• Title/Summary/Keyword: Pi5

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Annealing Behavior of Pretilt Angles on Polyimide Surface with Rubbing and Ion Beam Irradiation

  • Lee, Sang-Keuk;Lim, Ji-Hun;Oh, Byeong-Yun;Kim, Young-Hwan;Han, Jeong-Min;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.9 no.6
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    • pp.243-246
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    • 2008
  • We have studied the liquid crystal (LC) alignment, the pretilt angle generation, and the annealing behavior for a nematic liquid crystal (NLC) on the homogeneous polyimide (PI) surfaces by using the rubbing method and the ion beam (IB) method. An excellent LC alignment of the NLC on the PI surface with rubbing and IB irradiation were observed. The pretilt angle of NLC on the homogeneous PI surface for the rubbing method is decreased from $4.5^{\circ}$ to $3.5^{\circ}$ as rubbing time is increased, that of the for the IB irradiation method is decreased from $0.5^{\circ}$ to $0.1^{\circ}$ as the time of IB irradiation is increased. After the annealing, the pretilt angles of the rubbed PI surfaces increased up to $4^{\circ}$, these of the IB irradiated PI surfaces little increased. It is considered the side chain of the rubbed PI show the its abilities of the original capacities, while the side chain of the IB irradiated PI cannot show the its abilities of the original capacities due to the IB has already destroyed the side chain of the PI.

The p110${\gamma}$ PI-3 Kinase is Required for the Mechanism by Which the EphA8-induced Neurites are Modulated by Ephrin-A5 Engagement

  • Park, Soo-Chul
    • Animal cells and systems
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    • v.8 no.1
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    • pp.57-63
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    • 2004
  • This study provides evidence that expression of EphA8 receptor in NG108-15 cells results in a substantial increase in the number of neurite-bearing cells. However, the EphA8-induced neurite outgrowth does not require either ephrin-A5 stimulation or ectopic expression of $p110{\gamma}$ PI-3 kinase. In contrast, co-expression of a lipid kinase-inactive $p110{\gamma}$ mutant together with EphA8 causes neurite retraction in the presence of ephrin-A5 stimulation. This effect was not observed in the absence of ephrin-A5 stimulation. Significantly, the tyrosine kinase activity of EphA8 is not important for either of these processes. Taken together, our results strongly suggest that $p110{\gamma}$ PI-3 kinase is critically involved in the regulatory process by which ephrin-A5 exerts effects on the EphA8-induced neurite outgrowth.

Characterizations of Copoly(ester imide)s with New 2,7-Dihydroxynaphthalene Bis(trimellitate anhydride) (새로운 2,7-Dihydroxynaphthalene Bis(trimellitate anhydride) 무수물을 이용한 폴리(에스터 이미드) 공중합체의 특성)

  • Ju, Jieun;Chang, Jin-Hae
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.632-639
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    • 2014
  • 2,7-Dihydroxynaphthalene bis(trimellitate anhydride) (2,7-TA) was synthesized from trimellitic anhydride chloride and 2,7-dihydroxynaphthalene. Copolyimides (Co-PI) containing ester group were synthesized from 2,7-TA, pxylylenediamine, and 2,2'-bis(trifluoromethyl)benzidine (TFB). The Co-PI films were obtained from poly(amic acid) by solution casting through thermal imidization on a glass plate. The thermal property, gas permeation, and optical transparency of the Co-PI films with various TFB monomer contents were investigated. These Co-PIs could be solution-cast into a flexible and tough film. The cast Co-PI films exhibited high optical transparency with a cut-off wavelength of 370~395 nm in UV-vis. absorption and a low yellow index value of 3.55~7.63. The thermal property of Co-PI films increased linearly with increasing TFB content. However, the oxygen permeation and optical transparency of the Co-PI films was found to worsen with increasing TFB content.

