• Title/Summary/Keyword: PoP

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Estimation of the optimum factor of the crystalization for the phosphorus in WWTP (폐수내 인제거를 위한 결정화 최적 조건)

  • Kim, Ji-Yeon;Kim, Youn-Kwon
    • Proceedings of the KAIS Fall Conference
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    • 2007.11a
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    • pp.305-307
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    • 2007
  • Struvite(MAP) 및 hydroxyapatite(HAP) 결정화로 질소 및 인을 제거하기 위한 최적조건을 평가하기 위한 실험을 실시하였으며, $Mg^{2+}$, $NH_4^+$, $PO_4^{3-}$$Ca^{2+}$용액을 이용하여 인공폐수를 조제하였으며 각 이온의 몰비 조건을 1:1:1에서 실험을 수행하였다. $Ca^{2+}$$PO_4^{3-}$를 이용한 HAP 결정화는 알칼리조건의 pH 범위에서는 pH에 큰영향을 받지 않고 HAP가 형성되었으며, MAP 및 HAP 동시 결정화를 위한 실험에서는 pH가 증가하면서 $NH_4^+$, $PO_4^{3-}$ 제거효율은 감소하며 $Ca^{2+}$$Mg^{2+}$는 모든 pH에서 99% 이상 제거되었다. 폐수중에 $Ca^{2+}$이 포함되어 있다면 pH 9.5에서 $Mg^{2+}:NH_4^+:PO_4^{3-}:Ca^{2+}$는 1.2:1.0:1.2:2.0의 몰비로 존재했을 때 MAP 및 HAP 생성 최적조건인 것으로 나타났다. 그러나 pH가 10이상이 되면 부반응으로 인해 각종 무정형 결정체가 생성되므로 MAP 생성을 위해서는 pH 9.5로 운영을 하는 것이 가장 바람직하다.

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Phosphorous Removal in a Free Water Surface Wetland Constructed on the Gwangju Stream Floodplain (광주천 고수부지에 조성한 자유수면인공습지의 인 제거)

  • Yang, Hong-Mo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.40 no.1
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    • pp.100-109
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    • 2012
  • Removal rates of $PO_4-P$ and TP in a free water surface wetland system were investigated. The system was established in 2008 on a floodplain in the middle reach of the Gwangju Stream flowing through Gwangju City. Its dimensions were 46 meters in length and 5 meters in width. Two year old Typha angustifloria L. growing in pots were planted on half of the area and Zizania latifolia Turcz on the other half in 2008. Stream water was funneled into the wetlands by gravity flow, and its effluent was discharged back into the stream. The influent volume was controlled by valves and water depth was adjusted by wires. Volume and water quality of inflow and outflow were analyzed from January to December in 2010. Inflow into the system averaged approximately $710m^3/day$ and hydraulic residence time was about 1.5 hours. Average influent and effluent $PO_4-P$ concentration were 0.144 and 0.103mg/L, respectively, and $PO_4-P$ abatement amounted to 28.6%. Influent and effluent TP concentration averaged 0.333 and 0.262mg/L, respectively, and TP retention reached to 20.7%.$PO_4-P$ removal rate(%) during plant growing season(31.448) was significantly high(p<0.001) when compared with that during plant non-growing season(25.829). TP abatement rate(%) during plant growing season(27.230) was also significantly high(p<0.001) when compared with that of the non-growing season(14.856). Major phosphorous removals in the system resulted from adsorption of phosphorous in the litter-soil layers; sedimentation of particulate phosphorous and Ca, Al, Fe bounded phosphates; and absorption of phosphorous by emergent plants. The adsorption and sedimentation occurred throughout the year, however, the absorption took place during plant growing season. This resulted in higher removals of $PO_4-P$ and TP during plant growing season.

