxy surveys such as EUCLID and LSST, to the analysis of CMB data such as those from Planck mission. Our numerical simulation utilizes two methods, namely, the small-de ectionangle approximation and full ray-tracing analysis. Using the fitted void density profiles and radius (RV ) distribution available in the literature from N-body simulations, we simulated the secondary temperature anisotropy (lensing) of CMB photons induced by voids along a line of sight from redshift 0 to 2. Each line of sight contains approximately 1000 voids of effective radius $RV_{,eff}=35h^{-1}Mpc$ with randomly distributed radial and projected positions. Both methods are used to generate temperature maps. The two methods will be compared for their accuracy and effciency in the implementation of theoretical modeling.

리튬이온전지의 유기용매분해에 따른 SEI film형성과 전기화학적 거동에 관한 연구 (A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior)

  • 김민성;구할본
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
    • /
    • pp.545-549
    • /
    • 2001
  • We have produced electrolyte solution out of 1.15M LiPF$\sub$6/ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M LiPF$\sub$6/DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M LiPF$\sub$6/ EC/DEC(1/2 by vo%%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC, DMC and EMC brought the de-decomposition peak of salt anion of PF$\sub$6/$\^$-/ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. Li/Li$\^$+/\`). In addition, a kinetics current peak, in which intercalation of Li$\^$+/ is proceeded at 750mv, 450mv(vs. Li/Li$\^$+/), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance(R$\sub$ct/) according to the electric potential of Li$\^$+/ intercalation at 750mv(vs. Li/Li$\^$+/), which was the same as the resistance (R$\sub$f/) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance(R$\sub$p/) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

  • PDF

저소득층 대학생들의 진로준비과정에서의 성별·전공별 특성에 대한 사례연구: 텍스트 빈도분석과 연관분석의 적용 (A Case Study on Characteristics of Gender and Major in Career Preparation of University Students from Low-income Families: Application of Text Frequency Analysis and Association Rules)

  • 이지혜;이신혜
    • 디지털융복합연구
    • /
    • 제16권12호
    • /
    • pp.61-69
    • /
    • 2018
  • 이 연구는 청년들의 높은 비정규직 비율과 계층 양극화의 우려 속에서 저소득층 대학생의 진로준비과정에 대해 이해하고 시사점을 구하기 위한 것이다. 이를 위하여 S 장학재단에서 장학금 지원을 받는 13명의 대학생들을 연구 대상으로 선정하였고, 6회의 인터뷰를 진행하여 그 축어록을 바탕으로 텍스트마이닝 기법을 활용한 분석을 실시하였다. 분석 결과, 대학생들은 인터뷰 과정에서 이전의 학업 경험을 회상하거나 진로를 설계할 때, 가정환경과 소득수준의 영향을 받는 것으로 보이며, 이러한 차이는 성별, 전공별로 다른 특성이 있는 것으로 나타났다. 이 연구는 질적 연구 방법으로 축적된 자료에 텍스트마이닝 기법을 융합적으로 적용하여 분석한 연구로 종래의 진로연구에 비하여 방법론적 확장을 시도했다는 의의를 갖고 있다. 그 결과, 저소득층 대학교 장학생들의 성별 및 전공별 진로준비과정의 차이를 대학생활 및 진로준비와 관련된 단어들의 관계를 통해 탐색적으로 살펴볼 수 있었다.

사회경제적 수준과 구강건강과의 관련성 연구: 제6기 국민건강영양조사 자료를 이용하여 (A study on the relationship between socioeconomic level and oral health: analysis of data from the Sixth Korean National Health and Nutritional Examination Survey)

  • 송애희;윤혜정
    • 한국치위생학회지
    • /
    • 제19권4호
    • /
    • pp.565-575
    • /
    • 2019
  • Objectives: In this study, both subjective and objective levels of oral health were used to identify the relationship between oral health inequalities. Methods: Korean National Health and Nutritional Examination Survey data from 2013 to 2015 were combined to create an analysis plan. Oral health questions categorized as subjective oral health conditions and oral health-related diseases used dental tissue disease status as data measured by the Community Periodical Index(CPI) and decayed, missing, filled teeth(DMFT) experience. Other data on oral health behaviors such as toothache experience, the frequency of toothbrush use, chewing problems, oral examination status, and unmet dental care needs were classified and analyzed according to the socioeconomic level. Data were analyzed using frequency and cross analyses, and the statistical significance level was set at 0.05. Results: It was found that higher the economic and educational level, better was the subjective oral health, lower the CPI, lower the experience of toothache, higher the frequency of toothbrush use, lower the number of people having chewing problems, and higher the frequency of oral checkups. Conclusions: Oral health inequality exists among social classes. It is suggested that continuous research and efforts be carried out to promote oral health while considering socioeconomic and educational levels. Further, active government efforts will be needed to address polarization by social class.

