• Bulletin of the Korean Chemical Society
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• 제20권11호
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• pp.1263-1268
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• 1999

The fluorescence properties and photoisomerization behavior of 1-(9-anthryl)-2-(2-quinolinyl)ethene (2-AQE) have been investigated in various solvents. Instead of phenyl ring in 1-(9-anthryl)-2-phenylethene, the intro-duction of quinoline ring reduces not only the fluorescence yield but also the photoisomerization yield, due to competition of efficient radiationless deactivation and an increase in the torsional barrier for twisting in the singlet manifold. The S1 decay parameters were found to be solvent-dependent due to the charge-transfer character of lowest S1 state. Polar solvents reduce the activation barrier to twisting, thus slight enhancing the isomerization of t-2-AQE in the singlet manifold. As solvent polarity is increased, Φf of c-2-AQE is greatly reduced, but Φc →ｔ is practically independent of solvent polarity. Dual fluorescence in t-2-AQE was observed and two fluorescing species could be assigned t-2-AQE and c-2-AQE, where the ratio between two species was dependent on the solvent polarity. Interestingly, in the concentration above 1×10 -4 M, the shapes of the fluorescence excitation spectra of t- and c-2-AQE are significantly altered without spectral changes of their fluorescence and absorption, probably due to the formation of excimer.

• 한국멀티미디어학회논문지
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• 제7권5호
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• pp.744-754
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• 2004

본 논문에서는 웨이블릿 계수 변화량을 고려한 극성 기반 블라인드 워터마킹 방법을 제안한다. 제안한 방법에서는 영상을 변형시키는 다양한 공격에서 워터마크 검출력을 높이기 위해 삽입과 검출시에 사용되는 임계치를 달리하여 적용하는 비대칭 임계치 워터마킹을 적용하였다. 또한 워터마크 검출시 계수 값의 작은 변화에 따른 워터마크 검출 값의 오류 현상을 개선하기 위해 계수 값 이동 변화량을 분석하여 이 범위 안에 속하는 계수 변화량은 인정하지 않아 계수 값의 변화 민감성을 둔화시켰다. 이를 위해 극성 유지 임계치 $\beta$를 설정하여 $\beta$ 이상의 차이 값에 대해서만 극성 내용을 토대로 워터마크를 검출하였다. 실험 결과 제안한 방법은 비교적 우수한 화질에서 손실 JPEG 압축, 잡음 첨가, 클로핑, 블러링 등의 공격에 강인함을 알 수 있었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 추계학술대회 논문집 전기설비전문위원
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• pp.93-96
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• 2004

In this paper, we analyzed the current limiting characteristics according to increase of source voltage in the flux-lock type high-Tc superconducting fault current limiter (SFCL). The flux-lock type SFCL consisted of two coils, which were wound in parallel each other through an iron core, and high-Tc superconducting (HTSC) element connected with coil 2 in series. The flux-lock type SFCL has the characteristics better in comparison with the resistive type SFCL because the fault current in the flux-lock type SFCL can be divided into two coils by the inductance ratio of coil 1 and coil 2. The fault current limiting operation of the flux-lock type SFCL can be different due to winding direction of the two coils. The winding method where the decrease of linkage flux between two coils in the accident happens is called the subtractive polarity winding and the winding method in case of the increase of linkage flux is called the additive polarity winding. The fault current limiting experiments according to the source voltage were performed for these two winding methods. Through the comparison and the analysis of the experimental data, we confirmed that the quench time was shorter, irrespective of the winding direction as the source voltage increased and that the fault current and the HTSC's resistance increased as the amplitude of the source voltage increased. The additive polarity winding made the fast quench time and the lower resistance of HTSC element in comparison with the subtractive polarity winding. The fault current of the subtractive polarity winding was larger than that of the additive polarity winding. In conclusion, we found that the additive polarity winding reduced the burden of SFCL because the quench time was shorter and the fault current was smaller than those of the subtractive polarity winding.

• 한국전기전자재료학회논문지
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• 제28권1호
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• pp.40-45
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• 2015

Electrode systems: a protrusion on conductor (POC), a protrusion on enclosure (POE), a crack in epoxy plate and a free particle (FP) were fabricated to simulate insulation defects in a gas insulated switchgear (GIS). $SF_6$ gas was filled in the electrode systems by 3 bar and/or 5 bar, respectively. Partial discharge (PD) pulses were detected through a $50{\Omega}$ non-inductive resistor. A calibration test was carried out according to IEC 60270, and the sensitivity was 0.25 pC/mV. PD pulses were distributed in the phase of $50^{\circ}{\sim}135^{\circ}$ and over 95% of them existed in the phase of $55^{\circ}{\sim}120^{\circ}$ for the POC. PD pulses were distributed in the phase of $230^{\circ}{\sim}310^{\circ}$ and over 90% of them existed in phase of $220^{\circ}{\sim}300^{\circ}$ for the POE. PD pulses occurred in the phase of $40^{\circ}{\sim}60^{\circ}$ and $220^{\circ}{\sim}300^{\circ}$ for the crack, and pulse counts were 25% higher in negative polarity than in positive polarity. PD pulses were distributed in every phase unlike to other three electrode systems and the peak magnitude was measured at $118^{\circ}$ and $260^{\circ}$ for the FP. As described above, PD pulses were observed in positive polarity for the POC, in negative one for the POE, in both one for the crack and the FP. In conclusion, it is expected that the identification rate of defect type can be improved by considering the polarity ratio of PD pulses on the PRPDA method.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2006년도 춘계학술대회 논문집
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• pp.467-470
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• 2006