Chemical Composition, Herbage Yield and Nutritive Value of Panicum antidotale and Pennisetum orientale for Nili Buffaloes at Different Clipping Intervals

  • Sarwar, Muhammad;Mahr-un-Nisa, Mahr-un-Nisa;Khan, M. Ajmal;Mushtaque, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.2
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    • pp.176-180
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    • 2006
  • This study was carried out to establish clipping interval of Pennisetum orientale (PO) and Panicum antidotale (PA) to get maximum biomass production with optimal nutritional value for Nili buffaloes. Two clipping intervals i.e. $CI_1$, and $CI_2$ (clipped after every one and two months, respectively) were studied for both grasses. The data on various parameters were compared with PO and PA each clipped at 4 months of age (control). Leaf to stem ratio in both PO and PA declined with increasing clipping interval. Concentration of dry matter (DM) and organic matter (OM) increased (p<0.05) whereas crude protein contents decreased with increasing clipping interval in both grasses. Crude protein and dry herbage yields in PO and PA increased (p<0.05) with increasing clipping interval. The DM and neutral detergent fiber (NDF) digestibilities of PO and PA in ruminally cannulated buffalo bulls decreased (p<0.05) due to more lignification with increasing clipping interval. Ruminal extent of digestion, rate of disappearance of DM and neutral detergent fiber of PO and PA decreased in buffaloes while ruminal lag time of these nutrients increased significantly (p<0.05) with increasing clipping interval. The results from the study imply that two month clipping interval for both PO and PA grasses favored higher biomass with greater nutritional value for Nili buffaloes and sustained grass vigor.

Stabilization of Heavy Metals-contaminated Soils Around the Abandoned Mine area Using Phosphate (인산염을 이용한 휴.폐광산 주변 중금속 오염토양의 안정화처리에 관한 연구)

  • Lee, Eun-Gi;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.100-106
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    • 2007
  • The objective of this study was to evaluate the efficiency of $(NH_4)_2HPO_4$, $Na_2HPO_4{\cdot}12H_2O$, $CaHPO_4{\cdot}2H_2O$, $Ca(H_2PO_4)_2{\cdot}H_2O$ and $H_3PO_4$ for the stabilization of soils contaminated with multi-metals containing Pb, Cd and As. The application rate of stabilizers to soils was determined based on $PO_4/Pb_{total}$ molar ratio of 0.5, 1, 2, 4. The results of Korea Standard Test and TCLP (EPA Method 1311) showed the reduction of metal leachabilities below the regulatory limits for Pb and Cd when $H_3PO_4$ and $Ca(H_2PO_4)_2{\cdot}H_2O$ were applied. However, stabilization efficiency for Cd was low and in case of As leaching concentration increased rather. It is considered that $PO_4$ reacted effectively $Pb^{2+}$ due to leaching Pb under low pH condition created by adding $H_3PO_4$. Accordingly Pb was stabilized by dissolution and precipitation of hydroxypyromorphite. From the change of metals fraction using sequential extraction procedure when $H_3PO_4$ applied as a stabilizer, we confirmed that residual fraction increased more than 60% and this result was accorded with XRD analysis that detected only hydroxypyromorphite peak in $H_3PO_4$.

Effect of Ponded Water on Variation of Redox Potential and Phosphorus Concentration in a Paddy Field (논에서 담수가 토양 산화.환원전위 변화와 인의 용출에 미치는 영향)

  • Kim, Young-Hyeon;Kim, Jin-Soo;Jang, Hoon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2010.05a
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    • pp.1661-1666
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    • 2010
  • 본 연구의 목적은 충북대학교 부속농장에서 2009년 영농기간을 중심으로 담수된 논에서의 산화환원전위(Eh)의 변화와 시비에 따라 영양물질인 인(P)의 농도변화 특성을 파악함으로써, 논으로 부터의 인의 유출제어에 관한 기초 자료를 제공하는데 있다. 이 연구는 2009년 5월부터 11월까지 논에서 담수의 총인(T-P)과 인산염 인($PO_4$-P)의 농도변화와 토양의 산화환원전위(Eh)와의 관계 특성을 파악하였다. 관개기의 논에서 인은 분얼비 시기에 인성분이 시비되지 않았는데도 불구하고 T-P농도가 0.68 mg/L로 높게 나타났다. 이는 담수의 영향으로 논이 환원상태로 되어, 논바닥에 침전된 철이온에 흡착되어 있던 인이 철이온의 환원으로 함께 용출하기 때문이라고 생각된다. 높은 Eh는 산화경향을, 낮은 Eh는 환원경향을 나타낸다. 본 연구기간 동안의 Eh 값은 연속적으로 담수되었던 7월 중순까지는 74~112 mV 가량 나타냈고, 그 이후에는 담수상태가 아닌 경우가 많아 179~636 mV로 높게 나타났다. 논 담수의 T-P와 $PO_4$-P 농도는 분얼비 직후 1주일후까지 같이 상승하다가 T-P농도는 약 2주일까지 더 상승한 반면 $PO_4$-P 농도는 하강하였는데 이는 논 토양이 환원상태로 되면서 바닥에 있던 입자성 인이 논 표면으로 떠올랐기 때문으로 사료된다. 그 후에는 담수가 끝나는 시점까지인 농도는 낮아졌다. 관개초기에 인의 농도는 비교적 높게 나타났지만, 7월 이후로는 작물의 생장에 필요한 영양물질 섭취 등으로 인 농도가 낮게 나타났는데 이는 7월 이후의 논은 인의 유출을 억제하고 있는 것으로 추정된다. 또한 논 담수위의 증감에 따른 $PO_4$-P 농도와 Eh 값을 회귀분석 한 결과 각각 정의 상관관계와 부의 상관관계가 있는 것으로 나타났다. 이와 같이 논 담수 및 시비에 따른 인의 유출부하 특성과 산화환원전위(Eh)의 변화 특성이 규명된다면, 향후 환경부하가 작은 물관리가 가능해 질 것으로 판단된다.