A Research on Industrial Trend Analysis of Materials & Components in Jeollanam-do

  • 정중채;김은이;김성민;박성현;이용상
    • 고무기술
    • /
    • 제22권2호
    • /
    • pp.119-149
    • /
    • 2021
  • Domestic materials & components industry is making a shift from quantitative growth to qualitative growth, while the paradigm of a future society is changing rapidly to energy, mobility, smartification and etc. The main features of materials & components industry are analyzed broadly based on three aspects that are: ① industry Status, ② the value chain structure, ③ the competitiveness. With regard to the national aspect, it is shown that the number of an export and a trade surplus increased consistently after the government advanced the policy on materials & components and Korea's trade deficit with Japan has been decreased. Moreover, the state's export ranking increased from tenth place in 2001 into sixth place in 2017, dedicating to the growth of a national economy. The analysis of the chain value indicates that specifications of an end product are set when the materials & components are combined with manpower, infrastructure and technologies. In terms of the competitiveness, it requires a long time and high costs to develop technologies on materials and it is important for components to have a process innovation and credibility wired. Following the industry structure with priority given on materials, Jeonnam Province accounts for 14.8% of national material production. As a result of analyzing Jeonnam's export competitiveness, it is measured that a serious polarization exists, revealing there are 6 major technology industries by 11 categories for materials & components, Jeonnam has presented 6 major materials & components considering the key industry and the new industry in future to remedy the mentioned problem so far, and plans to knock on the industry development through 10 different strategies.

고온 고분자 막 전해질 연료전지 캐소드의 가스 확산층 및 바인더 함량에 따른 완화 시간 분포(DRT) 저항 분석 (Resistance Analysis by Distribution of Relaxation Time According to Gas Diffusion Layers and Binder Amounts for Cathode of High-temperature Polymer Electrolyte Membrane Fuel Cell)

  • 김동희;정현승;박찬호
    • 한국수소및신에너지학회논문집
    • /
    • 제34권3호
    • /
    • pp.283-291
    • /
    • 2023
  • The physical properties were analyzed for four gas diffusion layers, and gas diffusion electrodes (GDEs) for the cathode of high-temperature polymer electrolyte membrane fuel cell were fabricated through bar coating with three binder to carbon (B/C) ratios. Among them, The GDE from JNT30-A6P showed a significant change in secondary pore volume at a B/C ratio of 0.31, which had the largest pore volume among all GDEs. In the polarization curve, JNT30-A6P GDE showed the best membrane electrode assembly (MEA) performance with a peak power density of 384 mW/cm2 at a a B/C ratio of 0.31. From the distribution of relaxation time analysis, the peak 1 corresponding to mass transfer resistance of oxygen reduction reaction (ORR) was significantly reduced in the JNT30-A6P GDE. This is the result that when the binder content decreased, the volume of the secondary pore increased, and the mass transfer resistance of ORR decreased, which played an essential role in the MEA performance.

