• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.04b
• /
• pp.30-33
• /
• 2004

Shallow p+-n junctions were formed by low-energy ion implantation and dual-step annealing processes The dopant implantation was performed into the crystalline substrates using $BF_2$ ions. The annealing was performed with a rapid thermal processor and a furnace. FA+RTA annealing sequence exhibited better junction characteristics than RTA+FA thermal cycle from the viewpoint of junction depth. A new simulator is designed to model boron diffusion in silicon, which is especially useful for analyzing the annealing process subsequent to ion implantation. The model which is used in this simulator takes into account nonequilibrium diffusion, reactions of point defects, and defect-dopant pairs considering their charge states, and the dopant inactivation by introducing a boron clustering reaction. Using a resonable parameter values, the simulator covers not only the equilibrium diffusion conditions but also the nonequilibrium post-implantation diffusion. Using initial conditions and boundary conditions, coupled diffusion equation is solved successfully. The simulator reproduced experimental data successfully.

• Carbon letters
• /
• v.9 no.1
• /
• pp.8-16
• /
• 2008

Oxidized activated carbons were prepared by reacting steam-activated carbon developed from pecan shells with nitric acid of varying strength (15, 30, 45 and 60%). The textural properties and the chemistry of the surface of the non-oxidized and of the oxidized carbons were determined from nitrogen adsorption and base neutralization capacities. The uptake of Pb(II) and Cd(II) from aqueous solution by these carbons was determined by kinetic and equilibrium experiments as well as by the column method. Treatment with nitric acid brought about drastic decrease in surface area and remarkable increase in the pore size of the carbon with these changes depending on the strength of nitric acid. Nitric acid increased the surface acidity by developing new surface oxygen functional groups of acidic nature. $HNO_3$-oxidized carbons exhibited high adsorption capacities for Pb(II) and Cd(II). The adsorption of these ions increased with the decrease of the surface pH of the carbon and with the increase of the solution pH from 2.5 to 6 and 7. The amount adsorbed from lead and cadmium was also related to the amount of surface acidity, the pH of the point of zero charge and on some metal ion parameters. Cadmium and lead uptake by the investigated carbons followed pseudo-second order model and the equilibrium sorption data fitted Langmuir adsorption model.

• 한국신재생에너지학회:학술대회논문집
• /
• 2008.05a
• /
• pp.33-36
• /
• 2008

The transient behavior of a passive air breathing direct methanol fuel cell (DMFC) operated on vapor-feeding mode is studied in this paper. It generally takes 30 minutes after starting for the cell response to come to its steady-state and the response is sometimes unstable. A mathematical dynamic one-dimensional model for simulating transient response of the DMFC is presented. In this model a DMFC is decomposed into its subsystems using lumped model and divided into five layers, namely the anodic diffusion layer, the anodic catalyst layer, the proton exchange membrane (PEM), the cathodic catalyst layer and the cathodic diffusion layer. All layers are considered to have finite thickness, and within every one of them a set of differential-algebraic governing equations are given to represent multi-components mass balance, such as methanol, water, oxygen and carbon dioxide, charge balance, the electrochemical reaction and mass transport phenomena. A one-dimensional, isothermal and mass transport model is developed that captures the coupling between water generation and transport, oxygen consumption and natural convection. The single cell is supplied by pure methanol vapor from a methanol reservoir at the anode, and the oxygen is supplied via natural air-breathing at the cathode. The water is not supplied from external source because the cell uses the water created at the cathode using water back diffusion through nafion membrane. As a result of simulation strong effects of water transport were found out. The model analysis provides several conclusions. The performance drop after peak point is caused by insufficiency of water at the anode. The excess water at the cathode makes performance recovery impossible. The undesired crossover of the reactant methanol through the PEM causes overpotential at the cathode and limits the feeding methanol concentration.

• Korean Chemical Engineering Research
• /
• v.61 no.1
• /
• pp.155-161
• /
• 2023

Ion concentration polarization (ICP) is one of the essential important mechanisms for biomolecule preconcentration devices as well as a fundamental transport phenomenon found in electrodialysis, electrochemical cell, etc. The ICP triggered by externally applied voltage enables the biomolecular analyte to be preconcentrated at an arbitrary position by a locally amplified electric field inside the microchannel. Conventional preconcentration methodologies using the ICP have two limitations: uncertain equilibrium position and hydrodynamic instability of preconcentration plug. In this work, a new preconcentration method in the dead-end microchannel around cation exchange membrane was numerically studied to resolve the limitations. As a result, the numerical model showed that the analyte was concentrated at a shock front developed in a geometrically confined dead-end channel. Furthermore, the electrokinetic behaviors for preconcentration dynamics were analyzed by changing microchannel's applied voltage and volumetric charge concentration of microchannel as key parameters to describe the dynamics. This work would provide an effective means for a point-of-care platform that requires ultra-fast preconcentration method.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.22 no.2
• /
• pp.261-269
• /
• 2018

This paper presents a convenient method to estimate the internal parameters of plenoptic camera using CCD(charge-coupled device) camera model. The images used for plenoptic camera calibration generally use the checkerboard pattern used in CCD camera calibration. Based on the CCD camera model, the determinant of the plenoptic camera model can be derived through the relationship with the plenoptic camera model. We formulate four equations that express the focal length, the principal point, the baseline, and distance between the virtual camera and the object. By performing a nonlinear optimization technique, we solve the equations to estimate the parameters. We compare the estimation results with the actual parameters and evaluate the reprojection error. Experimental results show that the MSE(mean square error) is 0.309 and estimation values are very close to actual values.

