• Title/Summary/Keyword: Pigment concentration

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Dyeing Properties of Natural Red Colorants Extracted from Phytolacca americana Linne against Wool Fabrics (미국자리공으로부터 추출한 홍색색소의 모섬유에 대한 염색성)

  • 홍경옥;오태광;배순이;신인수
    • Textile Coloration and Finishing
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    • v.11 no.2
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    • pp.38-45
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    • 1999
  • Natural red colorants were extracted from Phytolacca americana Linne by using 50% ethanol solution at room temperature for 12 hours. The colorant components were partially purified as yellow and deep red colorants by thin layer chromatography. Natural red colorants were consisted of major water-soluble red colorant, having maximum absorbance at 538nm and alcohol-soluble yellow colorant, having maximum absorbance at 664nm. Concentration of red colorants were calibrated by the equation of dye(mg/ml) $A_{538nm}\times{1.284}$. Red colorants were changed to yellow at extreme alkali pH and repaired 55% color intensity by neutralization of pH and stabled below $55^\circ{C}$. Dyeability of red colorants against wool fabrics was mainly operated by red pigment having 538nm absorbance without big color differences. Below $55^\circ{C}$, color differences $(\Delta{E}^*_{ab})$ were not changed in spite of big difference of chroma$(c^*)$, having higher scores at higher temperature. The effect of mordants were not drastically changed parameters of color difference without copper ion. Citric acid was big changes of color difference$(\Delta{E}^*_{ab})$ in spite of similar chroma$(c^*)$ values. From these experimental results, red colorants from Phytolacca americana Linne is available for wool fabric dyeing.

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Effects of High Pressure and Sodium Nitrite Levels on Cured Color Development and Residual Nitrite Concentration in Pork Homogenates

  • Hong, Geun-Pyo;Kim, Ji-Sook;Chun, Ji-Yeon;Min, Sang-Gi
    • Food Science of Animal Resources
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    • v.31 no.5
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    • pp.641-648
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    • 2011
  • This study investigated the effects of high pressure with or without thermal treatment on the cured color development and residual nitrite contents of model meat systems (pork, NaCl and sodium nitrite). At low nitrite levels (${\leq}50{\mu}g/g$), 200 MPa of pressure alone (P) did not develop the cured meat color (p>0.05). Thermal treatment (T) showed curing pigmentation (higher CIE L* and CIE a*), and the impacts were more effective when pressure was combined with thermal treatment (PT). In contrast, nitrite levels did not contribute to the cured meat color when ${\geq}200{\mu}g/g$ of nitrite was added to the meat. At high nitrite levels, although the typical cured color that is induced by thermal treatment did not present by pressure alone, the PT treatment still showed a pinker color with low residual nitrite content compared to the T treatment. The higher the pressure level (300 MPa), the greater the cured meat pigmentation with lower residual nitrite. Therefore, the present study demonstrates the possible application of high pressure, both for cured pigmentation and reducing residual nitrite, respective to typical thermal treatments.

Design of Optical Biological Sensor for Phycocyanin Parameters Measurement using Fluorescence Technique

  • Lee, Sung Hwa;Mariappan, Vinayagam;Won, Dong Chan;Ann, Myungsuk;Yang, Seungyoun
    • International journal of advanced smart convergence
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    • v.5 no.2
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    • pp.73-79
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    • 2016
  • Remote sensing and measurement are of paramount importance of providing information on the state of water quality in water bodies. The formation and growth of cyanobacteria is of serious concern to in land aquatic life forms and human life. The main cause of water quality deterioration stems from anthropogenic induced eutrophication. The goal of this research to quantify and determine the spatial distribution of cyanobacteria concentration in the water using remote sensing technique. The standard approach to measure water quality based on the direct measurement of the fluorescence of the chlorophyll a in the living algal cells and the same approach used to detect the phycobilin pigments found in blue-green algae (a.k.a. cyanobacteria), phycocyanin and phycoerythrin. This paper propose the emerging sensor design to measure the water quality based on the optical analysis by fluorescence of the phycocyanin pigment. In this research, we developed an method to sense and quantify to derive phycocyanin intensity index for estimating cyanobacteria concentrations. The development of the index was based on the reflectance difference between visible light band 620nm and 665nm. As a result of research this paper presents, an optical biological sensor design information to measure the Phycocyanin parameters in water content.

