• 제목/요약/키워드: Physicochemical and mechanical properties

검색결과 95건 처리시간 0.023초

Influence of Functionalization on Physicochemical Properties of Multi-walled Carbon Nanotubes/Epoxy Matrix Nanocomposites

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • 제30권1호
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    • pp.124-128
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    • 2009
  • In this study, the effect of multi-step purification or functionalization on physicochemical properties of multi-walled carbon nanotubes (MWNTs)/epoxy (EP) nanocomposites was investigated. The nanocomposites containing multi-step purified MWNTs showed a stronger influence on $T_g$ and increased in mechanical properties in comparison to nanocomposites containing the same amount of only purified MWNTs. Consequently, the multi-step purification of MWNTs led to an improvement of thermomechanical properties of nanocomposites, resulting from improving the intermolecular interaction of MWNTs in epoxy matrix resins.

Effect of ionizing radiation on mechanical and electric properties of polymer composites

  • Soh, Dae-Wha;Kovtunets, V.A.;Kupchishin, A.I.;Mun, G.A.;Nurkeeva, Z.S.;Akhmetkalieva, G.T.;Khutoryanskiy, V.V.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.588-591
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    • 2002
  • Radiation technology is an effective way for regulating polymeric materials to physicochemical and mechanical properties. The effect of radiation on mechanical and electrochemical properties of new rubber-like polymeric composite materials based on poly(vinyl ether of ethyleneglycol : PVEEG) have been studied for investigating mechanical and electric property of polymer composites applications.

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Basic Physicochemical and Mechanical Properties of Domestic Bentonite for Use as a Buffer Material in a High-level Radioactive Waste Repository

  • Cho, W.J.;Lee, J.O.;Chun, K.S.;Hahn, D.S.
    • Nuclear Engineering and Technology
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    • 제31권6호
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    • pp.39-50
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    • 1999
  • The physicochemical, mineralogical, hydraulic, swelling and mechanical properties of a domestic bentonite for use as the buffer material in a high-level waste repository have been measured. The bentonite is identified to be a Ca-bentonite, and the hydraulic conductivity of the compacted bentonite with the dry density higher than 1.4 Mg/㎥ is lower than 10$^{-11}$ m/s When the dry densities are 1.4 to 1.8 Mg/㎥, the swelling pressures are in the range of 6.6 to 143.5 kg/$\textrm{cm}^2$. The unconfined compressive strength is about 94 kg/$\textrm{cm}^2$, and the coefficient of volume change and the coefficient of consolidation are in the range of 0.O0249 to 0.02142 $m^2$/MN and 0.018 to 0.115$m^2$/year, respectively.

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Effect of Ionizing Radiation on Mechanical and Electric Properties of Polymer Composites Based on Polyvinyl ether of Ethyleneglycol

  • Mun G. A.;Nurkeeva Z. S.;Kovtunets V. A.;Kupchishin A. I.;Akhmetkalieva G. T.;Khutoryanskiy V. V.;Al-Sayed A. A.;Soh Dea-Wha
    • Transactions on Electrical and Electronic Materials
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    • 제4권3호
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    • pp.25-28
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    • 2003
  • Radiation technology is an effective way for regulating polymeric materials to physicochemical and mechanical properties. New polymeric hydrogels based on vinyl ethers have been synthesized by the $\gamma$-initiated polymerization method. In this paper, we have studied the effect of radiation on mechanical and electrochemical properties of new rubber-like polymeric composite materials based on polyvinylether of ethyleneglycol (PVEEG).

