• Corrosion Science and Technology
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• v.19 no.1
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• pp.1-7
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• 2020

Chalk River Unidentified Deposits (CRUDs) were collected from the Korean pressurized water reactor (PWR) plant (A, B, and C) where the axial offset anomaly (AOA) occurred. AOA, also known as a CRUD-induced power shift, is one of the key issues in maintaining stable PWR plant operations. CRUDs were sampled from spent nuclear fuel rods and analyzed using an electron probe micro-analyzer (EPMA). This paper describes the characteristics of boron-deposits from the CRUDs sampled from twice-burnt assemblies from the Korean PWR. The primary coolant of a PWR contains boron and lithium. It is known that boron deposition occurs in a thick CRUD layer under substantial sub-cooled nucleate boiling (SNB). The results of this study are summarized as follows. Boron was not found at the locations where the existence was confirmed in simulated CRUDs, in other words, the cladding and CRUD boundaries. Nevertheless, we clearly observed the presence of boron and confirmed that boron existed as a lump in crystalline form. In addition, the study confirmed that CRUD existed in a crystal form with a unique size of about 10 ㎛.

• Nuclear Engineering and Technology
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• v.53 no.5
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• pp.1676-1685
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• 2021

We develop a new high-fidelity multiphysics model to simulate boron chemistry in the porous Chalk River Unidentified Deposit (CRUD) deposits. Heat transfer, capillary flow, solute transport, and chemical reactions are fully coupled. The evaporation of coolant in the deposits is included in governing equations modified by the volume-averaged assumption of wick boiling. The axial offset anomaly (AOA) of the Seabrook nuclear power plant is simulated. The new model reasonably predicts the distributions of temperature, pressure, velocity, volumetric boiling heat density, and chemical concentrations. In the thicker CRUD regions, 60% of the total heat is removed by evaporative heat transfer, causing boron species accumulation. The new model successfully shows the quantitative effect of coolant evaporation on the local distributions of boron. The total amount of boron in the CRUD layer increases by a factor of 1.21 when an evaporation-driven increase of soluble and precipitated boron concentrations is reflected. In addition, the concentrations of B(OH)₃ and LiBO₂ are estimated according to various conditions such as different CRUD thickness and porosity. At the end of the cycle in the AOA case, the total mass of boron incorporated in CRUD deposits of a reference single fuel rod is estimated to be about 0.5 mg.

• Journal of Ocean Engineering and Technology
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• v.20 no.4 s.71
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• pp.50-57
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• 2006

The effect of discharges from the Seomjin River on the dispersion of thermal effluent from the Hadong Power Plant, located along the south coast of Korea, was investigatedusing intensive field observation and three-dimensinal Princeton Ocean Model simulations. A POM and observed CTD data was used to predict the mixing behaviour of the Summer freshet, during the July 2005 intensive observing period. The dispersal of the river discharge anomaly, associated with the Seomjin River plume, was seen to be highly responsive to tidal currents and river flows during the spring tide.

• Ocean and Polar Research
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• v.43 no.3
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• pp.165-178
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• 2021

Gadolinium (Gd), one of a rare earth element (REE), has been widely used worldwide since the 1980s, as a resource material for contrast agents injected into examiners of magnetic resonance imaging (MRI) test. The organic complexed form of Gd shows an extremely stable behavior in natural environment (water), so is known that the artificial Gd from medical uses is not removed from the waste water treatment plant (WWTP) and eventually introduced into the ocean through the estuary. Since the 1990s, some previous studies have often been conducted on Gd anomalies in natural water and their effects an artificial origin from land or metropolitan areas, but little research has been potential impacts on the ocean water. In this paper, we review and introduce recent studies related to Gd anomaly in natural water and related marine effects, and also propose the future research directions.

• Journal of the Mineralogical Society of Korea
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• v.23 no.4
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• pp.347-356
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• 2010

Bauxite is a main raw material for the production of alumina and aluminum hydroxide in the processing plant of KC company. It is a NORM (Naturally Occurring Radioactive Materials), and its waste, red mud, is a TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). The purpose of the geochemical and mineralogical investigations of the bedrock and soils in and around the plant, a large NORM source, was to provide basic data for measuring the radiation dose and protecting from radioactive hazards. Soils were mixtures of minerals derived from the country rock (quartz, feldspar, mica, kaolin, gibbsite, and sepiolite) and bauxite (hematite, boehmite, and calcite) of open-air storage. Average U and Th contents of the soil samples were 4.7 ppm and 23 ppm, respectively, indicating somewhat Th anomaly. The average concentrations of radionuclides are $^{40}K$ 100~1,433 Bq/kg, $^{226}Ra$ anomaly in the red mud open-air storage. Soil external hazard indices range from 0.10 to 1.66 with an average of 0.63. Although most of the indices are below 1.0 that is a regulation value, those of 4 samples of total 41 soil samples exceed 1.0, requiring further detailed investigation.

