• Title/Summary/Keyword: Physical stability

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Association Between Communication for Chemical Hazards Information and Characteristics of Occupational Safety and Health manager (산업안전보건관리자 특성과 화학물질 유해성 정보전달의 관련성)

  • Kim, Ki-Woong;Park, Jin Woo;Jeong, Mu Soo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.22 no.2
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    • pp.156-163
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    • 2012
  • Objectives: The aim of the present study was undertaken to investigate the association between communication for chemical hazard information and characteristics of occupational safety and health managers. Subjects and Methods: We surveyed 78 occupational safety and health managers(64 male and 14 female) in 78 chemical manufacturing plants. Data were obtained using a self-reported questionnaire about size and type of company, products, communication system for chemicals and work-related characteristics of occupational safety and health managers. All analyses in this study were performed using SPSS program 12.0. Results: 64.1% of the study participants were occupational health managers aged 39.3 years on average and were graduated from college and university around 90%. 30.0% and of them were majoring in chemistry (engineering chemistry), 18.0% occupational health, 16% nursing and 30.0% others. Occupational safety managers were aged 39.4 years on average, 42.9% of them were majoring in chemistry (engineering chemistry), 21.4% environmental engineering, 10.7% occupational safety and 25% others. 86% of occupational health managers and 71.4% of occupational safety managers were classified as office job. Over 94% of the hazards information for chemicals were delivered by occupational safety and health managers, but about 28.2% workers preferred outside experts who have a profound knowledge about occupational safety and health and understandable. Occupational safety and health managers and workers had difficulties in understanding toxicological information, hazards identification, stability/reactivity, composition/information on ingredients, physical/chemical properties and ecological information. On multiple logistic regression analysis for the 16 heading of material safety data sheet, content of material safety data sheet was significantly associated with education level (odds ratio=0.286, 95% confidence interval=0.105-0.780). The hazard identification (odds ratio=3.947, 95% confidence interval=1.092-14.271) and toxicological information (odds ratio=0.841, 95% confidence interval=0.705-0.998) were significantly associated with type of occupation. Conclusions: This finding implies that the education level, type of occupation and speciality of occupational safety and health managers may affects hazards information delivery.

Properties of Sol-Gel Materials Synthesized from Colloidal Silica and Alkoxysilane Containing Epoxysilane (에폭시 실란을 함유한 콜로이드 실리카와 알콕시 실란간의 졸겔코팅제 합성과 특성)

  • Kang, Dong-Pil;Park, Hoy-Yul;Ahn, Myeong-Sang;Myung, In-Hye;Choi, Jae-Hoon;Kim, Hyun-Joong
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.822-826
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    • 2005
  • Colloidal Silica (CS)/methyltrimethoxysilane (MTMS) and CS/MTMS/epoxysilane (ES) sol solutions were prepared using various synthesizing parameters such as reaction time and types of CS and silane. In order to understand their physical and chemical properties, sol-gel coating films on glass were fabricated. In the case of the CS/MTMS sol, the coating films had high contact angle and more enhanced flat surface than the CS/MTMS/ES sol. In the case of thermal stability, thermal degradation of the CS/MTMS and CS/MTMS/ES coating films did not occur up to $550^{\circ}C$ and $440^{\circ}C$, respectively. The coating films prepared from the CS/MTMS sol were thicker than those of the CS/MTMS/ES sol. In addition, the coating films prepared from single CS were thicker than those of mixed CS. Hardness of the coating films prepared from CS/MTMS increased by adding ES. In case of the mixed CS, the hardness decreased by adding ES.

