• 제목/요약/키워드: PoE

검색결과 344건 처리시간 0.023초

Conformational Transition of Form II to Form Ⅰ PoLy(L-proline) and the Aggregation of Form Ⅰ in the Transition: Water-Propanol Solvent System

  • 김현돈
    • Bulletin of the Korean Chemical Society
    • /
    • 제18권9호
    • /
    • pp.922-928
    • /
    • 1997
  • The conformational transition of poly(L-proline) (PLP), Form Ⅱ → Form Ⅰ and the intermolecular aggregation of the product, Form Ⅰ, during and after the transition in water-propanol (1:7, 1:9, 1:15.7, and 1:29 v/v) were studied. For the study, the viscosity change and excess light scattering intensity were measured in the course of the transition which was determined by the Form Ⅰ fraction, fI of the sample solution. For the PLP sample of molecular weight Mv=31,000 the experimental results show that the reaction course is roughly divided into three regions: in the first region [fI=0.27 to 0.40 (- [α]D=400 to 330)], the conformational change of Form Ⅱ → Form Ⅰ occurs with decrease of viscosity, in the second region [fI=0.40 to 0.80 (- [α]D=330 to 120)], a partial side-by-side (p-S-S) type aggregation in which Form Ⅰ blocks interact with each other, which induces the increase of viscosity, starts to occur, and in the third region [fI=0.80 to 1.00 (- [α]D=120 to 15)], a side-by-side type (raft like) aggregation of Form Ⅰ or an end-to-end (E-E) type aggregation occurs according to the solvent situation, i.e., in a water-rich medium [water-propanol (1:9 or 1:7 v/v)], the (S-S) type aggregation with a gross decrease in viscosity occurs while in a water-poor medium [water-propanol (1:29 or 1:15.7 v/v), the (E-E) type aggregation with a large increase in viscosity occurs. The (S-S) type aggregation was promoted at high temperatures. Based on the structure of PLP, a reasonable mechanism for the (p-S-S) and (S-S) aggregation which occurs with the transition of Form Ⅱ → Form Ⅰ is considered. The suggested mechanism was also supported by the result of chain length effect of PLP for the aggregation.

고온 플랜트용 내열 합금강 가속열화 기구의 현장 사용재 비교 검증 (Comparative Verification of Accelerated Degradation Mechanism of Heat-Resistant Steel for High Temperature Plant with that Used in the Field)

  • 이승미;김재연;변재원
    • 한국신뢰성학회지:신뢰성응용연구
    • /
    • 제15권4호
    • /
    • pp.262-269
    • /
    • 2015
  • Accelerated degradation mechanism of the heat-resistant steel for high temperature plant was analysed in terms of microstructure and hardness. In order to simulate the microstructure of the steel actually used at $540^{\circ}C$ in the field, isothermal exposure was carried out at $630^{\circ}C$ up to 4,800 hours. The artificial degradation mechanism was comparatively verified to successfully simulate degradation of the long-time used field material. For the artificially degraded specimens, databases including size and aspect ratio of carbide, chemical composition (i.e., Cr/Mo ratio) of grain boundary carbide were built up. These degradation parameters were suggested as fingerprints for PHM (i.e., prognostics health management) of power plants.

세균 단세포단백질(SCP) 생산을 위한 보조균주의 분리와 그 효과 (Isolation and its effect of a second organism for single cell protein(SCP) production)

  • 권오진;양성호
    • 한국환경보건학회지
    • /
    • 제22권2호
    • /
    • pp.10-18
    • /
    • 1996
  • Experiments were carried out to find the possibility of an economic production of single cell protein(SCP) in mixed culture by Cellulomonas sp. KL-6 and a second organism. The second organism, strain LI-10, was isolated from the large intestines of a mouse. 1. When these strains were mixed, cell growth and carboxymethyl cellulase (CMCase) activity were increased to about 63% and 161%, respectively compared with that of single culture of strain KL-6. We found the mixed culture as a proper method of degradation of cellulose in our study. 2. Strain LI-10 was identified as E. coli. 3. This strain produced trace amounts of cellobiose, but glucose was not found in detectable amounts in the filter paper(FP) medium. 4. $CaCO_3$ injected in the medium at the ratio of 0.1% not only enhanced cell growth but also was effective as an acid neutralizing agent. 5. When this organism was cultured under the optimal medium (glucose 0.1%, $NH_4Cl$ 0.1%, yeast extract 2.0%, $KH_2PO_4$ 0.1%, KCl 0.05%, pH 7.2 and a temperature 30$\circ$C) for 5 days, a cell mass produced 1.18 g/l. The results showed the increase of cell mass up to 300% compared to 0.28 g/l produced in CMC medium.