Photoelectrochemical Properties of Gallium Nitride (GaN) Photoelectrode Using Cobalt-phosphate (Co-pi) as Oxygen Evolution Catalyst (산소발생용 Cobalt-phosphate (Co-pi) 촉매를 이용한 Gallium Nitride (GaN) 광전극의 광전기화학적 특성)

  • Seong, Chaewon;Bae, Hyojung;Burungale, Vishal Vilas;Ha, Jun-Seok
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.2
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    • pp.33-38
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    • 2020
  • In the photoelectrochemical (PEC) water splitting, GaN is one of the most promising photoanode materials due to high stability in electrolytes and adjustable energy band position. However, the application of GaN is limited because of low efficiency. To improve solar to hydrogen conversion efficiency, we introduce a Cobalt Phosphate (Co-pi) catalyst by photo-electrodeposition. The Co-pi deposition GaN were characterized by SEM, EDS, and XPS, respectively, which illustrated that Co-pi was successfully decorated on the surface of GaN. PEC measurement showed that photocurrent density of GaN was 0.5 mA/㎠ and that of Co-pi deposited GaN was 0.75 mA/㎠. Impedance and Mott-Schottky measurements were performed, and as a result of the measurement, polarization resistance (Rp) and increased donor concentration (ND) values decreased from 50.35 Ω to 34.16 Ω were confirmed. As a result of analyzing the surface components before and after the water decomposition, it was confirmed that the Co-pi catalyst is stable because Co-pi remains even after the water decomposition. Through this, it was confirmed that Co-pi is effective as a catalyst for improving GaN efficiency, and when applied as a catalyst to other photoelectrodes, it is considered that the efficiency of the PEC system can be improved.

EVALUATION SUBGROUPS AND CELLULAR EXTENSIONS OF CW-COMPLEXES

  • Lee, Kee-Young;Woo, Moo-Ha
    • Bulletin of the Korean Mathematical Society
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    • v.32 no.1
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    • pp.45-56
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    • 1995
  • D. H. Gottlieb [1, 2] studied the subgroups $G_n(X)$ of homotopy groups $\pi_n(X)$. In [5, 7, 10], the authors introduced subgroups $G_n(X, A)$ and $G_n^{Rel}(X, A) of \pi_n(X)$ and $\pi_n(X, A)$ respectively and showed that they fit together into a sequence $$ \cdots \to G_n(A) \longrightarrow^{i_*} G_n(X, A) \longrightarrow^{j_*} G_n^{Rel}(X, A) \longrightarrow^\partial $$ $$ \cdots \to G_1^{Rel}(X, A) \to G_0(A) \ to G_0(X, A) $$ where $i_*, j_*$ and \partial$ are restrictions of the usual homomorphisms of the homotopy sequence $$ \cdot \to^\partial \pi_n(A) \longrightarrow^{i_*} \pi_n(X) \longrightarrow^{j_*} \pi_n(X, A) \to \cdot \to \pi_0(A) \to \pi_0(X) $$.

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An Auto-tuning Algorithm of PI Controller Using Time Delay Element (시간 지연 요소를 이용한 PI 제어기 자동 동조 알고리즘)

  • Oh, Seung-Rohk
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.47 no.6
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    • pp.1-5
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    • 2010
  • We propose an algorithm which can classify the system should use a PI controller, which have a weak high frequency attenuation characteristics near the critical frequency. To classify the system, we use a time delay element to calculate a gain attenuation rate near the critical frequency. The proposed algorithm also can design PI controller with the given magnitude margin and phase margin specification. The proposed algorithm uses time delay element and saturation function to identify the one point information in frequency domain. We justify the proposed algorithm via the simulation.

Effect of Ginsenosides from Red Ginseng on the Enzymes of Cellular Signal Transduction System (홍삼 사포닌류(Ginsenosides)의 세포 신호 전달계 효소에 미치는 영향)

  • 임경택;최진성
    • Journal of Ginseng Research
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    • v.21 no.1
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    • pp.19-27
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    • 1997
  • The present study was conducted to assess the effect of total saponins from Korean red ginseng on the biosynthesis of inositol phospholipids in vivo and also effects on the metabolic enzymes, such as phosphatidylinositol-specific phospholipase C(Pl-PLC) and PI-kinases. The administration of 0.1% saponin solution, 0.1 ml 3 times a day intraperitoneally to 5 mice for 30 days has increased a 23% of the body weight when it compared with a control group. The amounts of 32P-phoschorus radioactivity incorporated into the phosphoinositides from the liver and brain tissues have increased a 310% and 260%, respectively, in the saponin treated mice. The activities of PI-PLC from liver and brain were stimulated in the various amounts by the conditions treated with saponins. The PI-kinases from liver and brain were also activated by saponins, but its effect was lower than that of PI-PLC. From these results, it was confirmed that red ginseng saponins have affected positively not only on the biosynthesis of phosphoinositides but also on the PI-PLC and PI-kinases related to the cellular signal transduction.

