• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2000년도 추계학술대회 논문집
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• pp.178-183
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• 2000

Electrorheological(ER) effect on the dispersive system of polarizable fine powder/dielectric oil has been investigated. The electrical and rheological properties of zeolite and starch based ER fluid were reported. The ER fluids were constructed by mixing zeolite and starch power with two different dielectric oils. Yield stress of the fluids were measured on the couette cell type rheometer as a function of electric fields, particle concetrations, and temperatures. The electric field is applied by high voltage DC power supply. The outer cup is connected to positive electrode(+) and the bob becomes ground(-). And the temperatures the viscosity(or shear stress) versus shear rates were measured. In this experiment shear rates were increased from 0 to $200s^{-1}$ in 2 minutes.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 제39회 하계학술대회
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• pp.1156-1157
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• 2008

The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about 205 $C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}$ = 2.5 V, while the positively charged density became the maximum, about 61.1 $C/m^3$ at the region where it was located around the cathode layer. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2008년도 추계학술대회 논문집
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• pp.201-204
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• 2008

The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about 205 C/$m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}$ = 2.5 V, while the positively charged density became the maximum, about 61.1 C/$m^3$ at the region where it was located around the cathode layer. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

• Transactions on Electrical and Electronic Materials
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• 제8권4호
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• pp.182-187
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• 2007

The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about $205C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}=2.5V$, while the positively charged density became the maximum, about $61.1C/m^3$ at the region where it was located around the cathode layer. The performance of the best sample was found to be better in terms of the charge density (Cs) and specific energy ($E_s$) with a maximum value of ${\sim}8.4F/g$ and 26 Wh/kg. The $C_s$ obtained from the PEA method agreed well with that from the energy conversion method. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

• Bulletin of the Korean Chemical Society
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• 제12권1호
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• pp.93-97
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• 1991

Rate constants have been measured spectrophotometrically for the reactions of alkali metal ethoxides with 4-nitrophenyl benzoate, S-4-nitrophenyl thiobenzoate and 4-nitrophenyl thionbenzoate in ethanol at 25$^{\circ}$C. Substitution of S for O in the leaving group has not affected reactivity significantly, while the effect of the similar replacement in the acyl group has led to rate decrease by a factor of 10, although pronounced rate enhancements have been expected for both systems. The replacement of O by a polarizable S has also influenced the reactivity of the esters toward alkali metal ethoxides, i.e. the reactivity decreases as the size of the metal ion decreases. The alkali metal ions have showed inhibition effect instead of catalytic effect which would have been expected for the present system. The effect of replaced sulfur atom on the reactivity for the present system is attributed to the nature of hard and soft acids and bases.

• Bulletin of the Korean Chemical Society
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• 제16권11호
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• pp.1015-1019
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• 1995

The electronic structures and properties of the neutral and multiply charged C60n ions (n=2+ to 6-) with spin states have been investigated by semi-empirical MNDO calculations. In the ground state, C601- has the lowest total energy and the highest binding energy. The neutral C60 ion is supposed to have a high ionization potential and a high electron affinity. The HOMO and LUMO positions are lower in the cationic C60 than in the anionic C60. The LUMO energy becomes increasingly positive from C601- to C606- and the HOMO energy becomes increasingly negative from C602+ to C60. The HOMO-LUMO gap of the neutral C60 ion is higher than that of the multiply charged C60 ions. From the HOMO-LUMO gap, it seems reasonable to expect that electrons of the multiply charged C60 ions will be more polarizable than those of the neutral C60 ion. The HOMO and LUMO energies increase as the negative charge increases.

• Bulletin of the Korean Chemical Society
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• 제10권6호
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• pp.585-591
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• 1989

The effects of the charged metal on the overall electrostatic potential profiles and the capacitances of the electrical double layer are brought out. A model with a simplified jellium and a point-charged electrolyte is utilized in the present calculations. Electrons are assumed not to penetrate electrode surface due to a strong screening of electrolyte at the interface. Electron density functions and ion density functions are obtained, which are also based upon the Poisson equation and Boltzmann equation on either side of the interface. A complete potential profile starting from bulk electrode and ending at bulk electrolyte is obtained by connecting the two potential profiles (one inside the metal electrode, the other inside the electrolyte) with proper boundary conditions. In spite of the simplicity of the model, the present model reveals the importance of the effect of the charged metal on the electrostatic potential profile and the electrical double layer capacitances. The results are discussed and compared with the predictions by Gouy Chapman theory.

