• Title/Summary/Keyword: Polar low

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Effect of NH3 plasma on thin-film composite membrane: Relationship of membrane and plasma properties

  • Kim, Eun-Sik;Deng, Baolin
    • Membrane and Water Treatment
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    • v.4 no.2
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    • pp.109-126
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    • 2013
  • Surface modification by low-pressure ammonia ($NH_3$) plasma on commercial thin-film composite (TFC) membranes was investigated in this study. Surface hydrophilicity, total surface free energy, ion exchange capacity (IEC) and zeta (${\zeta}$)-potentials were determined for the TFC membranes. Qualitative and quantitative analyses of the membrane surface chemistry were conducted by attenuated total reflectance Fourier transform infrared (ATR FT-IR) spectroscopy. Results showed that the $NH_3$ plasma treatment increased the surface hydrophilicity, in particular at a plasma treatment time longer than 5 min at 50 W of plasma power. Total surface free energy was influenced by the basic polar components introduced by the $NH_3$ plasma, and isoelectric point (IEP) was shifted to higher pH region after the modification. A ten (10) min $NH_3$ plasma treatment at 90 W was found to be adequate for the TFC membrane modification, resulting in a membrane with better characteristics than the TFC membranes without the modification for water treatment. The thin-film chemistry (i.e., fully-aromatic and semi-aromatic nature in the interfacial polymerization) influenced the initial stage of plasma modification.

Free-Radical Copolymerization of Glycidyl Methacrylate with Phthalimidoethyl Acrylate : Synthesis and Determination of Monomer Reactivity Ratios (GMA와 프탈이미드아크릴레이트의 공중합체 합성과 반응성비)

  • Oh, Seung-Min;Oh, Dae-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.297-304
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    • 2013
  • Free-radical copolymerization of glycidyl methacrylate(GMA) and N-phthalimidoethyl acrylate(NPEA) were carried out at $60^{\circ}C$ in dimethylformamide(DMF) solution in the presence of benzoylperoxide(BPO) at low conversion. The polymers were characterized by IR and $^1H$-NMR. The compositions of the copolymer was analyzed by ultra violet(UV/Vis) spectrophotometry. The reactivity ratios of the monomer was determined by the application of Fineman-Ross(FR) and Kelen-T$\ddot{u}$d$\ddot{o}$s(KT) methods. The monomer reactivity ratios of the system and Alfrey-Price's resonance effect(Q) and polar effect(e) value for NIEA were determined as follow. The reactivity ratios of the monomer obtained from FR and KT are found to be $r_1$=0.87, $r_2$=0.98 and $r_1$=0.88, $r_2$=0.99 respectively. The Q and e values of poly(GMA-co-NPEM) calculated from $r_1$ and $r_2$ was Q= 1.31, e=0.75 respectively.

Analyzing an Economic Feasibility for Restoration/Creation of Artificial Tidal Flats (인공갯벌 조성에 관한 경제적 타당성 분석)

  • Nam, Kwang-Hyun;Oh, Wee-Yeong
    • Ocean and Polar Research
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    • v.25 no.4
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    • pp.593-601
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    • 2003
  • The purpose of this paper is to investigate economic feasibility of creating artificial tidal flats using cost-benefit analyses. We assumed that the cost factors are associated with designing, construction and monitoring, and the benefit factors are associated with fisheries production, habitation, prevention of disasters, water purification, aesthetic value and existence value. First, for analyzing economic feasibility, the scenario suggests that a design can be made in a year, construction can be completed in three years and monitoring must be made for 20 years. Assuming the discount rate of 7.5%, economic feasibility analyses showed that B/C was 2.26 and IRR was 14.50. This study indicated there is economic validity of implementing creation of artificial tidal flat. In addition, we carried out a sensitivity analysis at the change of discount rate and restoration rate. The result of sensitivity analysis clearly showed that economic validity is low when discount rate is over 15%, and changes in restoration rate did not significantly effect on the economic validity.

Genetic Diversity of the Mud Crab Scylla serrata in Micronesia based on Microsatellite Marker Analysis (마이크로세틀라이트 마커 분석을 이용한 남서태평양 일대에 서식하는 남방톱날꽃게(Scylla serrata)의 유전적 다양성)

  • Jang, Yo-Soon;Yi, Soon-Kil;Noh, Choong-Hwan;Oh, Sung-Yong
    • Ocean and Polar Research
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    • v.31 no.4
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    • pp.319-326
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    • 2009
  • Analysis of four microsatellite markers from Mud Crab Scylla serrata revealed that there is high level of genetic diversity within this species. Genetic diversity of S. serrata was calculated using allele diversity, observed heterozygosity, expected heterozygosity (Het-exp), polymorphic information content, gene differentiation and Nei's $D_{A}$ distance. Mean polymorphic information content value was 0.797, which reflected high level of polymorphism across the loci of S. serrata. The Palau population has the highest genetic diversity (Het-exp=0.871), while the Kosrae population has the lowest genetic diversity (Hetexp=0.806). However, the geographical genetic distance among S. serrata populations from Yab, Chuuk, Pohnpei, Kosrae, and Palau were low (0.2009${\sim}$0.3350). These results suggest that despite their wide distribution, S. serrata are no different in geographical genetic diversity within the five sampled locations.