XAS Studies of Ion Irradaited MgO Thin Films

  • Suk, Jae-Kwon;Gautam, Sanjeev;Song, Jin-Ho;Lee, Jae-Yong;Kim, Jae-Yeoul;Kim, Joon-Kon;Song, Jong-Han;Chae, Keun-Hwa
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
    • /
    • pp.312-312
    • /
    • 2012
  • Magnesium oxide has become focus for research activities due to its use in magnetic tunnel junctions and for understanding of do ferromagnetism. Theoretical investigations on such type of system indicate that the presence of defects greater than a threshold value is responsible for the magnetic behaviour. It has also been shown experimentally that by decreasing the film thickness and size of nanoparticles, enhancement/increase in magnetization can be achieved. Apart from the change in dimension, swift heavy ions (SHI) are well known for creating defects and modifying the properties of the materials. In the present work, we have studied the irradiation induced effects in magnesium oxide thin film deposited on quartz substrate via X-ray absorption spectroscopy (XAS). Magnesium oxide thin films of thickness 50nm were deposited on quartz substrate by using e-beam evaporation method. These films were irradiated by 200 MeV Ag15+ ion beam at fluence of $1{\times}10^{11}$, $5{\times}10^{11}$, $1{\times}10^{12}$, $3{\times}10^{12}$ and $5{\times}10^{12}ions/cm^2$ at Nuclear Science Centre, IUAC, New Delhi (India). The grain size was observed (as studied by AFM) to be decreased from 37 nm (pristine film) to 23 nm ($1{\times}10^{12}ions/cm^2$) and thereafter it increases upto a fluence of $5{\times}10^{12}ions/cm^2$. The electronic structure of the system has been investigated by X-ray absorption spectroscopy (XAS) measurements performed at the high energy spherical grating monochromator 20A1 XAS (HSGM) beamline in the National Synchrotron Radiation Research Center (NSRRC), Taiwan. Oxides of light elements like MgO/ZnO possess many unique physical properties with potentials for novel application in various fields. These irradiated thin films are also studied with different polarization (left and right circularly polarized) of incident x-ray beam at 05B3 EPU- Soft x-ray scattering beamline of NSRRC. The detailed analysis of observed results in the wake of existing theories is discussed.

  • PDF

마약남용자 11명의 타액 중 메스암페타민의 분석 (Analysis of Methamphetamine and Amphetamine in Oral Fluid of Eleven Drug Abusers)

  • 김은미;이주선;최혜영;최화경;정희선
    • 약학회지
    • /
    • 제52권6호
    • /
    • pp.419-425
    • /
    • 2008
  • A qualitative and quantitative analytical method was developed for detection of methamphetamine (MA) and its main metabolite amphetamine (AM) in oral fluid. Oral fluids of eleven drug abusers were provided by Police, specimens were collected by stimulation with a cotton swab treated with 20 mg of citric acid ($Salivette^{(R)}$; Sarstedt, USA). As the preliminary test, oral fluid samples were screened for amphetamines by Fluorescence Polarization Immunoassay (TDxFLx, Abbott Co.). Extraction for MA was performed using solid-phase extraction (SPE) by $RapidTrace^{TM}$ (Zymark, USA) with mixed mode cation exchange cartridge, CLEAN $SCREEN^{(R)}$ (130 mg/3 ml, UCT) after dilution with phosphate buffer. Samples were evaporated and derivatized by pentafluoropropionic acid anhydride (PFPA). Quantitation of MA and AM was performed by gas chromatography-mass spectrometry (GC-MS) using selective ion monitoring (SIM), the quantitation ions were m/z 204 (MA), 208 (MA-$D_5$), 190 (AM) and 194 (AM-$D_5$). The selectivity, linearity of calibration, limit of detection (LOD) and quantification (LOQ) within- and between day precision, accuracy and recoveries were examined as parts of the method validation. All oral fluid samples gave positive results to immunoassay for MA (cut-off level, 50 ng/ml as d-amphetamine). Concentrations of MA and AM by GC-MS in eleven samples were ranged 104.2${\sim}$4603.3 ng/ml and 32.4${\sim}$268.6 ng/ml, respectively. Extracted calibration curves of MA and AM were linear over the two concentration range of 1${\sim}$100 and 50${\sim}$1000 ng/ml with correlation coefficient of above 0.999. LOQ of MA and AM was 1 and 3 ng/ml, respectively. The intraand inter-day run precisions (CV) for MA and AM were less than 10%, and the accuracies (bias) for MA and AM were also less than 10% at the two different concentrations 5 and 100 ng/ml at low calibration range, 50 and 1000 ng/ml at high calibration range. The absolute recoveries of MA and AM at low and high calibration ranges were more than 82% and 75%, respectively. In this study the qualitative and quantitative analytical method of MA in oral fluid was established. Oral fluid testing may detect drug use in past hours because of its shorter detection window than urine, and be useful in post-accident situations. So oral fluids will be most useful for testing drug abuse in the driving under the influence of drug (DUID) as the alternative specimens of urine.