Superconducting fault current(SFCLs) are expected to improve not only reliability but also stability of real power systems. The analysis on the single line-to-ground fault current of the integrated three phase flux-lock type SFCL, which consists of three flux-lock reactor wound on an iron core in each single phase and three YBCO thin films, was investigated in current limiting operating characteristics. We compared additive polarity winding with the subtractive one in the flux lock reactor. Its turns ratio each phase between the primary and the secondary coils is 63:42. When a single line-to-ground fault occurred in any phase, the peak value of line current in the fault phase of the additive polarity winding increased up to 31.44[A] during first-half cycle. On the other hand, the peak value in the subtractive polarity winding increased up to 81.77[A] under the same conditions. This is because the current flow between the primary and the secondary windings becomes to be additive or subtractive in each winding direction. We confirmed that the current limiting behavior in the additive polarity winding was more effective for a single-line-to ground fault.

• 전기의세계
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• 제26권6호
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• pp.78-85
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• 1977

This paper studies flashover voltage and surface corona loss of A.C and D.C in the mixed gas of air and SF$_{6}$ for solid insulators P.V.C, arcylic, glass and bakelite in two cases. In one case, those solids are covered with transformer oil and the other case, those solids are not covered with it. 1) The flashover voltage for each solids in SF$_{6}$ is more than three times compared with that in the air. The flashover voltage for P.V.C is the highest and then arcylic, glass, bakelite in a decreasing order. 2) The more the amount of SF$_{6}$ in the mixing ratio, the less corona loss. The P.V.C shows the least amount of corona loss and the bakelite the largest. 3) Compared with the corona loss of positive polarity and the negative polarity, the former has less corona loss than the latter. 4) The more the number of flashover discharge, the less insulation of each solids, but in case of bakelite, insulation almost vanishes after a couple of discharge. 5) When each insulator is covered with transformer oil, the flashover voltage generally increases and the corona loss decreases.eases.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 추계학술대회 논문집 전력기술부문
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• pp.180-181
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• 2007

In this paper, SFCL using two magnetically coupled coils was modeled and simulated by PSCAD/EMTDC. The simulation was shown that fault current could be adjusted with the inductance ratio and the winding direction of two coils. The limited fault current in case of the additive polarity winding was lower than that of the subtractive polarity. The analysis results were compared with the calculated ones, and both the results agreed.

• 전력전자학회논문지
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• 제13권3호
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• pp.196-205
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• 2008

고전압 DC 전원 응용에 사용되는 높은 입출력 전압 변환비의 특성을 가지는 새로운 극성 반전형 dc/dc 전력 변환 회로를 제안하였다. 제안안 회로의 특징은 기존회로보다 소자의 전압 스트레스가 감소된다. 제안한 회로의 동작원리를 분석하고 특징을 비교하였다. 제안한 회로의 타당성을 검증하기 위해 시뮬레이션결과와 실험결과를 비교 분석 하였다.

• Bulletin of the Korean Chemical Society
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• 제7권6호
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• pp.458-461
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• 1986

The fluorescence intensity of khellin-dimethylfumarate C$_4$-cycloadduct (KDF) is very sensitive to temperature and to the nature of solvents, especially hydrogen-bonding ability. The fluorescence quantum yields of KDF in ethanol and isopentane at 77K are 0.73 and 0.54, respectively, both of which are much larger than the room temperature values. The phosphorescence lifetime is very long and decreases with decreasing the solvent polarity. The phosphorescence and fluorescence quantum yield ratio is very small and decreases with decreasing solvent polarity. The solvent relaxation plays an important role in the excited states of KDF. The internal conversion is a major decay process of the excited singlet state of KDF in all the solvents used at room temperature.

• Bulletin of the Korean Chemical Society
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• 제13권6호
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• pp.684-688
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• 1992

Three photocyclodimers of 5,7-dimethoxycoumarin (DMC) were isolated and characterized from the photolysis of DMC in acetonitrile. The configuration of the dimers was found to be anti head-to-head, syn head-to-head and syn head-to-tail, respectively. The number and the ratio of the products are solvent dependent. The anti head-to-head dimer is favored in nonpolar solvents and the preference decreases as the solvent polarity increases giving almost 100${\%}$ syn dimers and less than 1${\%}$ anti dimer from methanol solution. The overall yields of dimers also increase with the solvent polarity. From sensitization and quenching experiments, anti dimer was found to be formed via excited singlet state while syn dimers were formed via both excited singlet and triplet states.