• Journal of the Korean earth science society
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• v.43 no.2
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• pp.303-311
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• 2022

Gadolinium, commonly used as a contrast agent for magnetic resonance imaging (MRI), is discharged into aquatic environments without removal after treatment in wastewater treatment plants (WWTPs) because of its high stability. In this study, we collected water samples from Suyeong WWTP, Busan, to investigate the dissolved rare earth element (REE) removal capacity of each wastewater treatment process and to evaluate the discharge of anthropogenic Gd (Gd_anth) from effluents. As wastewater passed through each stage of treatment, the concentrations of light REEs (La-Eu) decreased, whereas those of heavy REEs (Tb-Lu) were relatively consistent. Negative Sm anomalies (<1) were observed in several samples, indicating that Sm can be removed by adsorption onto particles or phosphate during the biological removal process. Positive Gd anomalies (149±50, n=9) were observed in all samples. The ratios of Gd_anth concentrations to measured Gd concentrations in all wastewater treatment processes were higher than 97%. This indicates that Gd_anth was discharged to the Suyeong River without removal during the wastewater treatment process. Considering the daily treatment capacity in each process, the total flux of Gd_anth was estimated to be 259 mmol/day. Our results suggest that mid- and/or long-term monitoring of Gd is needed because Gd_anth is continuously discharged into Suyeong Bay through WWTPs.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.1 no.1
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• pp.73-79
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• 2003

In a pressurized water reactor, radioactive corrosion products (CRUD) in primary coolant system are one of the major sources for the occupational radiation exposure of the personnel in a nuclear power plant. Through the recent trend of long term fuel cycle in a nuclear power Plant, radioactive corrosion products deposited in reactor core for a long time are also the cause of Axial Offset Anomaly (AOA) having m effect on reactor power by the hideout of boron. CRUD consist primarily of magnetite, nickel ferrite, cobalt ferrite, and so on. They have the characteristic of strong magnetism. Therefore it is performed the conceptual design to develop the filter which removes the CRUD by magnetic field that is generated by an arrangement of permanent and electric magnets. Contrary to the conventional filter, the proposed filter does not interrupt the fluid flow, so there is little pressure drop and it can be used continuously. It is expected to be applied as one of the technologies for removal of the CRUB.

• Plant Biotechnology Reports
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• v.4 no.1
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• pp.85-94
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• 2010

In vitro shoot regeneration of gladiolus in three different culture systems, viz., semi-solid agar (AS), membrane raft (MR), and duroplast foam liquid (DF) cultures was evaluated following the kinetics of shoot multiplication and hyperhydricity at optimized growth regulator combinations. Compared to the AS system, matrixsupported liquid cultures enhanced shoot multiplication. The peak of shoot multiplication rate was attained at 18 days of incubation in the MR and DF systems, whereas the maximum rate in the AS system was attained at 21 days. An early decline in acceleration trend was observed in liquid cultures than the AS culture. The hyperhydric status of the regenerated shoots in the different culture systems was assessed in terms of stomatal attributes and antioxidative status. Stomatal behavior appeared to be normal in the AS and MR systems. However, structural anomaly of stomata such as large, round shaped guard cells with damage in bordering regions of stomatal pores was pronounced in the DF system along with a relatively higher $K^+$ ion concentration than in the AS and MR systems. Antioxidative status of regenerated shoots was comparable in the AS and MR systems, while a higher incidence of oxidative damages of lipid membrane as evidenced from malondialdehyde and ascorbate content was observed in the DF system. Higher oxidative stress in the DF system was also apparent by elevated activities of superoxide dismutase, ascorbate peroxidase, and catalase. Among the three culture systems, liquid culture with MR resulted in maximum shoot multiplication with little or no symptoms of hyperhydricity. Shoots in the DF system were more prone to hyperhydricity than those in the AS and MR systems. The use of matrix support such as membrane raft as an interface between liquid medium and propagating tissue could be an effective means for rapid and efficient mass propagation with little or no symptoms of hyperhydricity.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2003.11a
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• pp.38-42
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• 2003

In a pressurized water reactor, radioactive corrosion products (CRUD) in primary coolant system are one of the major sources for the occupational radiation exposure of the personnel in a nuclear power plant. Through the recent trend of long term fuel cycle in a nuclear power plant, radioactive corrosion products deposited in reactor core for a long time are also the cause of Axial Offset Anomaly (AOA) having an effect on reactor power by the hideout of boron. CRUD consist primarily of magnetite, nickel ferrite, cobalt ferrite, and so on. They have the characteristic of strong magnetism. Therefore it is peformed the conceptual design to develop the filter which removes the CRUD by magnetic field that is generated by an arrangement of permanent and electric magnets. Contrary to the conventional filter, the proposed filter does not interrupt the fluid flow, so there is little pressure drop and it can be used continuously. It is expected to be applied as one of the technologies for removal of the CRUD.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.11a
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• pp.220-221
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• 2005

Sub-bottom profiler(SBP) has been used extensively for the mapping of basement in the foundation design of offshore structure, for pre- and post-dredging operations within harbors and channels, for selection of pipeline routes, sitting of drilling platforms, and in the exploration for an aggregates such as sands and gravels. During the construction of Siwha embankment for irrigation water and the expansion of arable land, the breaking of an embankment unfortunately occurred so that a lot of riprap was swept away and widely dispersed by the tide and strong current. The feasibility study for the construction of the tidal-powered electric plant in Siwha embankment was performed quite recently. Therefore we made use of SBP survey to investigate the distribution of the lost riprap. We could successfully map out the distribution of the lost riprap from the reflection amplitude characteristics of the sediments in SBP data set. We demonstrated the variation of reflection amplitude versus the sediments with and/or without riprap by means of the numerical modeling of acoustic wave equation using finite difference method. Also we examined an amplitude anomaly of the ripraped area through the physical modeling using ultrasonic.