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Isolation and Characterization of Insoluble Phosphate-Solubilizing Bacteria with Antifungal Activity (항진균능을 가진 불용성 인산 가용화 세균의 분리 및 특성)

  • Park, Ki-Hyun;Son, Hong-Joo
    • Korean Journal of Microbiology
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    • v.42 no.3
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    • pp.223-229
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    • 2006
  • To develop multifunctional microbial inoculant, an insluble phosphate-solubilizing bacterium with antifungal activity was isolated from plant rhizospheric soil. On the basis of its morphological, cultural and physiological characteristics and Biolog analysis, this bacterium was identified as Pseudomonas fluorescens RAF15. P. fluorescens RAF15 showed antifungal activities against phytopathogenic fungi Botrytis cinerea and Rhizoctonia solani. The optimal medium composition and cultural conditions for the solubilization of insoluble phosphate by P. fluorescens RAF15 were 1.5% of glucose, 0.005% of urea, 0.3% $MgCl_2{\cdot}6H_2\;0.01%\;of\;MgSO_4{\cdot}7H_2O\;0.01%,\;of\;CaCl_2{\cdot}2H_2O$, and 0.05% of NaCl along with initial pH 7.0 at $30^{\circ}C$. The soluble phosphate production under optimum condition was 863 mg/L after 5 days of cultivation. The solubilization of insoluble phosphates was associated with a drop in the pH of the culture medium. P. fluorescens RAF15 showed resistance against different environmental stresses like $10-35^{\circ}C$ temperature, 1-4% salt concentration and pH 2-11 range. The strain produced soluble phosphate to the culture broth with the concentrations of 971-1121 mg/L against $CaHPO_4$, 791-908 mg/L against $Ca_3(PO_4){_2}$, and 844 mg/L against hydroxyapatite, respectively. However, the strain produced soluble phosphate to the culture broth with the concentrations of 15 mg/L against $FePO_4$, and 5 mg/L against $AlPO_4$, respectively.

Microwave Irradiation as a Way to Reutilize the Recovered Struvite Slurry and to Enhance System Performance (회수된 MAP 슬러리의 재이용과 공정효율 향상을 위한 도구로서의 극초단파 조사)

