• 분석과학
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• 제31권1호
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• pp.23-30
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• 2018

어린이 제품 중 22 종의 알러지 유발 방향성 물질들을 기체 크로마토그래피 불꽃 이온화 검출기(GC-FID)와 기체 크로마토그래피 질량 분석기(GC-MSD)를 사용하여 분석하였다. 분석물질들은 자동속슬렛 추출장치를 사용하여 추출하였으며, 고속 냉동 원심분리기에서 10분동안 원심분리 후 상징액을 2 mL vial 옮겨 Split mode로 주입하여 분석하였다. 확립된 조건에서 검정곡선은 0.996 이상의 상관계수를 갖는 직선성을 보였으며, 감도의 경우는 6.7~1,859,839로서 물질별로 기기특성 및 검출기에 따라 상당히 넓은 범위의 감도를 나타내었다. 기기검출한계는 $0.0032{\sim}0.0335{\mu}g/mL$로서 최대 약 $0.1{\mu}g/mL$이하의 기기검출한계를 나타내었고, 방법검출한계는 $0.0033{\sim}0.1161{\mu}g/mL$의 범위를 나타내었다. 또한 정량한계는 $0.0100{\sim}0.5422{\mu}g/mL$의 범위를 보였고, 정밀도는 0.21~4.89 %, 정확도는 89~111%의 범위를 나타내었다. 본 연구에서 개발한 분석법으로 시판품에 실제 적용하였다.

• 한국지진공학회논문집
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• 제1권1호
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• pp.57-67
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• 1997

본 논문의 목적은 보-전단벽식 고층아파트의 단소성 지진응답해석을 수행하여 내진성능을 검토하는 것이다. 이를 위해 우선 구조물을 3차원 입체모델화하여 정적 탄소성해석을 수행하고 층 강성을 평가한 후, 그 결과를 이용하여 집중질량계모델을 사용한 시간이력 응답해석을 수행한다. 이때 탄소성 이력모델로는 modified Clough 모델을, 입력하중으로는 3종류의 기록 지진동 El-Centro 1940 NS, Taft 1952 EW, Hachinohe 1968 NS를 사용하되, 최대 지반가속도를 0.12g, 0.24g로 조절하여 사용한다. 해석모델로 장변 방향을 배치된 전단벽의 단면적이 단변의 0.5배이고, 동일한 평면을 가진 2세대가 일자형으로 배치된 25층의 아파트를 선정한다. 층간 변형각, 소성율등을 구하고 우리나라 및 미국, 일본의 내진규준에서 정하고 있는 제한사항과 비교검토한다.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2227-2232
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• 2009

Novel polythiol materials of urethane lens series for plastic optical lens were synthesized from polyol materials via thioisouronium of thiourea with c-HCl in refluxing aqueous solution, in which polythiol material was carried out from hydrolysis of thioisouronium by ammonia water. Their structure properties were identified by EA, EI-MS, FT-IR, $^1H\;and\;^{13}C$ NMR spectroscopies and TGA. Their ophthalmic lenses as polythiourethane material were prepared by thermal curing to an injected glass mold using the evenly solutions of diisocyanates series (TDI, XDI, HDI or IPDI) with polythiols. Polythiourethane shows that the strong stretching mode for SH group of polythiol disappeared in FT-IR spectra after thermosetting polymerization. Thermal deformation starting temperature of ophthalmic lenses was determined by TMA. Ophthalmic lenses made from characteristic polythiol and diisocyanate series have transparency, colorless and good impact strength, in which thermal resistance and impact strength of ophthalmic lenses were influenced by diisocyanate series. Physical properties of ophthalmic lens have contrast thermal resistance with impact strength. The property of thermal resistance and impact strength for respective ophthalmic lenses was examined by TMA and drop ball test.