  • PDF

Band Gap Tuning in Nanoporous TiO2-ZrO2 Hybrid Thin Films

  • Kim, Chang-Sik;Jeong, Hyun-Dam
    • Bulletin of the Korean Chemical Society
    • /
    • 제28권12호
    • /
    • pp.2333-2337
    • /
    • 2007
  • Nanoporous TiO2 and ZrO2 thin films were spin-coated using a surfactant-templated approach from Pluronic P123 (EO20PO70EO20) as the templating agent, titanium alkoxide (Ti(OC4H9)4) as the inorganic precursor, and butanol as a the solvent. The control of the electronic structure of TiO2 is crucial for its various applications. We found that the band gap of the hybrid nanoporous thin films can be easily tuned by adding an acetylacetonestabilized Zr(OC4H9)4 precursor to the precursor solution of Ti(OC4H9)4. Pores with a diameter of 5 nm-10 nm were randomly dispersed and partially connected to each other inside the films. TiO2 and ZrO2 thin films have an anatase structure and tetragonal structure, respectively, while the TiO2-ZrO2 hybrid film exhibited no crystallinity. The refractive index was significantly changed by varying the atomic ratio of titanium to zirconium. The band gap for the nanoporous TiO2 was estimated to 3.43 eV and that for the TiO2-ZrO2 hybrid film was 3.61 eV.

Icefex: Protocol Format Extraction from IL-based Concolic Execution

  • Pan, Fan;Wu, Li-Fa;Hong, Zheng;Li, Hua-Bo;Lai, Hai-Guang;Zheng, Chen-Hui
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • 제7권3호
    • /
    • pp.576-599
    • /
    • 2013
  • Protocol reverse engineering is useful for many security applications, including intelligent fuzzing, intrusion detection and fingerprint generation. Since manual reverse engineering is a time-consuming and tedious process, a number of automatic techniques have been proposed. However, the accuracy of these techniques is limited due to the complexity of binary instructions, and the derived formats have missed constraints that are critical for security applications. In this paper, we propose a new approach for protocol format extraction. Our approach reasons about only the evaluation behavior of a program on the input message from concolic execution, and enables field identification and constraint inference with high accuracy. Moreover, it performs binary analysis with low complexity by reducing modern instruction sets to BIL, a small, well-specified and architecture-independent language. We have implemented our approach into a system called Icefex and evaluated it over real-world implementations of DNS, eDonkey, FTP, HTTP and McAfee ePO protocols. Experimental results show that our approach is more accurate and effective at extracting protocol formats than other approaches.

Spatiotemporal Routing Analysis for Emergency Response in Indoor Space

  • Lee, Jiyeong;Kwan, Mei-Po
    • 한국측량학회지
    • /
    • 제32권6호
    • /
    • pp.637-650
    • /
    • 2014
  • Geospatial research on emergency response in multi-level micro-spatial environments (e.g., multi-story buildings) that aims at understanding and analyzing human movements at the micro level has increased considerably since 9/11. Past research has shown that reducing the time rescuers needed to reach a disaster site within a building (e.g., a particular room) can have a significant impact on evacuation and rescue outcomes in this kind of disaster situations. With the purpose developing emergency response systems that are capable of using complex real-time geospatial information to generate fast-changing scenarios, this study develops a Spatiotemporal Optimal Route Algorithm (SORA) for guiding rescuers to move quickly from various entrances of a building to the disaster site (room) within the building. It identifies the optimal route and building evacuation bottlenecks within the network in real-time emergency situations. It is integrated with a Ubiquitous Sensor Network (USN) based tracking system in order to monitor dynamic geospatial entities, including the dynamic capacities and flow rates of hallways per time period. Because of the limited scope of this study, the simulated data were used to implement the SORA and evaluate its effectiveness for performing 3D topological analysis. The study shows that capabilities to take into account detailed dynamic geospatial data about emergency situations, including changes in evacuation status over time, are essential for emergency response systems.