Assessment of total is ocyanates by OSHA and NIOSH analytical methods : accuracy and precision and airborne concentrations by process (NIOSH와 OSHA 측정 방법을 이용한 이소시아네이트류 발생 공정별 농도 분포 평가)

  • Kang, Hyoung Kyoung;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.9 no.2
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    • pp.1-18
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    • 1999
  • The purpose of this study was to compare performances of two analytical methods, the OSHA 42 and the NIOSH 5522, of quantifying total isocyanates in air. These methods were compared in terms of accuracy and precision and the detection limits using four(4) spiked samples in each of four(4) concentration levels which ranged from 0.25 to 2.0 times of the ACGIH TLV-TWA. In addition, two methods were used to as sess airborne concentrations of total isocyanates at the following processes including autobody spray painting, furniture spray painting, polyurethane foaming, urethane adhesion, UV coating, and pigment mixing. The results of this study showed that the NIOSH 5522 method was better than the OSHA 42 method in terms of accuracy, precis ion, and detection limit for quantifying airborne total isocyanates. It was also clear that the NIOSH method was capable of detecting not only monomeric but also non-monomeric isocyanates. The results of air concentrations of total isocyanates among processes studied indicate that some processes may exceed the recommended level of isocyanates. In addition, to evaluate toxicological effects of total isocyanates, it is recommended to consider additive effects of isocyanates present in mixtures.

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Synthesis and Characterization of Brilliant Yellow Color Pigments using α-FeOOH Nanorods (α-FeOOH 나노로드를 이용한 선명한 황색 안료 합성 연구)

  • Yun, JiYeon;Yu, Ri;Kim, YooJin
    • Journal of Powder Materials
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    • v.23 no.6
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    • pp.453-457
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    • 2016
  • In this work, we synthesize brilliant yellow color ${\alpha}$-FeOOH by controlling the rod length and core-shell structure. The characteristics of ${\alpha}$-FeOOH nanorods are controlled by the reaction conditions. In particular, the length of the ${\alpha}$-FeOOH rods depends on the concentration of the raw materials, such as the alkali solution. The length of the nanorods is adjusted from 68 nm to 1435 nm. Their yellowness gradually increases, with the highest $b^*$ value of 57 based on the International Commission on Illumination (CIE) Lab system, by controlling the nanorod length. A high quality yellow color is obtained after formation of a silica coating on the ${\alpha}$-FeOOH structure. The morphology and the coloration of the nal products are investigated in detail by X-ray diffraction, scanning electron microscopy, UV-vis spectroscopy, and the CIE Lab color parameter measurements.

Induction of Differentiation of the Human Histocytic Lymphoma Cell Line U-937 by Hypericin

  • Kim, Joo-Il;Park, Jae-Hoon;Park, Hee-Juhn;Choi, Seung-Ki;Lee, Kyung-Tae
    • Archives of Pharmacal Research
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    • v.21 no.1
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    • pp.41-45
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    • 1998
  • Hypericin, a photosensitizing plant pigment, was found to be a potent inducer of differentiation of human myeloid leukemia U-937 cells. At a concentration of $0.2{\mu}M$, hypericin exhibited 50% growth inhibition. An effect on cell differentiation by hypericin was assessed by its ability to induce phagocytosis of latex particles, and to reduce nitroblue tetrazolium (NBT). Approximately 51% of $0.2{\mu}M$ hypericin-treated cells were stained with NBT and 63% showed phagocytic activity. In order to establish whether hypericin induces differentiation of U-937 cells to macrophage or granulocyte, esterase activities and cell sizes were measured. When U-937 cells were treated with $0.2{\mu}M$ and $0.15{\mu}M$ of hypericin, the .alpha.-naphthyl acetate esterase activity was increased by 38.4% and 48.1%, respectively, but naphthol AS-D chloroacetate esterase activity was not influenced. The size of hypericin-treated cells in terms of cell mass was larger than that observed in untreated cells as determined by flow cytometry. Protein kinase C (PKC) inhibitor, NA-382, decreased the NBT reducing activity of hypericin, whereas a cAMP-dependent protein kinase A (PKA) inhibitor, H-89, did not show any influence on the differentiations. These results indicate that hypericin triggers differentiation toward monocyte/macrophage lineage by PKC stimulation.