A Basic Study on Non-aqueous Electrolysis of Neodymium for Room-temperature Metallurgy (상온제련을 위한 네오디뮴의 비수계 전해 기초연구)

  • Park, Jesik;Lee, Churl Kyoung
    • Resources Recycling
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    • v.27 no.4
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    • pp.29-35
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    • 2018
  • In this study, the electrochemical redox behavior of neodymium in non-aqueous electrolytes was investigated to confirm the possibility of neodymium metallurgy at room temperature. The non-aqueous electrolytes include ionic liquids such as $[C_4mim]PF_6$, $[C_4mim]Cl$, and $[P_{66614}]PF_6$, ethanol which are highly soluble in neodymium salts, and mixed electrolytes based on carbonate with highly electrochemical stability. The electrochemical redox properties of neodymium were better than those of other electrolytes in the case of the mixed electrolyte based on ethylene carbonate (EC)/di-ethylene carbonate (DEC). Ethanol was added to improve the physical properties of the mixed electrolyte. Thorough the analysis about ionic conductivity of EC/DEC ratio, ethanol content and $NdCl_3$ concentration, the best electrolyte composition was 50 vol% content of ethanol and 0.5 M of $NdCl_3$. Using cyclic voltametry and linear sweep voltametry, a current peak estimated at -3.8 V (vs. Pt-QRE) was observed as a limiting current of neodymium reduction. Potentiostatic electrolysis for 18 hours at room temperature at -6 V (vs. Pt-QRE) confirmed that metallic neodymium was electrodeposited.

The effect of notification disposition in the current juvenile justice system from the perspective of institutionalized children's welfare (시설보호아동의 복지 관점에서 본 소년법상 통고제도)

  • Lee, Hyung-Seob;Jung, Sun-wook
    • Journal of the Korean Society of Child Welfare
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    • no.56
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    • pp.69-99
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    • 2016
  • Taking the perspective of children's welfare, this study aimed at critically analyzing the system of notification disposition which institutionalized children have experienced. Notification disposition is a juvenile justice process that, when a child (10 th 18 years old ) has been delinquent or is at risk for delinquency, is initiated without investigation or prosecution procedures by direct notification to a judge from the caregivers, school principals, chief probation officers, or directors of child care institutions. The data used in the analysis included case records of probation offices, and court sentencing documents of juvenile protective dispositions. Results showed that notification cases were initiated by directors of child shelters/care institutions. The most common reasons of notification were theft, runaway, physical violence, drinking, and smoking. Furthermore, there were more controversial reasons, such as "bad influence on another institutionalized children", "showing no remorse", "no sense of guilt"and "challenge of rearing in institutions" Based on the results, we discussed three problematic aspects of the direct notification system by directors of childcare institutions : (1) too much reliance on the judicature judgment of juvenile court; (2) less stability of the judicial status of notified children, and (3) inadequacies of the notifying eligibility for directors of child care institutions.

A Study on Fire Explosion Characteristics via Physico-chemical Analysis of Petroleum Residues (석유 부산물의 물리화학적 분석을 통한 화재폭발 특성연구)

  • Kim, Hyeonggi;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.30 no.5
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    • pp.556-561
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    • 2019
  • In this study, the physical and chemical analyses of petroleum residues (pyrolized fuel oil, PFO) were conducted and major components were selected to investigate their fire and explosion characteristics. Major component distribution areas of the PFO were identified via the GC-SIMDIS and MALDI-TOF analyses. In addition, the qualitative analysis of major component distribution areas was performed by GC-MS analysis. Major components of pyrolysis residue were selected based on the results of various analyses such as EA, SARA and TGA. As a result, benzene, toluene and xylene were selected as major components. Finally, the process hazard analysis software tool (PHAST) analysis was performed to investigate the range of maximum damage effect in case of fire and explosion. Toluene presented the highest risk due to the radiation effect of $227kW/m^2$ and 118 m in the case of jet fire. Xylene and benzene showed the maximum radiant heat values of 114 and $151kW/m^2$, respectively. It was also confirmed from the analysis of pasquill stability and wind speed that the radiant heat increased up to 55% according to wind speed in benzene, which was considered to be a main factor increasing the influence range.

