• Title/Summary/Keyword: PiD

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Synthesis and Characterization of Colorless Polyimide Nanocomposite Films Containing Pendant Trifluoromethyl Groups

  • Jin, Hyo-Seong;Chang, Jin-Hae;Kim, Jeong-Cheol
    • Macromolecular Research
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    • v.16 no.6
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    • pp.503-509
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    • 2008
  • A series of colorless polyimide (PI) nanocomposite films were synthesized from 2,2'-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) and 2,2'-bis(trifluoromethyl)-4,4'-diaminobiphenyl (TFDB) with various organoclay contents by solution intercalation polymerization to poly(amic acid)s, followed by thermal imidization. The variation with the organoclay content of the thermomechanical properties, morphology, and optical transparency of the hybrids was examined at organoclay loadings ranging from 0 to 1.0 wt%. The hybrid films showed high optical transparency and almost no color, with cut-off wavelengths ranging from 352 and 356 nm and very low $b^*$ values of 1.19-1.77. The hybrid PI films showed good thermal properties with a glass transition temperature of $280-287^{\circ}C$. Most films did not show any significant thermal decomposition below $490^{\circ}C$. The addition of only a small amount of organoclay was sufficient to improve the tensile properties of the PI films with maximum enhancement being observed at 0.25 wt% organoclay. Moreover, these PI hybrids also had low coefficients of thermal expansion (CTE).

Electronic structure of the Au intercalated monolayer graphene on Ni(111)

  • Hwang, H.N.;Jee, H.G.;Han, J.H.;Tai, W.S.;Kim, Y.D.;Hwang, C.C.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.342-342
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    • 2010
  • We have investigated an Au intercalated monolayer graphene on Ni(111) using angle-resolved photoemission spectroscopy (ARPES), high resolution photoemission spectroscopy (HRPES), and low energy electron diffraction (LEED) at the 3A2 ARUPS beamline in Pohang Accelerator Laboratory. We find the monolayer graphene is well grown on the Ni(111) surface by the adsorption of acetylene. However, the graphene does not show the characteristic $\pi$ band near the Fermi level due to its strong interaction with the underlying substrate. When Au is adsorbed on the surface and then annealed at high temperature, we observe that Au is intercalated underneath the monolayer graphene. The process of the Au intercalation was monitored by HRPES of corresponding Au 4f and C 1s core levels as well as the electronic structure of the $\sigma$, $\pi$ states at $\Gamma$, K points. The $\sigma$, $\pi$ bands of graphene shift towards the Fermi level and the $\pi$ band is clearly observed at K point after the intercalation of full monolayer Au. The full width at half maximum (FWHM) of the C 1s peak narrows to approximately 0.42 eV after intercalation. These results imply that the interaction between the graphene and substrate is considerably weakened after the Au intercalation. We will discuss the graphene is really closer to ideal free standing graphene suggested recently.

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Investigation of Etching Characteristics for Powered Edge-Ring Utilizing PI-VM in Capacitively Coupled Argon/SF6/O2 Plasma (PI-VM을 이용한 용량 결합 Ar/SF6/O2 플라즈마에서의 전력 인가 에지 링 식각 특성 조사)

  • Hyunju Lee;Jaemin Song;Taejun Park;Nam-Kyun Kim;Gon-Ho Kim
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.4
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    • pp.7-12
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    • 2023
  • The edge ring placed on the outside of the electrostatic chuck (ESC) is a key component for protecting the ESC and controlling the etching uniformity of the edge of the wafer. Therefore, it is very important to understand the etching phenomenon of edge rings for edge ring management and equipment homeostasis. In this study, a specimen with SiO2 hard mask and underlying Si mold was installed on the edge ring surface and the etching results were measured by varying the edge ring 2MHz RF power. By developing PI-VM model with high prediction accuracy and analyzing the roles of key parameters in the model, we were able to evaluate the effect of plasma and sheath characteristics around the edge ring on edge ring erosion. This analysis method provided information necessary for edge ring maintenance and operation.

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Dynamic Surface In-plane Switching Property using the Ferroelectric Liquid Crystal on the surface

  • Choi, Sang-Ho;Choi, Su-Seok;Shin, Hyun-Ho;Chung, In-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.868-871
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    • 2006
  • In-plane switching characteristics of PI rubbed ITO sandwich cell with low molecule FLC (ferroelectric liquid crystal) surface was investigated. FLC on the surface is governed by the applying frequency and surface condition. By controlling the Ps (spontaneous polarization) direction of dual FLC surfaces, switching characteristics are improved without change of cell structure.

