• Title/Summary/Keyword: Po Kim

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Improved Rate Capability of Li/Li3V2(PO4)3 Cell for Advanced Lithium Secondary Battery

  • Lim, Hyun-He;Cho, A-Ra;Sivakumar, Nagarajan;Kim, Woo-Seong;Yoon, Won-Sub;Lee, Yun-Sung
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1491-1494
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    • 2011
  • Lithium vanadium phosphate, $Li_3V_2(PO_4)_3$ was prepared by a simple solid state route. It was found that making a fine powder of $Li_3V_2(PO_4)_3$ by the mechanical milling is very effective for increasing the insertion/extraction of lithium from $Li_3V_2(PO_4)_3$ structure. In charge/discharge test, the ball-milled $Li_3V_2(PO_4)_3$ sample exhibited a higher initial discharge capacity of 174 mAh/g in the voltage range of 3.0-4.8 V, compared with pure $Li_3V_2(PO_4)_3$ sample (152 mAh/g). Furthermore, the ball-milled $Li_3V_2(PO_4)_3$ presented not only higher cycle retention rate after 50 cycles, but also better rate capability compared with pure sample in the whole region (0.1-7 C).

Importance of Colloidal 210Pb and 210Po in Groundwater of Subterranean Estuary (해저 하구의 지하수 중 콜로이드 상 210Pb과 210Po의 중요성)

  • Kim, Tae-Hoon;Kim, Intae
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.19 no.2
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    • pp.125-130
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    • 2014
  • In order to evaluate the distributions of colloidal $^{210}Pb$ (half life = 22.2 years) and $^{210}Po$ (half life = 138 days) in subterranean estuary, we have measured $^{210}Pb$ and $^{210}Po$, for the first time, in the total dissolved (< $0.45{\mu}m$), true dissolved (<10 kDa), and colloidal ($10kDa-0.45{\mu}m$) phases in subterranean estuary of Hampyeong Bay in July 2010 and of Jeju Island in January 2011. The $^{210}Pb$ and $^{210}Po$ activities in groundwater were in the ranges of $0.21-2.52mBqL^{-1}$ and $0.12-2.07mBqL^{-1}$ for true dissolved phase and $0.10-1.71mBqL^{-1}$ and $0.03-0.97mBqL^{-1}$ for colloidal phase, respectively. The proportions of the colloidal phase to the total dissolved phase were $40{\pm}5%$ for $^{210}Pb$ and $28{\pm}5%$ for $^{210}Po$ in groundwater. This result indicates that colloids may play an important role in transporting trace elements through subterranean estuary into the coastal ocean.

A Study on Phosphate Removal Characteristic of EAF Slag for Submarine Cover Material (EAF Slag의 해양복토제 활용을 위한$PO_4{^-}-P$ 제거특성에 관한 연구)

  • Kim, Jae-Won;Seo, Jong-Beom;Kang, Min-Gyeong;Kim, In-Deuk;Oh, Kwang-Joong
    • Clean Technology
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    • v.16 no.4
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    • pp.258-264
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    • 2010
  • This study estimated the possibility of phosphate removal characteristics to utilize EAF(electric arc furnace) slag as submarine cover material. The major phosphate removal mechanism was a certain formation of HAP precipitation occurred by the ionization reaction between $Ca^{2+}$ and $OH^-$, which were leached from the EAF Slag. Another phosphate removal mechanism was the adsortion of EAF slag surface. As a result of $PO_4{^-}-P$ removal characteristics using continuous column reactor, $PO_4{^-}-P$ concentration decreased rapidly after 3 days and 10 days later, it show under 0.5 ppm. The result as applied in real sea water, shows that the phosphate removal effects were 93~98% by the subaqueous sediment removal using the EAF slag. In conclusion, EAF slag is useful in $PO_4{^-}-P$ removal and control and it is possible to use without additional process like crush and selection.

Hydrothermal Growth of $GaPO_{4}$ Single Crystals in HCI Solution

  • Pan-Chae Kim;Shin-Ichi Hirano
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.1 no.1
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    • pp.60-65
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    • 1991
  • The hydrothermal growth of $GaPO_{4}$ Single Crystals was carried out by the horizontal temperature gradient method. The most promising solvents for the crystal growth of $GaPO_{4}$ are $H_{3}PO_{4}$ and HCl solutions. Single crystals have been hydothermally grown at temperatures over the range $210-290^{\circ}C$ in these solutions with seed crystals. The glowth rates in HCl solution were higher than that for comparable conditions in $H_{3}PO_{4}$ solution. Morphologies of crystals grown at temperatures below $200^{\circ}C$ tended to be bounded by small major rhombohedral(10$\bar{1}$1) faces. In the temperature range from 200 to $430^{\circ}C$, the single crystals have morphologies bounded by prism (10$\bar{1}$0), small major rhombohedral(10$\bar{1}$1) and minor rhombohedral(01$\bar{1}$1) faces at the early stage, and grew with well developed basal(0001) faces by increasing the growth temperature.

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High-Performance Soft Carbons Prepared by Treatment with Various Phosphorus Acids

  • Jeong, Seong Hun;Koh, Jeong Yoon;Kim, Tae Jeong;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2357-2360
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    • 2014
  • Phosphorus-doped soft carbons were successfully prepared by carbonizing petroleum cokes treated with phosphorus acids, such as $H_3PO_2$, $H_3PO_3$, and $H_3PO_4$. The effect of the type of phosphorus acids used on the composition, structure, and electrochemical performance of the soft carbons was extensively investigated. The soft carbons modified with $H_3PO_3$ and $H_3PO_4$ exhibited dramatically improved reversible capacities and outstanding rate capabilities.