• Journal of the Korean Geotechnical Society
• /
• v.19 no.2
• /
• pp.75-85
• /
• 2003

Laboratory model blast and in-situ rock blast tests were conducted to determine blast-induced stress wave propagation characteristics under different explosive types, different loading conditions and different mediums. Dynamic numerical approaches were conducted under the same conditions as experimental tests. Stress magnitudes at mid-point between two blast holes which were detonated simultaneously increased up to two times those of single hole detonation. The rise time of maximum stress in a decoupled charge condition was delayed two times that of a fully charged condition. Dynamic numerical analysis showed almost similar results to blast test results, which verifies the effectiveness of numerical approaches fur optimizing the tunnel blast design. Dynamic numerical analysis was executed to evaluate rock behavior and damage of the contour hole, the sloping hole adjacent to the contour hole in the road tunnel blasting pattern. The rock damage zone of the sloping hole from the numerical analysis was larger than that of the contour hole. Damage in the sloping hole can be reduced by using lower density explosive, by applying decoupled charge, or by increasing distance between the sloping hole and the contour hole.

• Journal of the Institute of Electronics Engineers of Korea SD
• /
• v.46 no.12
• /
• pp.105-112
• /
• 2009

In this paper, we investigated abnormal ESD failure on guard-rings in the smart power IC fabricated with $0.35{\mu}m$ Bipolar-CMOS-DMOS (BCD) technology. Initially, ESD failure occurred below 200 V in the Machine Model (MM) test due to current crowding in the parasitic diode associated with the guard-rings which are generally adopted to prevent latch-up in high voltage devices. Optical Beam Induced Resistance Charge (OBIRCH) and Scanning Electronic Microscope (SEM) were used to find the failure spot and 3-D TCAD was used to verify cause of failure. According to the simulation results, excessive current flows at the comer of the guard-ring isolated by Local Oxidation of Silicon (LOCOS) in the ESD event. Eventually, the ESD failure occurs at that comer of the guard-ring. The modified comer design of the guard-ring is proposed to resolve such ESD failure. The test chips designed by the proposed modification passed MM test over 200 V. Analyzing the test chips statistically, ESD immunity was increased over 20 % in MM mode test. In order to avoid such ESD failure, the automatic method to check the weak point in the guard-ring is also proposed by modifying the Design Rule Check (DRC) used in BCD technology. This DRC was used to check other similar products and 24 errors were found. After correcting the errors, the measured ESD level fulfilled the general industry specification such as HBM 2000 V and MM 200V.

• Microbiology and Biotechnology Letters
• /
• v.18 no.5
• /
• pp.517-524
• /
• 1990

The solubilization and desolubilization of proteins in CTAB/hexanol/isooctane reverse micellar system were investigated for the selective separation of proteins. Several proteins were used, including bovine serum albumin (BSA), pepsin, trysin and ribonuclease-a. Most proteins could be solubilized into reverse micelles in the pH range above the isoelectric point of each protein, where the net charge of protein was opposite to that of surfactant. However BSA was solubilized above pH 10, which is serveral pH units above the pI 4.9. The kinds of anions in aqueous phase influenced on protein solubilization while no significant trend was observed with different cations, Protein solubilization decreased with increase of the ion size in the order of F -, C1-, Br- and I -. The size of CTAB micelles did not change significantly with increasing ionic strength, but the solubilization decreased. Protein desolubilization showedropposite behaviors to the solubilization. Several model mixtures such as pepsin/ trypsin, pepsin/ribonuclease-a and BSAlribonucleaee-a were successfully separated from each other without changing enzymatic activities.

• Journal of Advanced Marine Engineering and Technology
• /
• v.13 no.1
• /
• pp.57-68
• /
• 1989

This paper treats the analytical and experimental studies on the improvement of commutating circuit for the speed control of DC motor. A simple circuit composed of R, L and C elements is proposed here for switching off power SCR carrying the load current. The real important in this chopper circuit is to determine the reasonable values of commutating circuit constants. In this paper, the reasonable values of the commutating circuit constants are basically determined on a view point of commutating performances in the given circuit model and must satisfy the following conditions. The first, the peak commutating current should be larger than the anticipated maximum load current. The second, the circuit turn-off time (tc) must be longer than the SCR turn-off time (tq). The third, the resistor should be enough large to permit the current to be neglected in the analysis of the commutation circuit, as well as be enough small to permit to charge the capacity voltage (Ec) to the half the value of source voltage (E) before the next communication cycle is initiated. The last, the period of chopping signal must be the least possible multiple of the damping vibration period of commutating circuit. The improved chopper circuit used in the experiment under unloaded condition was composed to meet the reasonable conditions mentioned above, and a successful commuting performance was achieved without failure. Several types of microprocessor having a different value of CPU speed individually have been applied to the experiment under the loaded conditions. Also it shows that the faster the speed of CPU is, the more stable the commutation turns out.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.25 no.10
• /
• pp.28-37
• /
• 2011

Though Korea has introduced CBP(Cost Based pool) power trading system since 2001, long-term Generation system planning has been executed by government for Cost minimization every 2 years. Until currently the model which is used for Generation system planning and best-mix only considers cost minimization and total yearly or quarterly electricity demand every year. In a view point of one day power supply operation, technical characteristics, like the ramp up/down rate of total generation system, minimum up/down time and GFRQ(Governor Free Response Quantity), are very important. this paper analyzes Optimal Fuel-Mix for 2022 Korea generation system satisfying these constraints of each fuel type and considering pump storage plants, construction cost and $CO_2$ emission charge Using MILP(Mixed Integer Linear Programming) method. Also the sensitivity analysis which follows in future power industry environmental change accomplished.