  • Cho, Joon-Hee;Lee, Jin-Eui;Ra, Chang-Six
    • Journal of Animal Science and Technology
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    • v.51 no.4
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    • pp.337-342
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    • 2009
  • The feasibility of reutilization of magnesium ammonium phosphate (MAP) or struvite slurry recovered from the process through microwave irradiation was studied in this experiment. For this purpose, 4 different operations were performed with or without Mg source addition and different levels of MAP recycled in a batch reactor. Dissolution rate of MAP, ${NH_4}^+$ elimination pattern and physicochemical changes of MAP during microwave irradiation were also studied. The result showed that only 33% orthophosphate ($PO_4-P$) and 27% $NH_4-N$ removal occurred without adding any external Mg source (run A), whereas 87% $PO_4-P$ and 40% $NH_4-N$ removed when 1.0 M ratio of $MgCl_2$ (run B) was added based on $PO_4-P$ in influent. Although the addition of 1.0 molar ratio of microwave irradiated MAP (Run C) removed lower $PO_4-P$ and $NH_4-N$ than 1.0 M $MgCl_2$ (run B), $PO_4-P$ removal was double when compared with no Mg addition (run A). Addition of half MAP and half $MgCl_2$ (run D) showed the similar removal efficiency (88% $PO_4-P$ and 35% $NH_4-N$) with sole $MgCl_2$ addition (run B). Based on these results, the reutilization of MAP irradiated by microwave would be a feasible way to enhance the removal efficiencies of N and P, as well as curtail the Mg chemical usage. Track study showed that $NH_4-N$ gradually increased at initial stage of microwave irradiation of MAP, and then started eliminating from liquor as temperature increased over $45^{\circ}C$. Dissolution rate of ${PO_4}^{-3}$ during microwave irradiation was proportional to the initial MAP concentration, having $0.0091x^{0.6373}$ mg/sec. It was found from the scanning electron microscope (SEM) study that physical structure of MAP crystal started breaking down into small cube granules within very short time by electromagnetic vibration force during microwave irradiation and then gradually melted down into solution.

Development of Seamless N-Screen Services through Multicast Transmission scheme (멀티캐스트 전송을 이용한 Seamless N-스크린 서비스 개발)

  • Hur, Kyeong;Choi, Sang-Gil;Lee, Hye-Jin;Jeon, Hye-Ji;Kim, Jin-Woo;Lee, Seong-Ro
    • Proceedings of the Korea Information Processing Society Conference
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    • 2015.04a
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    • pp.234-235
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    • 2015
  • P2P 스트리밍 가능한 OSMU(One Source Multi Use) N-스크린 서비스를 제공하기 위해서는 Seamless 무선 통신이 반드시 요구된다. 본 논문에서는 Seamless N-스크린 서비스를 위한 무선 통신 MAC 구조로서, WiMedia Distributed-MAC 프로토콜을 적용하고, OSMU N-스크린 서비스를 제공하기 위해, 멀티캐스트 전송 기술을 제안하고 성능을 분석하였다.

Smart and Secure Point of Sale Framework with Threat Modeling and Formal Verification

  • Mona faraj Nasser alwahabi;Shaik Shakeel Ahamad
    • International Journal of Computer Science & Network Security
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    • v.24 no.6
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    • pp.41-48
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    • 2024
  • Existing PoS (Point of Sale) based payment frameworks are vulnerable as the Payment Application's integrity in the smart phone and PoS are compromised, vulnerable to reverse engineering attacks. In addition to these existing PoS (Point of Sale) based payment frameworks do not perform point-to-point encryption and do not ensure communication security. We propose a Smart and Secure PoS (SSPoS) Framework which overcomes these attacks. Our proposed SSPoS framework ensures point-to-point encryption (P2PE), Application hardening and Application wrapping. SSPoS framework overcomes repackaging attacks. SSPoS framework has very less communication and computation cost. SSPoS framework also addresses Heartbleed vulnerability. SSPoS protocol is successfully verified using Burrows-Abadi-Needham (BAN) logic, so it ensures all the security properties. SSPoS is threat modeled and implemented successfully.

Fabrication of porous glass ceramics in Li$_2$O-TiO$_2$-P$_2$O$_{5}$ system (R$_2$O-TiO$_2$-P$_2$O$_{5}$계 다공질 글라스 세라믹스의 제조)

  • 권면주;윤영진;강원호
    • Proceedings of the KAIS Fall Conference
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    • 2000.10a
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    • pp.173-177
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    • 2000
  • 인산염계 5Li₂O, 36CaO, 20TiO₂, 27P₂O/sub 5/의 조성을 선정하여 10K/min 승온속도로 1300℃에서 2시간동안 유지시켜 모유리를 제조하였고, 최적의 핵형성을 위해 610℃에서 20시간, 최고 결정성장을 위해 840℃에서 20시간 동안 열처리함으로써 LiTi₂(PO₄)₃상과 β-Ca₃(PO₄)₂결정상이 존재하는 Glass Ceramics를 제조하였고, 이를 1N-HCI용액에서 3일간 담지하여 β-Ca₃(PO₄)₂결정상을 용출시켜 LiTi₂(PO₄)₃상만이 존재하는 다공성 Glass Ceramics를 제조하였다.