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Characterization of Weed Occurrence in Major Horticultural Crops - III. Phenological Aspects of Major Weeds (원예경작지(園藝耕作地)에서의 잡초발생(雜草發生) 특성에 관(關)한 연구(硏究) - III. 주요잡초종(主要雜草種)의 발생계절성(發生季節性))

  • Woo, I.S.;Pyon, J.Y.;Guh, J.O.
    • Korean Journal of Weed Science
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    • v.9 no.2
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    • pp.130-140
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    • 1989
  • 1) Dormancy brocken weed seeds were planted in soil at 15 days interval from June to December in 1986 and 1987 and test of normality and normal distribution curve were made to determine seasonal distribution characteristics of weed emergence in fields. Monthly emergence distribution pattern of each species can be concluded as following normal distribution equations. E. crusgalli $y={\frac{1}{2.52{\sqrt{2{\pi}}}}}e^{-{\frac{(x-10.057)^2}{12.7}}}$ E. indica $y={\frac{1}{2.17{\sqrt{2{\pi}}}}}e^{-{\frac{(x-9.16)^2}{9.45}}}$ A. lividus $y={\frac{1}{7.74{\sqrt{2{\pi}}}}}e^{-{\frac{(x-10.06)^2}{15.46}}}$ S. nigrum $y={\frac{1}{2.7{\sqrt{2{\pi}}}}}e^{-{\frac{(x-9.695)^2}{14.58}}}$ C. busrsa-pastoris $y={\frac{1}{2.83{\sqrt{2{\pi}}}}}e^{-{\frac{(x-9.02)^2}{16.02}}}$ D. sanguinalis $y={\frac{1}{2.8{\sqrt{2{\pi}}}}}e^{-{\frac{(x-8.58)^2}{15.67}}}$ S. viridis $y={\frac{1}{2.72{\sqrt{2{\pi}}}}}e^{-{\frac{(x-9.36)^2}{14.8}}}$ C. album $y={\frac{1}{2.596{\sqrt{2{\pi}}}}}e^{-{\frac{(x-8.07)^2}{13.48}}}$ P. oleraeda $y={\frac{1}{2.45{\sqrt{2{\pi}}}}}e^{-{\frac{(x-10.83)^2}{12.01}}}$ 2) Emergence peak period of weed species tested were from the end of May to early August and yearly variation of emergence was observed in E. crus-galli, S. viridis, S, nigrum, and P. oleracea and this fact may more related to rainfall pattern rather than temperature.

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Development of Quantitative Risk Assessment Methodology for the Maritime Transportation Accident of Merchant Ship (상선 운항 사고의 양적 위기평가기법 개발)

  • Yim, Jeong-Bin
    • Journal of Navigation and Port Research
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    • v.33 no.1
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    • pp.9-19
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    • 2009
  • This paper describes empirical approach methodology for the quantitative risk assessment of maritime transportation accident (MTA) of a merchant ship. The principal aim of this project is to estimate the risk of MTA that could degrade the ship safety by analyzing the underlying factors contributing to MTA based on the IMO's Formal Safety Assessment techniques and, by assessing the probabilistic risk level of MTA based on the quantitative risk assessment methodology. The probabilistic risk level of MTA to Risk Index (RI) composed with Probability Index (PI) and Severity Index (SI) can be estimated from proposed Maritime Transportation Accident Model (MTAM) based on Bayesian Network with Bayesian theorem Then the applicability of the proposed MTAM can be evaluated using the scenario group with 355 core damaged accident history. As evaluation results, the correction rate of estimated PI, $r_{Acc}$ is shown as 82.8%, the over ranged rate of PI variable sensitivity with $S_p{\gg}1.0$ and $S_p{\ll}1.0$ is shown within 10%, the averaged error of estimated SI, $\bar{d_{SI}}$ is shown as 0.0195 and, the correction rate of estimated RI, $r_{Acc}$(%), is shown as 91.8%. These results clearly shown that the proposed accident model and methodology can be use in the practical maritime transportation field.