Physicochemical Changes in UV-Exposed Low-Density Polyethylene Films

  • Salem, M.A.;Farouk, H.;Kashif, I.
    • Macromolecular Research
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    • 제10권3호
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    • pp.168-173
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    • 2002
  • Unstabilized low-density polyethylene (LDPE) films and films formulated with hindered amine light stabilizer (HALS) were exposed to UV-radiation; and the physicochemical changes during photooxidation processes have been investigated using tensile, FTIR spectre-photometric and thermal analytical (DSC) techniques. The dependence of tensile properties (elongation- and stress-at-break), carboxyl index and heat of fusion on UV-irradiation time have been discussed. The use of HALS is found to be effective in maintaining the UV-mechanical properties of the LDPE films. The experimental results showed that there exists no correlation between mechanical properties and carbonyl index, whereas crystallinity correlates well with carbonyl index in unstabilized and stabilized films for irradiation times greater than 100 h. The rate of formation of carbonyl groups is found to be dependent on UV exposure time. Crystallinity of the film samples is strongly influenced by both exposure time and presence of HALS.

실리콘겔 인공유방의 기계적 및 물리화학적 특성에 대한 연구 (Study for Mechanical and Physicochemcial Properties of Silicone Gel Filled Mammary Implants)

  • 백홍;장동혁;송정민;이승영;서무엽;박길종;맹은호
    • 대한의용생체공학회:의공학회지
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    • 제33권2호
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    • pp.89-97
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    • 2012
  • The purpose of this study is to develop the guideline of the physicochemical and mechanical properties evaluation for silicone gel filled breast implants. First of all, the use and development status for silicone gel filled breast implants were investigated, and then, standard and criteria about performance evaluation established by the international organizations such as ASTM, FDA guidance and ISO were examined. To evaluate the mechanical properties, data research and testing for breaking strength, elongation, tensile set, joint intensity, silicone gel cohesion, weight loss from heating, static rupture resistance, impact resistance test, fatigue test, and gel bleed were performed. On the other hand, to evaluate the physicochemical properties, volatile matter, extent of cross linking, heavy metals, and extractable were analyzed. In this study, results for general function, mechanical properties and physicochemical properties were examined and reviewed for the accordance with international standard, and objective and standardized guideline was provided.

동충하초 첨가식빵의 저장기간에 따른 이화학적. 텍스쳐 특성 (Physicochemical and Texture of Bread added Paecilomyces japonica according to Storage Period)

  • 박금순;김수진;박어진
    • 동아시아식생활학회지
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    • 제11권6호
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    • pp.485-497
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    • 2001
  • For a period of 5 days, the quality of breads with Paecilomyces japonica powder were investigated using chemical, sensory, and mechanical evaluations at $25^{\circ}C$. The result of analysis of chemical properties revealed that the pH value of dough was increased as the amount of Paecilomyces japonica powder increased, but volume of dough and baking loss rate were decreased. Breads with 1% and 2% Paecilomyces japonica powder showed a good overall preference in sensory evaluation. As storing time passed. moisture content, lightness, and redness were decreased in all breads, but yellowness increased. Hardness and gumminess of texture analysis were increased as storing time passed, but springiness decreased. Springiness of the mechanical properties was negatively correlated with pH value of dough and volume of bread, while was positively correlated with volume of dough and baking loss rate. In the analysis of correlation between sensory and mechanical properties showed that hardness of mechanical properties had negative correlation with softness, moistness, and springiness. Cohesiveness of mechanical properties had positive correlation with acceptability.

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Effect of crude fibre additives ARBOCEL and VITACEL on the physicochemical properties of granulated feed mixtures for broiler chickens