Extracts and Essential Oil of Ledum palustre L. Leaves and Their Antioxidant and Antimicrobial Activities

  • Kim, Dong-Myong;Nam, Bong-Woo
    • Preventive Nutrition and Food Science
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    • v.11 no.2
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    • pp.100-104
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    • 2006
  • The in vitro antimicrobial and antioxidant activities of the essential oil and methanol extracts of Ledum palustre L. were investigated. Using GC-MS analysis, we identified 37 compounds in the essential oil, constituting 87.58% of the total oil. There are several monoterpenes, of which sabinene is the major compound ($16{\sim}17%$). There are several oxygenated monoterpenes of which terpinen-4-ol(7.6%) and myrtenal (3.5%) are the main constituents. $\beta$-Selinene, a-selinene, $\gamma$-elemene, a-caryophyllene are the main sesquiterpenes ($2{\sim}6%$ range). The oil strongly reduced the diphenylpicrylhydrazyl radical ($IC_{50}=1.56{\mu}g/mL$) formation and exhibited a hydroxyl radical scavenging effect in the $Fe^{3+}-EDTA-H_2O_2$ deoxyribose system ($IC_{50}=2.7{\mu}g/mL$), and also inhibited the nonenzymatic lipid peroxidation of rat liver homogenate ($IC_{50}=13.5{\mu}g/mL$). The polar phase of the extract showed antioxidant activity. The oil showed antimicrobial activity against Streptococcus pneumoniae, Clostridium perfringens, Candida albicans, Mycobacterium smegmatis, Acinetobacter lwoffii and Candida krusei while the water-insoluble parts of the methanolic extracts exhibited slight or no activity. This study confirms that the essential oil of Ledum palustre L. possesses antioxidant and low antimicrobial properties in vitro.

Sensibility Image Scales for Korean Traditional Motifs

  • Chang, Soo-Kyung;Kim, Jae-Sook
    • The International Journal of Costume Culture
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    • v.5 no.1
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    • pp.58-66
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    • 2002
  • The objectives of this study are to develope sensibility image scales for Korean traditional motifs by quantitatively measuring their images and preference and to classify them into clusters. Data were collected via a questionnaire from seven hundred twenty five Korean undergraduate students. Re experimental materials were forty eight stimuli of Korean traditional motifs with different categories, interpretation types, composition types, and application objects. The instruments consisted of 7-point polar semantic differential scales of twenty three bipolar adjectives including preference. Data were analyzed by correspondence analysis, cluster analysis, ANOVA and Duncan's multiple range test. Re major results are as follows; image scales for textile patterns and dress designs using Korean traditional motifs were constructed. The axes of sensibility image scales for both textile patterns and dress designs were defined by quality level and degree of simplicity. Second, four clusters on the scale of textile patterns and two clusters on the scale dress designs were identified. Third, in the case of textile Patterns, the preferred cluster had high-quality and classical images, while the cluster that was not preferred had a complex image. In the case of dress designs, the preferred cluster had simple and high-quality images, while the cluster that was not preferred had complex and low-quality images.

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Ocean Disaster Detection System(OD2S) using Geostationary Ocean Color Imager(GOCI) (천리안해양관측위성을 활용한 해양 재난 검출 시스템)

  • Yang, Hyun;Ryu, Jeung-Mi;Han, Hee-Jeong;Ryu, Joo-Hyung;Park, Young-Je
    • Journal of Information Technology Services
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    • v.11 no.sup
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    • pp.177-189
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    • 2012
  • We developed the ocean disaster detection system(OD2S) which copes with the occurrences of ocean disasters (e. g. the red and green tide, the oil spill, the typhoon, and the sea ice) by converging and integrating the ocean color remote sensing using the satellite and the information technology exploiting the mass data processing and the pattern recognitions. This system which is based on the cosine similarity detects the ocean disasters in real time. The existing ocean color sensors which are operated in the polar orbit platforms cannot conduct the real time observation of ocean environments because they support the low temporal resolutions of one observation a day. However, geostationary ocean color imager(GOCI), the first geostationary ocean color sensor in the world, produces the ocean color images(e. g. the chlorophyll, the colored dissolved organic matter(CDOM), and the total suspended solid(TSS)), with high temporal resolutions of hourly intervals up to eight observations a day. The evaluation demonstrated that the OD2S can detect the excessive concentration of chlorophyll, CDOM, and TSS. Based on these results, it is expected that OD2S detects the ocean disasters in real time.