Vector Control of SPMSM Using MATLAB/SIMULINK & dSPACE 1104 System (MATLAB/SIMULINK와 dSPACE 1104 시스템을 이용한 표면 부착형 영구자석 동기전동기 벡터제어)

  • Lee, Yong-Seok;Ji, Jun-Keun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.2
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    • pp.317-326
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    • 2008
  • This paper presents a vector control implementation for SPMSM(Surface-mounted Permanent Magnet Synchronous Motor) using dSPACE 1104 system and MATLAB/SIMULINK. SPMSM can be treated as a DC motor provided that currents of flux and torque component are controlled independently using vector control. Therefore various control algorithms for conventional DC motor control can be adopted to SPMSM. The system is designed to improve set-point tracking capability, fast response, and accuracy In This paper, d-q equivalent modeling of PMSM is derived based on vector control theory. PI controller is used for speed control and decoupling PI controller is used for current control. For the implementation of high performance vector control system, dSPACE 1104 system is used. Experiments were carried out to examine validity of the proposed vector control implementation.

Magnetic Properties of $Nd_xFe_{90.98-x}B_{9.02}$ Thin Films Grown by a KrF Pulsed Laser Ablation Method (KrF Pulsed Laser Ablation 법으로 제조한 $Nd_xFe_{90.98-x}B_{9.02}$ 박막의 자기특성)

  • 김상원;양충진
    • Journal of the Korean Magnetics Society
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    • v.7 no.6
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    • pp.299-307
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    • 1997
  • NdFeB films have been grown onto Si(100) substrate by a KrF pulsed laser ablation of the targets of $Nd_xFe_{90.98-x}B_{9.02}$ (x=17.51~27.51) at the substrate temperature of 620~700 $^{\circ}C$ and the laser beam energy density of 2.75~5.99 J/$\textrm{cm}^2$. The films exhibit no preferred orientation, however, good hard magnetic properties were produced from as-deposited condition : $4{\pi}M_s$=7 kG, $4{\pi}M_r$=4 kG, and $H_c$=300~1000 Oe. The depositon rate was not greatly influenced by changing the substrate temperature, but it increases linearly by increasing the beam energy density. The beam energy density of 3 J/$\textrm{cm}^2$ gave the optimal condition to have the highest $4{\pi}M_r$ and $H_c$ as well. The higher content of Nd induces a higher coercivity and $4{\pi}M_r$ at the same time without prominent change in $4{\pi}M_s$.

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Reflective Bistable Chiral Splay Nematic Liquid Crystal Display (반사형 쌍안정 카이랄 스플레이 네마틱 액정표시소자)

  • Kim, Tae-Hyung;Lee, Joong-Ha;Shen, Zheng-Guo;Jang, Ji-Hyang;Kim, Jeong-Soo;Jhun, Chul-Gyu;Kwon, Soon-Bum;Yoon, Tae-Hoon;Kim, Jae-Chang
    • Korean Journal of Optics and Photonics
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    • v.22 no.1
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    • pp.23-29
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    • 2011
  • Bistable chiral splay nematic liquid crystal display (BCSN LCD) is a memory type liquid crystal display using splay and $-\pi$ twist states as two stable states. When the cell thickness to pitch (d/p) ratio is 0.25, splay and $-\pi$ twist states have permanent memory time. However, when the transition from $-\pi$ twist state to splay state is caused by a fringe field, pixel regions show that the splay state is not perfect, but rather includes a contribution from the $-\pi$ twist state. In this paper, we propose a reflective BCSN LCD using $-\pi$ twist state in which the two stable states do not coexist. The fabricated reflective BCSN LC cell shows a high contrast ratio of over 30:1 and response times of 950 ms and 450 ms in vertical and fringe field switching, respectively. The proposed cell also shows wide viewing angle characteristics of $180^{\circ}$ in left- and right directions.

SIZE OF DOT PRODUCT SETS DETERMINED BY PAIRS OF SUBSETS OF VECTOR SPACES OVER FINITE FIELDS

  • Koh, Doowon;Pi, Youngjin
    • Journal of the Chungcheong Mathematical Society
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    • v.26 no.4
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    • pp.853-867
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    • 2013
  • In this paper we study the cardinality of the dot product set generated by two subsets of vector spaces over finite fields. We notice that the results on the dot product problems for one set can be simply extended to two sets. Let E and F be subsets of the d-dimensional vector space $\mathbb{F}^d_q$ over a finite field $\mathbb{F}_q$ with q elements. As a new result, we prove that if E and F are subsets of the paraboloid and ${\mid}E{\parallel}F{\mid}{\geq}Cq^d$ for some large C > 1, then ${\mid}{\Pi}(E,F){\mid}{\geq}cq$ for some 0 < c < 1. In particular, we find a connection between the size of the dot product set and the number of lines through both the origin and a nonzero point in the given set E. As an application of this observation, we obtain more sharpened results on the generalized dot product set problems. The discrete Fourier analysis and geometrical observation play a crucial role in proving our results.