A Review on TOPCon Solar Cell Technology

  • Yousuf, Hasnain;Khokhar, Muhammad Quddamah;Chowdhury, Sanchari;Pham, Duy Phong;Kim, Youngkuk;Ju, Minkyu;Cho, Younghyun;Cho, Eun-Chel;Yi, Junsin
    • Current Photovoltaic Research
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    • v.9 no.3
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    • pp.75-83
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    • 2021
  • The tunnel oxide passivated contact (TOPCon) structure got more consideration for development of high performance solar cells by the introduction of a tunnel oxide layer between the substrate and poly-Si is best for attaining interface passivation. The quality of passivation of the tunnel oxide layer clearly depends on the bond of SiO in the tunnel oxide layer, which is affected by the subsequent annealing and the tunnel oxide layer was formed in the suboxide region (SiO, Si2O, Si2O3) at the interface with the substrate. In the suboxide region, an oxygen-rich bond is formed as a result of subsequent annealing that also improves the quality of passivation. To control the surface morphology, annealing profile, and acceleration rate, an oxide tunnel junction structure with a passivation characteristic of 700 mV or more (Voc) on a p-type wafer could achieved. The quality of passivation of samples subjected to RTP annealing at temperatures above 900℃ declined rapidly. To improve the quality of passivation of the tunnel oxide layer, the physical properties and thermal stability of the thin layer must be considered. TOPCon silicon solar cell has a boron diffused front emitter, a tunnel-SiOx/n+-poly-Si/SiNx:H structure at the rear side, and screen-printed electrodes on both sides. The saturation currents Jo of this structure on polished surface is 1.3 fA/cm2 and for textured silicon surfaces is 3.7 fA/cm2 before printing the silver contacts. After printing the Ag contacts, the Jo of this structure increases to 50.7 fA/cm2 on textured silicon surfaces, which is still manageably less for metal contacts. This structure was applied to TOPCon solar cells, resulting in a median efficiency of 23.91%, and a highest efficiency of 24.58%, independently. The conversion efficiency of interdigitated back-contact solar cells has reached up to 26% by enhancing the optoelectrical properties for both-sides-contacted of the cells.

Material Characteristics and Nondestructive Deterioration Assessment for the Celestial Chart Stone, Korea (천상열차분야지도 각석의 재질특성과 비파괴 훼손도 평가)

  • Yoo, Ji Hyun;Lee, Myeong Seong;Choie, Myoungju;Ahn, Yu Bin;Kim, Yuri
    • The Journal of the Petrological Society of Korea
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    • v.27 no.4
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    • pp.207-222
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    • 2018
  • Celestial Chart Stones (original and reproduction) in the National Palace Museum are representative scientific cultural heritage of Korea. Material analysis and nondestructive deterioration assessment were conducted for long-term preservation of these stones. Material analysis revealed that the original was composed of slate and the reproduction was made of dolostone. The original consists of quartz, mica, dolomite minerals, while the reproduction was made up of dolomite, calcite and forsterite. Major deterioration factors of the original stone were cracks and breakouts. In case of the reproduction, scratches and artificial materials were mainly observed. The green and black surface contaminants present at the sides and back of the two celestial chart stones were interpreted as resin-based paint materials. The physical property evaluation using ultrasonic velocity showed a low velocity in the upper left side of the original, while the front right side of the reproduction showed a weak property. Meanwhile, the To-Tc method using ultrasonic velocity was applied to major cracks that impede stability of the original. As a result, it has been calculated that the beginning and the center of the crack are the deepest.