Composition and Structure of Macrofouling Communities on Ocean-going Ships in the Far East Sea Basin

  • Moshchenko, Alexander V.;Zvyagintsev, Alexander Y.
    • Ocean and Polar Research
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    • v.23 no.2
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    • pp.63-75
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    • 2001
  • Species composition and community structure of the fouling found on the hulls of 28 ships traveling through 6 main shipping routes (SR)in the Far East Sea Basin were analyzed using statistical methods. Samples obtained during 1976-1990 expeditions of the Institute of Marine Biology were used for the analyses. These samples were taken from the ships anchored in the harbor by SCUBA diving and in dry-docks of the Vladivostok ship-repairing yard. Similar composition of the fouling communities occurred on the ships travelling the same SR. In five cases, fouling was dominated by different Cirripedia communities. And, in one case, a community of the mussel Mytilus trossulus was found. In most cases the results of the factor analyses showed extremely low level of the relationships among different animals and algal species in fouling communities. Each ocean-going ship had an original structure of the fouling. Spatially disconnected animal associations of tropical and boreal origin may simultaneously coexist at the same ship. This paper testified to the originality of the zone of anthropogenic substrata as a benthos concentrator in the pelagic regions of the world ocean. The fouling from different zones showed that each zone possesses peculiar features and regularities of the composition and relationships between organisms dwelling here.

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The Effects of Adsorption on Phosphate Benthic Fluxes in the Intertidal Sediments of Keunso Bay, Yellow Sea (황해 근소만 조간대 퇴적물에서 인산염 흡착이 저층플럭스에 미치는 영향)

  • Kim, Dong-Seon;Kim, Kyung-Hee
    • Ocean and Polar Research
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    • v.31 no.3
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    • pp.247-255
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    • 2009
  • We measured phosphate benthic fluxes and conducted phosphate adsorption experiments in order to find out the effects of adsorption on phosphate benthic fluxes in the intertidal sediments of Keunso Bay during summer and winter. Organic carbon contents showed little variation with season at St. S1, but noticeable changes were observed at St. S2, which were three times higher in winter than in summer. The higher organic carbon contents in winter resulted from the bloom of benthic algae in surface sediments. Pore water phosphate concentrations were much higher in summer than in winter. The higher phosphate concentration in summer was probably due to the faster remineralization rate of organic matter in summer. At St. S1, benthic fluxes of phosphate showed a negative value in summer and a positive value in winter. However, St. S2 had a negative benthic flux both in summer and winter. The negative benthic flux was ascribed to the phosphate adsorption on iron oxides in surface sediments. The equilibrium concentrations of phosphate obtained from the adsorption experiment were three times higher at St. S1 than at St. S2. The relatively high adsorption coefficient and low equilibrium concentration indicated that phosphate was strongly adsorbed on the surface sediments of Keunso Bay. The strong adsorption affinity significantly reduced benthic fluxes of phosphate in the intertidal sediments.

Evaluation of Temperature and Salinity Fields of HYCOM Reanalysis Data in the East Sea (HYCOM 재분석 자료가 재현한 동해 수온 및 염분 평가)

  • Hong, JinSil;Seo, Seongbong;Jeon, Chanhyung;Park, Jae-Hun;Park, Young-Gyu;Min, Hong Sik
    • Ocean and Polar Research
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    • v.38 no.4
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    • pp.271-286
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    • 2016
  • We evaluate the temperature and salinity fields in the East Sea reproduced by the global ocean reanalysis data using HYbrid Coordinate Ocean Model (HYCOM for short). Temporal correlation of Sea Surface Temperature (SST) change between HYCOM and the Group for High Resolution Sea Surface Temperature (GHRSST) are higher in summer than winter. Though distributions of temperature and salinity in the HYCOM are similar to those from historical data (World Ocean Atlas 2013 V2), salinity in the HYCOM is lower (highter) in the region where the salinity is high (low). Temperature fields in the Ulleung basin of HYCOM are quite similar to those derived from Pressure-recording Inverted Echo Sounder (PIES), such as the correlation coefficient is higher than 0.7. This indicates that the HYCOM represents well the circulation and meso-scale phenomena in the Ulleung basin.