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Washing Effects on Generation of Pretilt Angle in NLC, 5CB, on a Polyimide Surface with Trifluoromethyl Moieties

  • Lee, Sang-Keuk;Han, Jeong-Min;Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.1
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    • pp.21-23
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    • 2003
  • The washing effects on pretilt angle generation in a nematic liquid crystal (NLC), 4-n-pentyl-4'-cyanobiphenyl (5CB) on a rubbed polyimide (PI) surface with trifluoromethyl moiety have been successfully studied. The pretilt angle of 5CB is increased by the washing process on the rubbed PI surface. The surface tension on the rubbed PI surface increases with the rubbing strength RS and then saturated above RS: 150 mm. The pretilt angle of 5CB for all washing processes on the rubbed PI surface decreases with the surface tension. We have found that the pretilt angle of 5CB on the rubbed PI surface may be attributed van der walls (VDW) dispersion interaction between the LC molecules and the polymer surfaces having trifluoromethyl moieties.

Synthesis and Spectral Properties of 1,2-Bispyrazyl Ethylene (1,2-비스피라질 에틸렌의 합성과 분광학적 성질에 대한 연구)

  • Shim Sang Chul;Lee Dong Soo;Chae, Jeong Seok;Song Pili Soon
    • Journal of the Korean Chemical Society
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    • v.20 no.5
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    • pp.398-405
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    • 1976
  • A new compound, 1,2-bispyrazyl ethylene,is synthesized starting from pyrazine carboxylic acid and methyl pyrazine. The compound is characterized utilizing UV-VIS, IR, NMR and mass spectra along with elemental analysis. Spectroscopic properties are studied from UV-VIS and fluorescence spectra. From unusual salt effects on fluorescence spectra, it is believed that $(n,\;{\pi}^*)$ state has about the same energy as $({\pi},\;{\pi}^*)$ state. The compound fluoresces from $({\pi},\;{\pi}^*)$ state with the quantum yield of 0.025 at $77^{\circ}K$ compared to near unity for stilbene at the same temperature indicating the efficient intersystem crossing to triplet state, because of strong $(n,\;{\pi}^*)$ and $({\pi},\;{\pi}^*)$ mixing in the lowest excited state.

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Pi2 Pulsations During Extremely Quiet Geomagnetic Condition: Van Allen Probe Observations

  • Ghamry, Essam
    • Journal of Astronomy and Space Sciences
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    • v.34 no.2
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    • pp.111-118
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    • 2017
  • A ultra low frequency (ULF) wave, Pi2, has been reported to occur during periods of extremely quiet magnetospheric and solar wind conditions. And no statistical study on the Pi2 has been performed during extremely quiet conditions, using satellite observations to the author's knowledge. Also Pi2 pulsations in the space fluxgate magnetometers near perigee failed to attract scientist's attention previously. In this paper, Pi2 pulsations detected by the Van Allen probe satellites (VAP-A & VAP-B) were investigated statistically. During the period from October 2012 to December 2014, ninety six Pi2 events were identified using VAP when Kp = 0 while using Kakioka (KAK, L = 1.23) as a reference ground station. Seventy five events had high coherence between VAP-Bz and H components at KAK station. As a result, it was found that 77 % of the events had power spectra between 5 and 12 mHz, which differs from the regular Pi2 band range of from 6.7 to 25 mHz. In addition, it was shown that it is possible to observe Pi2 pulsations from space fluxgate magnetometers near perigee. Twenty two clean Pi2 pulsations were found where L < 4 and four examples of Pi2 oscillations at different L shells are presented in this paper.