• 한국전산구조공학회논문집
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• 제19권1호
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• pp.73-83
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• 2006

본 논문에서는 내구성과 수명을 획기적으로 향상시키기 위해 제3세대 건설재료인 섬유강화 플라스틱(FRP) 소재로 제작된 사각형 중공 교량 바닥판의 파괴모드를 실험과 해석을 통해 분석하였다. 재하시험 결과 바닥판의 강축방향의 거동은 파괴 직전까지도 거의 선형탄성적으로 거동한 반면, 약축방향의 거동은 재하초기부터 작은 하중하에서도 큰 비선형성을 보였다. 이 약축방향 비선형성의 원인은 웨브와 플랜지 연결부의 불완전한 일체거동으로 인한 소성거동 때문인 것으로 판단된다. 웨브와 플랜지의 연결부에 소성힌지를 도입한 간단한 구조모델을 이용하여 이를 확인하였다. 접착부의 박리 파괴 가능성도 검토하였으나 이는 대상 중공바닥판의 약축방향 파괴에 직접적으로 관여하는 것은 아닌 것으로 판단된다 약축방향의 구조거동을 개선시키기 위한 방안으로 내부를 폼으로 충전하는 방법을 제시하였으며 그 가능성을 구조해석을 통해 확인하였다.

• 대한토목학회논문집
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• 제28권1D호
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• pp.45-55
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• 2008

아스팔트 혼합물의 거동을 정확하게 예측하기 위하여 점탄소성 연속체 손상모형(이하 점탄소성 모형)을 개발하였다. 본 논문에서는 인장조건에서 점탄소성 모형의 개발과 4가지 혼합물(일반 밀입도, SBS, CR-TB, Terpolymer)을 이용한 모형의 검증과정을 다루고 있다. 모형 개발을 위해서 실내시험으로 측정한 아스팔트 혼합물의 전체 응답을 점탄성과 점소성 성분으로 구분하여 분석하였다. 점탄성 연속체 손상모형으로는 미세균열이 지배적인 상태에서 아스팔트 혼합물의 시간 의존적 거동을 해석하고, 고온 혹은 저속 하중 조건에서 발생한 영구변형(시간 종속과 비종속 성분을 모두 포함)은 점소성 모형으로 해석하였다. 변형률 분해 원리에 근거하여 각각의 모형을 통합하여 점탄소성 연속체 손상모형(VEPCD)을 개발하였다. 모형의 변수 결정을 위해서 직접인장시험을 수행하고 각각의 혼합물에 대한 선형 점탄성은 동탄성계수와 시간-온도 전이계수 그리고 위상각의 주곡선으로 정의하였다. 개발된 점탄소성 모형의 예측 성능을 평가하기 위하여 두 종류의 실내시험 실시하고 그 결과를 분석하였다 : 1) 단일 변형률 인장 시험, 2) 임의 하중조건을 모사한 피로 시험.

• Maxillofacial Plastic and Reconstructive Surgery
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• 제29권5호
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• pp.383-393
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• 2007

The aim of the present study is to investigate the effect of anodized surface of osseointegration implants by using of resonance frequency analysis (RFA) and histomorphometric analysis. A total of 96 screw-shaped implants were devided into 4 groups. Seventy-two implants were prepared by electrochemical oxidation with 3 different ways; Group 1 (n=24) were prepared at galvanostatic mode in 0.25M sulfuric acid and phosphoric acid, Group 2 (n=24) were prepared at galvanostatic mode in calcium glycerophosphate and calcium acetate, and Group 3 (n=24) were prepared at galvanostatic mode in 0.25M sulfuric acid and phosphoric acid followed by Calcium metaphosphate(CMP) coating. Control group (n=24) were the RBM surfaced implants. The implants were placed in the mandibles of 12 mini pigs. Bone tissue responses were evaluated by resonance frequency analysis(RFA) and histomorphometric analysis that were undertaken at 2, 4 and 6weeks after implant placement. The following result were obtained. 1. Twenty-two of 96 implants (4 in control group, 5 in group 1, 7 in group 2, and 6 in group 3) were failed due to faliure of osseoitegration. The failure rate of osseointegration was 22.9%. 2. The mean values of RFA in control, group 2 and groups 3 showed the similar values, but there was no significant difference among groups. 3. Histomorphometric evaluation demonstrated significantly higher bone-to-implant contact ratio in group 2 at 3 and 4 weeks after implant placement than other groups (p<0.05), but there was no significant difference among groups at 6weeks after implant placement.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2005년도 춘계학술대회논문집
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• pp.846-851
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• 2005

