• Journal of Environmental Science International
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• v.9 no.3
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• pp.229-239
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• 2000

Spring, ground and thermal waters in the vicinity of Mt. Geumjeong and Mt. Baekyang area have been sampled and analyzed for major and minor elements. According to the Piper diagram, spring water belongs to $Ca-HCO_3$ and $Na-HCO_3$ types, groundwater to $Ca-HCO_3$ type, and thermal water to Na-Cl type. Based on the phase stability diagrams of $[Ca^{2+}]/{[H^+]}^2, [Mg^{2+}]/{[H^+]}^2, [K^+]/[H^+]$, and $[Na^+]/[H^+] vs. [H_4SiO_4]$, spring water, groundwater and thermal water are mostly in equilibrium with kaolinite. The result of factor analysis shows three factors (factor 1, 2 and factor 3) for the spring water, the groundwater and the thermal water which are represented by the influence of the dissolution of feldspar, calcite, anthropogenic sources (domestic and industrial wastes) and salt water.

• Advances in environmental research
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• v.10 no.1
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• pp.43-57
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• 2021

Evaluation of groundwater quality is vital due to its diverse use for several purposes. In the present study, groundwater quality and suitability from the Peshawar basin, Pakistan, were evaluated for drinking and irrigation purposes. The water samples were analysed for major cations (Ca, Mg, Na and K) and anions (chloride, bicarbonate and sulphate) along with other physicochemical parameters (pH, electrical conductivity, total dissolved solids, and total hardness). About 95% of the water samples were found to be within the WHO, US-EPA and Pak-EPA permissible levels for drinking purposes. Seventy percent (70%) of the water samples belonged to the hard water category. Irrigation water quality parameters, such as, chloride, residual sodium bicarbonate, sodium adsorption ratio, percent sodium, magnesium adsorption ratio, Kelly's ration and permeability index were evaluated which demonstrated that the groundwater was highly to moderately suitable for irrigation. A correlation study was conducted to find out the mutual associations among the variables. Piper diagram indicated the overall chemical nature of the study area was calcium-magnesium bicarbonate type. Cluster analysis revealed mutual apportionment of various parameters in the groundwater of the Peshawar basin, Pakistan.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.2
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• pp.66-79
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• 1998

This study purposes to elucidate the characteristics of local water quality and the evolutional process of the spring water have been studied with the samples from 55 selected springs, from the coast region to the Baegrogdam, a caldera lake of Halla mountain in Cheju Island. Results of hydrochemical analyses in the 55 spring water show that Gwaneumsa is pollued with high hydrogen concentration, and spring waters from Yusuarmchun, Jangsumul, Dukjisemmul, Sinch'onk'nmul, Youngchunsa, Woonyangchun, Harwontongmul, Dongheamul, Seakdalsengsu, Andukkyekok, Dotimul, Kinmul, Harkangmul and Jungkeummul are polluted by the pollution sources from the surface surrounding ground. Spring waters of Samyang3suwon, Meungbusa, Sernurungmul, Tosanmul, Jungkeummul, Kwakgimul, Aewolharmul, Konemul and Nokgomul are also polluted from the sea water intrusion. The electrical conductivity, pH and the concentration of nitrate nitrogen and bicarbonate increase when the precipitation increases, but the concentration of sodium, chloride and sulphate decrease when the precipitation increases. The concentrations of potassium, magnessium and calcium are nearly independent of the precipitaion. Quality characteristics of spring water show complicated group of spring water through piper's trilinear diagram. The high mountain region consists of groups of sodium or potassium type and bicarbonate type; the middle mountain region consists of groups of sodium or potassium type and no dominant type; the low mountain consists of groups of no dominant type and sulfate or nitrate type; the coast region consists of groups of sodium or potassium type and chloride type or no dominant type. These characteristics indicate that the spring waters are changed from bicarbonate type in the high and middle mountain regions into non-bicarbonate type in the coastal region, as the precipitated waters flow downslope.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.4
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• pp.223-232
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• 1998