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Inhibition of Invasion and Induction of Apoptosis by Curcumin in H-ras-Transformed MCF10A Human Breast Epithelial Cells

  • Kim, Mi-Sung;Kang, Hye-Jung;Moon, Aree
    • Archives of Pharmacal Research
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    • v.24 no.4
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    • pp.349-354
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    • 2001
  • Curcumin, a dietary pigment in turmeric, posseses anti-carcinogenic and anti-metastatic properties. The present study was conducted to study in vitro chemopreventive effects of curcumin in transformed breast cells. Here, we show that curcumin inhibits H-ras-induced invasive phenotype in MCF10A human breast epithelial cells (H-ras MCF10A) and downregulates matrix metalloproteinase (MMP)-2 dose-dependently. Curcumin exerted cytotoxic effect on H-ras MCF10A cells in a concentration-dependent manner. Curcumin-induced cell death was mainly due to apoptosis in which a prominent downregulation of Bcl-2 and upregulation of Bax were involved. We also suggest a possible involvement of caspase-3 in curcumin-induced apoptosis. Curcumin treatment resulted in the production of reactive oxygen species (ROS) in H-ras MCF10A cells. Apoptotic event by curcumin was significantly inhibited by pretreatment of an antioxidant N-acetyl-$_L$-cysteine (NAC), suggesting redox signaling as a mechanism responsible for curcumin-induced apoptosis in H-ras MCF10A cells. Taken together, our results demonstrate that curcumin inhibits invasion and induces apoptosis, proving the chemopreventive potential of curcumin .

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Effect of Heat Treatment on the Lipophillic Pigments of Fresh Green Tea Liquor

  • Lu, Jian-Liang;Dong, Zhan-Bo;Pan, Shun-Shun;Lin, Chen;Zheng, Xin-Qiang;Devajit, Borthakur;Liang, Yue-Rong
    • Food Science and Biotechnology
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    • v.18 no.3
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    • pp.682-688
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    • 2009
  • Changes in lipophillic pigments concentration and its relation to color of fresh green tea liquor during heat treatment were studied. The results showed liquor greenness decreased markedly with extension of incubation time at $55^{\circ}C$, while the brightness and yellowness changed a little. Significant increase in 'a' and 'b' values of tea liquor was observed at $95^{\circ}C$. Color change of liquor at $55^{\circ}C$ was accompanied by a decrease in the level of chlorophylls, lutein and neoxanthin, and an increase in the pheophytins and ${\beta}-carotene$ levels. However, all pigments except ${\beta}-carotene$ decreased with time extension at $95^{\circ}C$. Significant correlation was found between pigments and color difference index. The browning of fresh green tea liquor was attributed to vicissitudes of lipophillic pigments during heat treatment, especially to the change of chlorophylls/pheophytins ratio. Result also showed addition of $Zn^{2+}$ at 1.6 ${\mu}mol/L$ could partially alleviate the decrease in greenness during heat treatment.

Effect of Hydroxyl Radicals on Photosynthesis Pigments of Phytoplankton in Ship's Ballast Water of 20t/h

  • Bai, Xiyao;Bai, Mindong;Zhang, Zhitao;Bai, Mindi;Yang, Bo
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05a
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    • pp.43-48
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    • 2004
  • A pilot-scale system of 20t/h for the treatment of ship's ballast water and the setup of dissolved hydroxyl radical was introduced in this paper. With this experimental system, the kill efficiencies of bacteria, mono-algae, protozoan reach 100% within 2.67s when dissolved OHㆍconcentration is 0.6mg/L. At the same time, the effect of hydroxyl radicals on the photosynthesis pigments of phytoplankton was done. The results indicate that the contents of chi-a, chl-b, chl-c and carotenoid are decreased to 35~64% within 8.0s further to the lowest limit of test after 5 minutes. When dissolved OHㆍratio concentration is 0.68mg/L, the attenuation efficiencies of photosynthesis pigment are 100%. Therefore the invasive marine species can be killed in the process of the inputting and discharge ship's ballast water.

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Synthesis and Characterization of Rutile TiO2 Powder by the Sulfuric Acid Method (황산법을 이용한 루틸형 TiO2 분말의 제조 및 특성 평가)

  • Choi, Soon Ok;Cho, Jee Hee;Kim, Won Yong;Lim, Sung Hwan
    • Korean Journal of Metals and Materials
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    • v.50 no.7
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    • pp.523-530
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    • 2012
  • We investigated the experimental method that uses the homogeneous precipitation method to prepare mica flakes-coated rutile-type titania pearlescent pigment with urea as a precipitant. $TiO_2$ particles exhibit a high reflection of lights and optical properties with chemical stabilities, so they are appropriate for coating on luminescent pigments (mica). The coating principle of mi ca coated titania with various thicknesses was analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and tested by spectrophotometer. Mica with a particle size in the range of $40-60{\mu}m$ was suspended in water, and metal sulphates and urea were added to the mixture, which was heated to boiling. The change in pH was continuously followed. The metal oxide and crystal structure were affected by the conditions of $TiOSO_4$ concentration and reaction time with a sintering temperature the range of $800-1100^{\circ}C$.