The purpose of this paper is that investigates the dynamic behavior characteristic of W.T.S(Wind turbine System) and carries out the evaluation analysis during operating W.T.S. To investigate the dynamic behavior characteristic of W.T.S, the experiments to measure vibration of the blade from the attached accelerometer on the flap and edge section of the blade that is one of the most important elements of dynamic characteristic of W.T.S are performed. Natural frequency and mode shape are calculated with commercial program (ANSYS) using the measured vibration acceleration that receives the signal with F.F.T Analyzer from the accelerometer. For validation of these experiments, the finite element analysis is performed with commercial F.E.M program (ANSYS) on the basis of the natural frequency and mode shape. The results indicate that experimental values have good agreements with the finite element analysis.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.57-60
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• 2005

The objective of this paper is to investigate and analyze the behaviour of prestressed I section structural members constructed with ultra high perfomance steel fiber reinforced cementitious concrete (SFR-UHPC). This material is known as reactive powder concrete (RPC) mixed with domestic materials and its compressive strength is over 150MP. The parameters of test specimens were span to depth ratio, prestressing force, prestressing wire placement and web width. Most influential parameter to determine the failure mode between shear and flexural action was proved to be shear span ratio. The characteristics of ultra high-strength concrete is basically brittle, but due to the steel fiber reinforcement behaviour of this structure member became ductile after the peak load. As a result of the test, the stress block of compressive zone should be redefined. The proposed analytical calculation of internal force capacity based by plastic analysis gave a good prediction for the shear and flexural strength of specimens. The numerical verification of the finite element model which constitutive law developed for Mode I fracture of fiber reinforced concrete correctly captured the overall behaviour of the specimens tested.

• 대한기계학회논문집
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• 제4권4호
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• pp.152-159
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• 1980

The temperature and the grain boundary precipitation have the great influence on the low-cycle fatigue behavior of austenite stainless steel at elevated temperature. For the purpose of investigating the mechanism concerning the change of fatigue micro crack mode in SUS 316 under various conditions low-cycle fatigue test was carried out at the elevated temperature 600.deg.C, plastic strain range 2% and constant strain rate .5c.p.m. A special attention is given to the observation of intergranular crack initiation. The results obtained are summarized as follows. The low-cycle fatigue behavior of SUS 316 at 600.deg.C is affected by transition of crack initiation mode from intergranular to transgranular. The transition is due to the aging effect, which is caused by grain boundary precipitations of Cr$\_$23/C$\_$6/. Since the intergranular crack initiation is brought about by the grain boundary sliding, the transgranular crack initiates in case that the strengthening of grain boundary due to the precipitation of Cr$\_$23/C$\_$6/ carbides takes place ahead of the intergranular crack initiation.

• 한국생산제조학회지
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• 제20권1호
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• pp.17-22
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• 2011

Ultimate goals in vehicle design can be summarized as environment-friendliness and safety. Along with these requirements, the importance of natural environment conservation has been focused lately. Therefore, reduced emission from vehicle and improved efficiency has become the top priority projects throughout the world. CFRP(Carbon Fiber Reinforced Plastics) of the advanced composite materials as structure materials for vehicles, has a widely application in lightweight structural materials of air planes, ships and automobiles because of high strength and stiffness. This study is to investigate the energy absorption characteristics of CFRP hat-shaped section members under the axial impact collapse test. The CFRP hat-shaped section members which manufactured from unidirectional prepreg sheets were made of 8plies. The axial impact collapse tests were carried out for each section members. The collapse mode and energy absorption characteristics were analyzed for CFRP hat-shaped section member according to the interface numbers(2, 3, 4, 6 and 7).