The Okmyong Waste Landfill which is one of major industrial waste landfills in Korea has been used for 10 years since January, 1988. The groundwater in range of 2∼3 km from the landfill is a little acidic and has high concentrations of EC, NO$_3$, and SO$_4$ because of acidic rain in Pohang. The groundwater pattern in Piper's trilinear diagram belongs to Ca-SO$_4$and Na-SO$_4$types, but Ca-SO$_4$type is more predominant. The groundwater of five monitoring wells at the landfill area is a litle alkaline and has high concentrations of TS, COD, Na, Cl, SO$_4$, Alkalinity and F because of the effect of the leachates. They also have high heavy metals of Mn, Zn, Pb, Cr and Ni but toxic organic compounds are not detected. Their groundwater pattern is Na-SO$_4$type and distinguished from the groundwater pattern Na-Cl types of the Nanjido and the Seokdae Municipal Waste Landfills. The range of groundwater contamination which is validated up to now is about 120m west from the entrance of the Okmyong Waste Landfill. To prevent the dispersion of the leachates to the outside, cutoff walls should be constructed at the boundary of the landfill. Several pumping wells should also be developed at the landfill so that the contaminated groundwater can be pumped and treated at a leachate-treatment plant in the landfill.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.258-261
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• 2002

남해 서부 연안 지역 지하수의 해수 침투 영향을 광역적으로 파악하기 위하여, 186개소의 지하수 시료를 random하게 채취하고 수리지구화학 연구를 수행하였다. 전체 시료 중 23.6%에서 500$\mu\textrm{m}$/cm을 초과하는 높은 EC값을 나타내어 상당한 정도의 해수 영향을 반영해 주었다 또한, 해수 영향 판단의 또 다른 파라메터로 사용되는 Cl/HCO$_3$ 몰비 역시 전체 시료의 23%에서 1.3 이상의 값을 나타내었다. 한편, 대표적으로 해수침투 영향 및 인위적 오염의 영향을 각각 반영하는 것으로 알려진 Cl과 NO$_3$의 농도에 관한 누적도수분포도(cumulative frequency curve)를 작성하여 배경수질군과 오염영향군을 구분 짓는 배경치(background concentration)를 구한 결과, 각각 Cl : 22.4 mg/1 및 NO$_3$= 23.4 mg/1로 나타났다. 이 두 파라메터의 농도 분포를 활용하여 샘플링된 지하수 시료를 크게 4개의 그룹으로 나눌 수 있었다. 그 결과, 자연적 또는 인위적 기원이 오염이 배제된 그룹 1은 전체 시료의 32%, 자연적 오염(해수 영향)을 반영하는 그룹 2는 전체의 15%, 인위적 오염의 영향을 반영하는 그룹 3은 전체의 7%, 해수 영향 및 인위적 오염을 동시에 반영하는 그룹 4는 전체의 46%로 나타났다 그룹 4 중 Piper diagram 상에서 Na-Cl 유형으로 점시되어 해수 영향을 강하게 반영하는 일부 시료와 그룹 2의 시료를 합쳐 보면, 전체 지하수 시료의 약 23%에서 해수의 영향을 반영하고 있다. 따라서, 여러 지구화학 방법에 의한 해수 영향 판단 결과는 서로 잘 일치하고 있음을 알 수 있다. 결국, 지구화학적 파라메터를 종합적으로 활용함으로써, 연안 지역 해수침투의 효과적인 파악은 물론 예측 및 방지, 복구에 효과적으로 사용될 수 있을 것으로 판단된다.