• 지구물리와물리탐사
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• 제10권2호
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• pp.138-146
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• 2007

이 연구에서 복소 전기비저항을 이용한 2차원 IP 모델링 알고리듬과 이를 이용한 역산 알고리듬을 개발하였다. 복소 전기비저항을 이용한 IP 탐사기법은 크기인 전기비저항과 위상정보를 제공함으로써 지하의 수리지질학적인 특성 및 내부 공극수 종류 등 다양한 정보의 제공이 가능하여 활용성이 확대되고 있다. IP 탐사 모델링 및 역산 알고리듬은 기존의 전기비저항 모델링 및 역산 알고리듬을 복소 연산을 포함하도록 확장함으로써 개발되었다. IP 모델링은 유한요소법을 이용한 2.5차원 모델링 알고리듬을, 역산 알고리듬으로는 평활화 제한을 가한 감쇠 최소자승법을 이용하였다. 모델링의 검증에는 슐럼버저 배열에 대하여 3차원 층서모형에 수치필터링을 이용한 1차원 모델링 결과와 비교하였으며, 쌍극자 배열에 대하여 고립이상체 모형에 3차원 적분방정식 IP 모델링 알고리듬과 비교하여 그 타당성을 확인하였다. 역산의 타당성을 확인하기 위하여 전기비저항 및 위상 중 하나는 배경매질과 동일하고 다른 물성 하나만 차이를 가지는 모델에 대하여 역산 실험을 수행하였으며, 전기비저항 및 위상 이상체를 정확히 영상화하고 있음을 확인하였다. 역산의 실제 복잡한 지질모델에의 적용성을 확인하기 위해, 3차원 층서구조 내에 두 번째 층의 일부에 위상 이상체가 존재하는 모형을 설정하여 수치실험을 수행한 결과 전기비저항 단면에서는 이상체가 잘 확인되지 않으나, 위상 단면에서 그 이상체가 명확히 나타나는 것을 확인하였다.

• Archives of Pharmacal Research
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• 제7권1호
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• pp.1-9
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• 1984

Polyethylene glycol 20, 000 and 6, 000 were found to have an upper consolute temperature, called "cloud point", and the effects of various additives on the polythylene glycols were investigated in this study. Electrolytes lowered the cloud point in proportion to their concentrations through dehydration and electrostriction. It was found that anions played a more important role than cations and the effects of both the cations and the anions clearly followed the classical Hofmeister series. However, the Schultze Hardy rule holds for the effect of anions, and fails for the effect of cations. Salts of large polarizable anions such as iodide and thiocynate rather raised the cloud point, and their effects were ascribed to the fact that they break the water structure and weaken hydrophobic bonding of the polyxyethylene moiety. Nitrates of polyvalent cations also raised the cloud point. This was ascribed to the complex formation between the polyvalent cations and ether oxygens of the polyoxyethylenes. This explained the failure 'of the Schultz-Hardy rule for cations. Uncharged aromatic compounds drastically lowered the clound point, while aliphatic alcohols slightly lowered the cloud point, This result suggests that there might be some interaction between ether oxygens and aromatic nucleus.c nucleus.

• Bulletin of the Korean Chemical Society
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• 제32권6호
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• pp.1985-1992
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• 2011

The stable conformers of glycine and the inter-conversions between them were studied theoretically at various levels of theory, B3LYP, MP2, CCSD and CCSD(T), in the gas phase and in aqueous solution. In aqueous solution, the structures examined by use of the conductor-like polarizable continuum model (CPCM) with various cavity models, UA0, UAHF, UAKS, UFF, BONDI and PAULING, and by use of a discrete/continuum solvation model with eight water clusters. The Gibbs free energy differences between the neutral (NE) and zwitterionic conformers (ZW), ${\Delta}G_{Z-N}[=G_{ZW}-G_{NE}]$, in aqueous solution were well reproduced by using the BONDI and PAULING cavity models. However the ${\Delta}G_{Z-N}$ values were underestimated in other cavity models, although the ZW conformers existed as stable species in aqueous solution. In the studies of a discrete/continuum solvation model with eight water clusters, gas phase results are still insufficient to reproduce the experimental findings. However the ${\Delta}G_{Z-N}$ values calculated by use of CPCM method in aqueous solution agreed well with the experimental ones.