  • Jakub Urban;Monika Michalczuk;Martyna Batorska;Agata Marzec;Adriana Jaroszek;Damian Bien
    • Animal Bioscience
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    • 제37권2호
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    • pp.274-283
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    • 2024
  • Objective: The aim of the study was to evaluate the physicochemical properties (nutrient composition, pH, water content and activity, sorption properties) and mechanical properties (compression force and energy) of granulated feed mixtures with various inclusion levels of crude fibre concentrates ARBOCEL and VITACEL for broiler chickens, i.e. +0.0% (control group - group C), +0.3%, +0.8%, +1.0%, +1.2%. Methods: The feed mixtures were analyzed for their physicochemical properties (nutrient composition by near-infrared spectroscopy, pH with the use a CP-401 pH meter with an IJ-44C glass electrode, water content was determined with the drying method and activity was determined with the Aqua Lab Series 3, sorption properties was determined with the static method) and mechanical properties (compression force and energy with the use TA-HD plus texture analyzer). The Guggenheim-Anderson-de Boer (GAB) model applied in the study correctly described the sorption properties of the analyzed feed mixtures in terms of water activity. Results: The fibre concentrate type affected the specific surface area of the adsorbent and equilibrium water content in the GAB monolayer (p≤0.05) (significantly statistical). The type and dose of the fibre concentrate influenced the dimensionless C and k parameters of the GAB model related to the properties of the monolayer and multilayers, respectively (p≤0.05). They also affected the pH value of the analyzed feed mixtures (p≤0.05). In addition, crude fibre type influenced water activity (p≤0.05) as well as compression energy (J) and compression force (N) (p≤0.001) (highly significantly statistical) of the feed mixtures. Conclusion: The physicochemical analyses of feed mixtures with various inclusion levels (0.3%, 0.8%, 1.0%, 1.2%) of crude fiber concentrates ARBOCEL or VITACEL demonstrated that both crude fiber types may be used in the feed industry as a feedstuff material to produce starter type mixtures for broiler chickens.

고압균질처리가 전분필름의 물성에 미치는 영향 (Effects of High Pressure Homogenization on Physicochemical Properties of Starch Films)

  • 강은정;이재권
    • 산업식품공학
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    • 제15권1호
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    • pp.70-74
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    • 2011
  • 전분필름의 물성에 미치는 고압균질 처리의 영향을 검토한 결과, 고압균질처리 옥수수전분필름은 산화전분필름과 유사한 투명도를 가지며, 용해도와 산소투과억제력의 증가와 함께 인장강도가 다소 높아지는 것을 확인하였다. 이러한 고압균질처리 옥수수전분필름의 물성변화는 고압균질기의 고압과 전단력에 의해 호화전분입자가 완전히 소실되고 전분의 용해도 증가와 보다 균일한 분산상이 형성되기 때문으로 판단되었다. 일반적인 호화과정을 통해 형성되는 전분필름의 구조는 연속상의 아밀로오스에 팽윤된 접분입자가 분산되어 있는 network 형태에서 형성된다. 반면 고압균질처리의 경우, 호화전분입자의 붕괴로 아밀로펙틴이 연속상을 이루고 여기에 아밀로오스가 분산상으로 존재하는 새로운 분산계(dispersed system)가 형성되어, 기존 호화 방법으로 제조한 필름과 다른 물성을 나타내는 것으로 판단되었다.

동결 건조된 옥수수 전분 스펀지 매트릭스의 이화학적 특성 (Physicochemical Properties of Freeze-dried Corn Starch Sponge Matrix)

  • 한경훈;김도희;송관영;이계희;윤택준;양성범;이석원
    • 한국식품영양학회지
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    • 제23권3호
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    • pp.419-427
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    • 2010
  • The focus of the current study was to investigate the physicochemical properties of a corn starch-sponge matrix prepared at a low concentration below gel forming by freeze-drying. The effect of variables(starch concentration, heating temperature, and heating hold time) on the physicochemical properties of the samples was analyzed by response-surface methodology. Regression models on the properties of samples such as hardness, springiness, and water solubility index(WSI) showed high correlation coefficients(r>0.95) and significant F values, but regression models for the other properties(swelling power, apparent viscosity, reducing sugar content, and digestibility) showed them to have relatively low significance. Sample hardness of sample showed the highest value at condition of $90^{\circ}C$ and 5%, whereas springiness was at a maximum at $130^{\circ}C$ and 5%. Also, at 1% of starch concentration, mechanical properties were greatly decreased as the relative humidity increased, compared with the 3% and 5%, especially in the hardness of samples. The WSI showed an increasing trend with heating temperature regardless of starch concentration. Overall, the physicochemical properties of freeze-dried corn starch-sponge matrix were influenced much more by starch concentration and heating temperature than by heating hold time. The results of this study show that the basic properties of freeze-dried corn starch-sponge matrix can be used for the specific food applications or as a functional material for its stability.