• The Journal of Engineering Geology
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• v.26 no.4
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• pp.561-570
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• 2016

For the investigation of hydrochemical changes in hot spring waters from the Onyang hot spring area, we analyzed water chemistry of 24 hot spring waters in 2011 and 2016. The results showed that there is no significant change in temperature and properties of the hot spring waters. The relationship of 2016 between temperature and $SiO_2$ and F reveals a positive trend ($r^2=0.60$, 0.47), and the relationship between temperature and Ca, Mg, Cl, $SO_4$, $HCO_3$, EC reveals a negative trend ($r^2=0.50$, 0.11, 0.50, 0.63, 0.23, 0.51). The relationship between temperature and pH is a positive trend, while the one between temperature and DO is a negative trend, indicating that the source is from deep groundwater. When plotted on Piper diagram, most of which are $Na-HCO_3$ but several hot waters are classified as the $Na(Ca)-HCO_3$, indicating inflow of shallow groundwater was occurred.

• Journal of Soil and Groundwater Environment
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• v.18 no.2
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• pp.36-44
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• 2013

The objectives of this study were to identify the characteristics of shallow groundwater from the oil-contaminated site for a long period and to evaluate the applicability of biopile technology to treat the soil excavated from it. The eight monitoring wells were installed in the contaminated site and pH, Electrical Conductivity (EC), Dissolved Oxygen (DO), Oxidation Reduction Potential (ORP), Temperature and the concentrations of major ions and pollutants were measured. The VOCs in soil gas were monitored during biopile operation and TPH concentration was analyzed at the termination of the experiment. The pH was 6.62 considered subacid and EC was 886.19 ${\mu}S/cm$. DO was measured to be 2.06 mg/L showing the similar characteristic of deep groundwater. ORP was 119.02 mV indicating oxidation state. The temperature of groundwater was measured to be $16.97^{\circ}C$. The piper diagram showed that groundwater was classified as Ca-$HCO_3$ type considered deep groundwater. The ground water concentration for TPH, Benzene, Toluene, Xylene of the first round was slightly higher than that of the second round. The concentration of carbon dioxide of soil gas was increased to 1.3% and the concentration of VOCs was completely eliminated after the 40 days. The TPH concentration showed 98% remediation efficiency after the 90 days biopile operation.

• Journal of the Korean Society of Groundwater Environment
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• v.5 no.4
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• pp.203-209
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• 1998

The quality of groundwater used for natural mineral water should be strictly regulated on international level by hydrogeology experts and officials because groundwater is greatly subjected to contaminations and its aquifer system may be easily destroyed by external reasons. A total of 18 natural mineral water plants exist in Precambrian metamorphic terrains of the Gyunggi massif and Yeungam massif. The g개undwater quality for the natural mineral water investigated in hydrochemical aspects shows that pH ranges from 6.85 to 8.02 with an average of 7.52. The electric conductivity (EC) and hardness average 134.1 $\mu$S/cm and 43.5, respectively, which are relatively low to the total average (151.4 $\mu$S/cm and 57.9). The contents of major cations and anions are in the order of $Ca^{2＋}$＞$Na^{＋}$＞Mg$^{2＋}$＞K$^{＋}$ and HCO$_3$$^{-}$ ＞SO$_4$$^{2－}$ ＞Cl$^{-}$ ＞F$^{-}$ , respectively. The dominant water types determined by Piper diagram are $Ca^{2＋}$－$Na^{＋}$－HCO$^{-}$ $_3$and $Ca^{2＋}$-HCO$^{-}$ $_3$, mainly due to the dissolution of plagioclase in the host rocks. Representative correlation coefficients between chemical species are $Ca^{2＋}$－HCO$^{-}$ $_3$(0.92), $Ca^{2＋}$－Cl$^{-}$ (0.63), $Na^{＋}$－F$^{-}$ (0.67), HCO$^{-}$ $_3$－Cl$^{-}$ (0.66), and $Na^{＋}$－HCO$^{-}$ $_3$(0.63). The determinative. coefficients between $Ca^{2＋}$ and HCO$^{-}$ $_3$, and (Ca$^{2＋}$＋$Na^{＋}$＋K$^{＋}$ and EC art highest among the elements. According to the saturation index, most chemical species are undersaturated with respect to major minerals, except for some silica phases. In viewpoint of phase equilibrium, the chemical evolution of the groundwater may continue to proceed with increasing pH because the groundwater is undersaturated with respect to feldspars.

