• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.276-283
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• 2018

For the first time, polyvinyl chloride (PVC) was used as an easily-handled chlorine source for preparation of isotropic pitch-based carbon fiber (IPCF) incorporating ethylene bottom oil (EO) as a raw material. Pitch precursors were prepared by the chlorination-dehydrochlorination triggered by chlorine radicals originated from PVC; aromatization and poly-condensation reactions occurred by polyene-type radicals from PVC. Radical production and co-carbonization were facilitated by pretreatments of EO through vacuum distillation, bromination, and additional heat treatment. Pitches were prepared by the co-carbonization of pretreated EO and EO containing 20 wt% PVC, and had higher yields and better spinnability than those by simple distillation.

• Carbon letters
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• v.15 no.4
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• pp.247-254
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• 2014

In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between $380^{\circ}C$ and $400^{\circ}C$ was required to obtain a softening point (SP) range of $220^{\circ}C-260^{\circ}C$ and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was conducted before the thermal treatment, the precursor pitch with a proper SP range could be obtained at reaction temperatures of $280^{\circ}C-300^{\circ}C$, which were about $100^{\circ}C$ lower than those for the case of thermal treatment only. With the acid treatments, the yield and SP of the precursor pitch increased dramatically and the formation of meso-phase was suppressed due to the lower reaction temperatures. Since the precursor pitches with acid and thermal treatment were not spinnable due to the inhomogeneity of properties such as molecular weight distribution and viscosity, the CTP was mixed with ethanol before the consecutive nitric acid and thermal treatments. The precursor pitches with ethanol, nitric acid, and thermal treatments were easily spinnable, and their spinning and carbon fiber properties were compared to those of air blowing and thermal treated CTP.

• Composites Research
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• v.26 no.5
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• pp.315-321
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• 2013

In this work, pitch-carbonized glass fibers were prepared for reinforcement of composites. The influence of acid functionalization of the fibers on the morphological, mechanical, and thermal properties of fiber-reinforced epoxy matrix composites was investigated. The acid functionalization of the fibers led to 10 and 150% increases in the mechanical and thermal properties, respectively, as compared to carbon fiber-reinforced composites. This can be attributed to the superior orientation of fiber structures and good interfacial interactions between fillers and epoxy matrix, resulting in enhanced degree of dispersion and formation of thermally conductive paths in the functionalized composites.

• Carbon letters
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• v.3 no.2
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• pp.80-84
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• 2002

The surface treatment of C-type isotropic pitch-based carbon fiber was carried out by anodic oxidation in 5 wt% $NH_4NO_3$ electrolyte. The changes of fiber surface and carbon fiber/ABS resin composites were characterized by SEM, XPS and mechanical properties test. The oxygen functional groups on the surface, such as hydroxyl (-C-OH), carboxyl (-COOH) groups etc., increased after oxidation. Tensile strength, flexural strength and modulus of carbon fiber/ABS composites were also enhanced. However, the impact strength decreased with the improvement of the surface adhesion between CF and matrix.

• Carbon letters
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• v.7 no.2
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• pp.114-118
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• 2006

Isotropic pitch-based carbon fiber has been activated by steam diluted in nitrogen in order to characterize the microporosity. Especially, 40 wt% burn-off ACFs were prepared from different conditions to compare the pore structure and size. The ACFs were thinly sliced to investigate the inside pores by TEM and image analyzer. As expected, the adsorption characteristics of these ACFs were quite different from one another because of different pore structure and size. Most pores are not slit-shaped but rather round. Small round micropores become broad and irregular as increasing the activation time and temperature.

• Transactions of the Society of Information Storage Systems
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• v.6 no.1
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• pp.12-17
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• 2010

Thermally-assisted magnetic recording (TAMR) is a potentially promising approach to increase the storage density of hard disk drive (HDD). However, TAMR has some issues such as temperature effects, media problems, thermal deformation and light delivery. In this research, we focused on light delivery. One of the powerful methods to deliver the light from laser diode to recording medium is the use of an optical fiber and a specially designed prism. However, the TAMR with optical fiber may have some flyability problems induced by the mounted optical fiber and prism. Also, the TAMR suspension using an optical fiber has high vertical and pitch stiffness. Therefore, p-torque is greatly increased by the optical fiber. Also, flying height (FH) of the slider with TAMR suspension can be largely changed by p-torque. Therefore, in this paper, we focus on the pitch static attitude (PSA) tolerance and the FH by PSA of the TAMR suspension. The FH is investigated using various errors and the PSA tolerance for TAMR suspension is proposed.

• 한국기계연구소 소보
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• s.15
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• pp.37-46
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• 1985

Properties of Precursor pitch derived from petroleum residue were studied physical and chemical analysis method for investigation of production of pitch fiber. For preparing of those precursor pitches it was carried out a temperature and time variation experiment i reactor. It was demonstrated the precursor pitch prepared in this study to have a similar properties to Ashland precursor pitch capable of bulk mesophase formation from the results of the basic analysis, that is, molecular weight distribution, coking yield, carbon content, chemical composition, etc.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2009.10a
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• pp.519-523
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• 2009

This paper presents the analysis of pitch static attitude (PSA) in thermally assisted magnetic recording (TAMR) suspension. The TAMR suspension using an optical fiber has high stiffness such as vertical, pitch and roll. Therefore, P-torque is greatly increased by the optical fiber. Also, flying height (FH) of the slider with TAMR suspension can be largely changed by PSA. In this paper, we focus on the FH by PSA of TAMR suspension. The FH is investigated using various PSA and proper PSA is proposed.

• Carbon letters
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• v.11 no.4
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• pp.304-310
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• 2010

To manufacture a carbon/carbon composite the coal tar pitch was used as the matrix precursor and the PAN (polyacrylonitrile)-based carbon fiber was used as the reinforcing material to weave 3-directional preform. For pressure carbonization HIP equipment was used to produce a maximum temperature of $1000^{\circ}C$ and a maximum pressure of 100 MPa. The carbonization was induced by altering the dwell temperature between $250^{\circ}C$ and $420^{\circ}C$, which is an ideal temperature for the moderate growth of the mesophase nucleus that forms within the molten pitch during the pressure carbonization process. The application of high pressure during the carbonization process inhibits the mesophase growth and leads to the formation of spherical carbon particles that are approximately 30 nm in size. Most particles were spherical, but some particles were irregularly shaped. The spread of the carbon particles was larger on the surface of the carbon fiber than in the interior of the matrix pocket.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.20 no.3
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• pp.229-234
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• 2010

This paper presents the analysis of pitch static attitude(PSA) in thermally assisted magnetic recording(TAMR) suspension. The TAMR suspension using an optical fiber has high stiffness such as vertical, pitch and roll. Therefore, P-torque is greatly increased by the optical fiber. Also, flying height(FH) of the slider with TAMR suspension can be largely changed by PSA. In this paper, we focus on the FH by PSA of TAMR suspension. The FH is investigated using various PSA and proper PSA is proposed.