A Row Decoder Design and Simulation Considering The Characteristics of PoRAM (PoRAM의 특성을 고려한 행 디코더 설계 및 시뮬레이션)

  • Park, Yu-Jin;Kim, Jung-Ha;Cho, Ja-Young;Lee, Sang-Sun
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.659-660
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    • 2006
  • The low crosstalk row-decoder is studied for PoRAM applications. Because polymer-based memories can be more densely integrated than established silicon-based ones, PoRAM is highly sensitive for the crosstalk problem. To overcome the problem and to suggest the suitable decoder for PoRAM, this paper shows the comparison of the row-path characteristics for both the 2-stage dynamic logic decoder and the 2-stage static logic decoder. Moreover, to suppress the Glitch effect which is observed by using the static logic decoder, the Master-Slave(M/S) D-Flip/Flop(D-F/F) is applied as a deglitch. Finally, the improved output result of the 2-stage static logic decoder with the M/S D-F/F is shown..

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Development of Seamless N-Screen Services through Multicast Transmission scheme (멀티캐스트 전송을 이용한 Seamless N-스크린 서비스 개발)

  • Hur, Kyeong;Choi, Sang-Gil;Lee, Hye-Jin;Jeon, Hye-Ji;Kim, Jin-Woo;Lee, Seong-Ro
    • Proceedings of the Korea Information Processing Society Conference
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    • 2015.04a
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    • pp.234-235
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    • 2015
  • P2P 스트리밍 가능한 OSMU(One Source Multi Use) N-스크린 서비스를 제공하기 위해서는 Seamless 무선 통신이 반드시 요구된다. 본 논문에서는 Seamless N-스크린 서비스를 위한 무선 통신 MAC 구조로서, WiMedia Distributed-MAC 프로토콜을 적용하고, OSMU N-스크린 서비스를 제공하기 위해, 멀티캐스트 전송 기술을 제안하고 성능을 분석하였다.

Electrical Conductivity of the System ThO$_2-Ho_2O_3$

  • Cho Seung Koo;Park Sung Ho;Kim Keu Hong;Choi Jae Shi
    • Bulletin of the Korean Chemical Society
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    • v.9 no.1
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    • pp.21-24
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    • 1988
  • The electrical conductivitv of the system $ThO_2-Ho_2O_3$ was measured in the temperature range 600-$1100^{\circ}C$ and $Po_2$range $10^{-5}-2{\times}10^{-1}$ atm. The mean value of activation energy was 1.45 eV. The observed conductivity dependence on $Po_2$ was ${Po_2}^{1/4}$ at $Po_2$'s above $10^{-3}$ atm and was independent on oxygen partial pressure at $Po_2$'s below $10^{-3}$ atm. It is suggested that these dependences are due to a mixed ionic plus electron hole conduction by Vo defect.

Residence Times and Chemical Composition of Atmospheric Aerosols II. Residence Times of Aerosols in Pusan (대기 에어로졸의 체류시간과 화학조성 II. 부산지역 에어로졸의 체류시간)

  • Yang, Han-Seob;Jun, Eun-Joo;Kim, Young-Ill;Ok, Gon
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.171-176
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    • 1999
  • To estimate the residence times of aerosols in air, the activities of $^{210}Pb$ and $^{210}Po$ in aerosols were measured at 4 sites in Pusan. All aerosol samples were collected by a high volume air sampler from January to October 1996. The activities $^{210}Pb$ and $^{210}Po$ in Pusan were varied from 11.77 to 67.57 dpm/1000$m^3$ and from 2.63 to 15.91 dpm/1000$m^3$, respectively. The mean activities were 34.62 dpm/1000$m^3$ for $^{210}Pb$ and 8.24 dpm/1000$m^3$ for $^{210}Po$. The highest values of the activities of $^{210}Pb$ and $^{210}Po$ were appeared at P3 site and the lowest values at P4 site. During the sampling period, the trends of the activities of $^{210}Po$ and $^{210}Pb$ were similar to total suspended particulate matter(TSP) concentrations. The mean residence times of atmospheric aerosols calculated from $^{210}Po$/$^{210}Pb$ activity ratio was about 60~80 days in Pusan. The longest residence time of atmospheric aerosols was in January because of the lack of rainout and washout, but the shortest residence time was in August, largely due to scavenging effect by frequent rains. The activities of $^{210}Po$ and $^{210}Pb$ in atmospheric aerosols were different in time and space, which seems that the distribution of $^{210}Po$ and $^{210}Pb$ activities and scavenging processes in air may be controlled by the local and meteorological conditions.

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High Pressure X-ray Diffraction Study of LiFePO4/C-olivine-like Phase (LiFePO4/C-유사 감람석 결정구조에 대한 고압 X-선회절연구)

  • Hwang, Gil-Chan;Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.26 no.1
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    • pp.35-44
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    • 2013
  • Synthetic carbon-coated olivine-like structured lithium iron phosphate ($Li^+Fe^{2+}(PO_4)^{3-}/C$) powder composites were compressed up to 35.0 GPa in the symmetrical diamond anvil cell at room temperature. Bulk modulus of $LiFePO_4/C$ was determined to be $130.1{\pm}10.3$ GPa. New peak appears at the d-spacing of 3.386 ${\AA}$ above 18 GPa, and another new one at 2.854 ${\AA}$ around 35 GPa. The crystallographic symmetry of the sample (i.e. orthorhombic) is apparently retained up to 35 GPa as no clear evidence for the phase transition into spinel structure has been observed. The pressure-induced volume change in the M1 site ($Li^+O_6$) is more significant than those in M2($Fe^{2+}O_6$) and $PO_4$ tetrahedral sites.