• Journal of Soil and Groundwater Environment
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• v.25 no.4
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• pp.98-105
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• 2020

In this study, the concentrations of some of the important ionic contaminants in groundwaters of national monitoring network in Korea were identified, and their correlation to nitrate concentration was investigated. Approximately 80% of the groundwater samples were found to be as Ca2+-(Cl-+NO3-) type groundwater with the concentration ranges [minimum to maximum values, median (mg/L)] of Ca2+[0.1~228.2, 19.7], Mg2+[0.1~53.2, 5.1], K+[0.1~50.8, 1.9], Na+[1.5~130.5, 18.1], NO3--N[0.1~73.4, 9.3], NH4+-N[0.0~53.9, 0.3], Cl-[3.1~482.6, 24.0], and SO42-[2.8~101.6, 7.0]. The prevalence of Ca2+-(Cl-+NO3-) type suggest that the composition of groundwaters were greatly influcenced by chemical fertilizers and animal manure, Correlation analyses indicated threre was positive correlation between NO3--N concentration and ionic species including Cl-, Ca2+, Mg2+, and Na+. In particular, the correlation was strongest for Cl- and NO3--N, suggesting that groundwaters largely impacted by agricultural and livestock breeding activities tend to contain high levels of Cl-.

• Proceedings of the Korea Water Resources Association Conference
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• 2023.05a
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• pp.17-17
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• 2023

국내의 부지특성 및 감시 관련 규정은 원자력 안전위원회 고시 제2021-16호 제4조(세부지침)와 원자력 안전위원회 고시 제2021-17호 제16조에 의거하고, 국외는 국제원자력기구(IAEA: International Atomic Energy Agency)에서 안전기준을 제시하고 있다(IAEA, 2011). 따라서 국내 중·저준위 방사성폐기물 처분시설은 2006년부터 광역 지질을 포함한 부지 지질/지형, 기상, 수문, 수리지질, 인문사회 등을 망라한 조사를 시행하여 부지 현황에 대한 분석 및 안정성 평가를 수행한다. 부지감시의 수문·지구화학 분야에서는 현장 수질 측정 6항목과 실내 분석 26항목을 감시하고 있으나, 본 연구는 이 중 9개 항목(EC, Na, K, Ca, Mg, SiO₂, Cl, SO₄, HCO₃)을 선정하여 분석하였다. 연구 목적은 물시료 분석자료의 주성분-다중선형회귀-군집 분석과 Piper Diagram 분석결과로부터 해수와 담수(지하수)와의 특성분석 및 해수 영향을 분석하는 것이다. 현장 부지내 지하수 7개 관정(GM-1, 2, 4, 5, 6, 7, 8)과 해수 2개 지점(Sea-1, 2)을 대상으로 통계학적 주성분 분석결과, 대부분의 지하수는2개~4개의 요인으로 구분되고, 해수와의 유사성을 해석하기 위해 확인한 관정은 GM-5, GM-6, GM-1 지점으로 분류되었다. 상기와 같이 해수의 영향을 확인하기 위해 해수 2개 지점과 동일한 군집으로 분류되는 지하수는 GM-5 관정으로 확인되었고, 해안선에서 가까운 GM-5 관정과 같이 유사한 거리에 분포한 지하수 GM-1, 2, 4 관정은 2개 혹은 3개의 최적 군집으로 분류하였을 때도 GM-5와는 다른 특성을 보여주었다. 이는 해안과 인접하더라도 수질은 다른 지질학적 특성(지형, 기상, 단열대 등)에 따라 영향받았음을 지시한다.