A Study on the Application of Modularization Technique to Standard Security Policy to Protect Information Assets and the Securement of Confidentiality and Integrity (정보자산 보호를 위한 표준 보안정책 모듈화 기법 적용과 기밀성 및 무결성 확보를 위한 연구)

  • Seo, Woo-Seok
    • The Journal of the Korea institute of electronic communication sciences
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    • v.14 no.1
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    • pp.111-118
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    • 2019
  • For the security of a vast amount of information, it has been started to diagnose the site as a way of operating and managing the information owned by a company holding assets, to establish indexes to check the actual status and all kinds of standards to obtain security, and also to classify the information assets based on that. This has been extended to many different areas including policies to operate and manage information assets, services, the management of owned devices as physical assets, and also the management of logical assets for application software and platforms. Some of these information assets are already being operated in reality as new technology in new areas, for example, Internet of Things. Of course, a variety of electronic devices like Smart Home are being used in ordinary families, and unlike in the past, these devices generate a series of information life cycles such as accumulating and processing information. Moreover, as even distribution is now being realized, we are facing a task to secure the stability of information assets and also information that assets are holding. The purpose of this study is to suggest and apply standard security policy by moduling methods for information assets owned by companies and even families and obtain the enhancement of confidentiality as well as integrity.

Rheological properties of flour dough containing roasted rice bran (볶은 쌀겨를 첨가한 밀가루 반죽의 rheology 특성)

  • Shin, Hyun-Kwang;Lee, Jeong-Hoon;Chung, Koo-Chun;Lee, Si-Kyung
    • Korean Journal of Food Science and Technology
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    • v.50 no.6
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    • pp.587-593
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    • 2018
  • This study was carried out to investigate the effect of roasted rice bran (RRB) on the rheological properties of bread dough. According to farinograph analysis, the consistency of the control sample was greatest. There were no significant differences in water absorption (p<0.05). Lower values of development time, stability, and time to breakdown, which were affected, by the addition of RRB, were observed for RRB-containing dough samples, compared to the control dough sample. Addition of RRB significantly increased the mixing tolerance index (MTI). According to rheofermentometer analysis, the values of H'm, $T^{\prime}_1$, and retention volume decreased with increase in the amount of RRB added. According to the rapid visco analyzer (RVA) analysis, peak viscosity, holding strength, and setback values were greater in the control than in the RRB-containing samples. The addition of RRB to the flour influenced rheological properties like fermentation volume and acidity. The total acidity increased with the increase in the amount of RRB added. The present study has indicated that there was no significant difference between the rheological properties of the control and 5% RRB-containing dough samples. Therefore, the addition of 5% RRB could be an effective way to produce functional flour bread without affecting its desirable physical properties.

Soil Properties of Granitic Weathered Soils in the Landslide-prone Areas in Seoul (서울지역 화강암 풍화토 토층지반의 토질특성)

  • Kim, Kyeong-Su
    • The Journal of Engineering Geology
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    • v.29 no.1
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    • pp.23-35
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    • 2019
  • Landslides occur due to heavy rainfall in the summer season. Some of water may infiltrate into the ground; it causes a high saturation condition capable of causing a landslide. Soil properties are crucial in estimating slope stability and debris flow occurrence. The main study areas are Gwanaksan, Suraksan and Bukhansan (Mountain) in Seoul. A total of 44 soil samples were taken from the study area; and a series of geotechnical tests were performed. Physical and mechanical properties were obtained and compared based on region. As a result, among well-graded soils, they are classified as a clayey sand. Coarse-grained and fine-grained contents are approximately 95% and 5%, respectively, with very low amount of clay content. Density, liquid limit and dry unit weight are ranged in $2.62{\sim}2.67g/cm^3$, 27.93~38.15% and $1.092{\sim}1.814g/cm^3$. Cohesion and internal friction angle are 4 kPa and $35^{\circ}$ regardless of mountain area. Coefficient of permeability is varied between $3.07{\times}10^{-3}{\sim}4.61{\times}10^{-2}cm/sec$; it means that it results in great seepage. Permeability is inversely proportional to the uniformity coefficient and is proportional to the effective particle size. In the formal case, there was a difference by mountain area, while in the latter, the tendency was almost similar.