자동차 환경에서 스마트 모바일 블랙박스 DVR (Smart Mobile Blackbox DVR in Car Environment)

  • 최선오;김영포;임용순;김영자;강은영
    • 한국인터넷방송통신학회논문지
    • /
    • 제13권5호
    • /
    • pp.9-15
    • /
    • 2013
  • 본 논문에서는 사고 자동인식 서비스 제공과 위험 운전 여부 등을 통하여 운전자의 운전습관을 교정해 주고 사고 전후의 동영상을 재현하는 확장성이 높은 모바일 블랙박스 DVR (SMBD, Smart Mobile Blackbox DVR) 컴퓨터의 모델링 설계를 하였다. SMBD는 임베디드 시스템에 무선 기능을 탑재하여 차량이 휴면상태에서도 사고발생 지점과 영상정보를 무선통신을 이용하여 24시간 관제센터에 통보함으로써 긴급구난 서비스 및 교통정보를 제공 받을 수 있다. 또한 차량 ECU(Electronic Control Unit)의 차량정보 및 센서 데이터와 연동하여 무선 eCall (Emergency Call) 서비스를 실현할 수 있다.

줄눈 보강을 통한 면내 방향의 조적조 사인장 전단강도 평가 (Shear Strength Evaluation in Masonry Assemblages by Reinforcing Materials in Joint)

  • 우종훈;신경재;이준섭;한승윤
    • 대한건축학회논문집:구조계
    • /
    • 제35권9호
    • /
    • pp.191-198
    • /
    • 2019
  • All over the Republic of Korea, there are many masonry buildings which have been built since 1970s. When the earthquake at Po-Hang occurred, this is the main cause of huge damage because the masonry buildings have not seismic capacity. When masonry buildings are failed, two type of the failure modes can be shown, which are in-plane mode and out-plane mode. In-plane mode can have seismic capacity in masonry so diagonal shear test is performed in this study. The purpose of this study was to find the best way to reinforce the materials through the diagonal shear test. Through the test, shear stress and shear modulus of elasticity will be calculated, referred to the ASTM E 519-02. The variables in this test are ${\phi}3$ wire, three types of wire meshes, polypropylene strap and different types of brick. Each variable is applied to the same condition of the $1.2m{\times}1.2m$ masonry walls which are made by ASTM E 519-02. Compared to each variable with shear stress and shear modulus of elasticity, the best way of reinforcing method to have seismic capacity will be proved in this study.

Shift of Vietnamese Consumer E-purchasing Behavior During and After Covid-19 Pandemic

  • Pham Thi Cam ANH;Nguyen Mai PHUONG;Nguyen Huong GIANG;Pham Ngoc Mai LINH;Nguyen Huong GIANG
    • 유통과학연구
    • /
    • 제22권1호
    • /
    • pp.47-59
    • /
    • 2024
  • Purposes: The study aimed at examining the impact of the COVID-19 pandemic on the shift of online consumer purchasing behavior and whether the new behaviors would be maintained after the epidemic season. The study also aims to investigate how online customers change based on perceived risks. Research design and Methodology: The study investigated purchasing behavior of the same 377 online Vietnamese consumers during two periods: (1) during the period of social distancing and (2) one and half year after that, allowing data to be collected in real time, so that consumers do not have to recall their behavior. Results: Purchasing behavior appeared to be more influenced by gender, age and household size. Aged consumers are more concerned about risks than those in the younger group, who only worry about the risks during the pandemic. Consumers in households with two or more people are more concerned about the risks than those living alone. Female appeared to be more influential in both during and after pandemic than male. Conclusions: The findings contribute to clarify shift of online consumer purchasing behavior, which helps business to develop effective marketing strategies and enhance their presence in the e-commerce sector.

Optical properties of LK-99 and Cu2S

  • Hong Gu Lee;Yu-Seong Seo;Hanoh Lee;Yunseok Han;Tuson Park;Jungseek Hwang
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제26권2호
    • /
    • pp.1-4
    • /
    • 2024
  • We investigated Pb10-xCux(PO4)6 (0.9 < x < 1.1) (LK-99) and Cu2S, presumed to be contained as an impurity in LK-99, in a wide spectral range from far infrared to ultraviolet using optical spectroscopy. The optical conductivity spectra of both samples were obtained from measured reflectance spectra at various temperatures from 80 to 434 K. Both samples showed several infrared-active phonons in the far and mid-infrared regions. LK-99 showed typical insulating features with a band gap of ~1 eV. Cu2S showed a nonmonotonic temperature-dependent trend and two energy gaps: one energy gap of ~93 meV and a band gap of 2.42 eV. Our results indicate that LK-99 cannot be a superconductor because it is an insulator with a large band gap.